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| 中文名 | N-甲基二丁炔呋喃 |
|---|---|
| 英文名 | N-butyl-N-methylbutan-1-amine |
| 中文别名 |
N-甲基二正丁胺
N-甲基二丁胺 N,N-二正丁基甲胺 二丁基甲胺 |
| 英文别名 |
N,N-Dibutylmethylamine
1-Butanamine,N-butyl-N-methyl Dibutylmethylamine di-1-butylmethylamine N-methyl-di-1-butylamine EINECS 222-288-9 DIBUTYLAMINE,N-METHYL N-Methyldibutylamine N,N-dibutyl-N-methylamine methyl dibutyl amine MFCD00009430 N-Methyldi-n-butylamine |
| 密度 | 0.777g/cm3 |
|---|---|
| 沸点 | 164.6ºC at 760mmHg |
| 分子式 | C9H21N |
| 分子量 | 143.27000 |
| 闪点 | 42.2ºC |
| 精确质量 | 143.16700 |
| PSA | 3.24000 |
| LogP | 2.51840 |
| 折射率 | n20/D 1.4178(lit.) |
| 储存条件 | 常温， 避光，通风干燥处，密封保存 |
| 稳定性 | 常温常压下稳定 |
| 分子结构 | 1、 摩尔折射率：47.46 2、 摩尔体积（m3/mol）：184.3 3、 等张比容（90.2K）：415.9 4、 表面张力（dyne/cm）：25.9 5、 极化率（10-24cm3）：18.81 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:1 4.可旋转化学键数量:6 5.互变异构体数量:无 6.拓扑分子极性表面积3.2 7.重原子数量:10 8.表面电荷:0 9.复杂度:53.7 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：无色液体 2. 密度（g/mL,25/4℃）：0.745 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC,5.2kPa）：49-51 7. 折射率：n20/D 1.4178 8. 闪点（ºC）：42.2 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 10 22 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Flammable. Harmful if swallowed. Causes burns. Potential Health Effects Eye: Causes eye burns. Skin: Causes skin burns. Ingestion: Harmful if swallowed. Causes gastrointestinal tract burns. Inhalation: Causes chemical burns to the respiratory tract. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Flammable liquid and vapor. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition. Use a spark-proof tool. Section 7 - HANDLING and STORAGE Handling: Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Flammables-area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 3405-45-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 49 - 51 deg C @ 10. Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: 42 deg C ( 107.60 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: .7450g/cm3 Molecular Formula: (CH3CH2CH2CH2)2NCH3 Molecular Weight: 143.31 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials, ignition sources. Incompatibilities with Other Materials: Strong oxidizing agents, strong acids. Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 3405-45-6: HR8225000 LD50/LC50: CAS# 3405-45-6: Oral, rat: LD50 = 540 uL/kg; Skin, rabbit: LD50 = 880 uL/kg. Carcinogenicity: N-Methyldibutylamine - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S.* Hazard Class: 8 (3) UN Number: 2734 Packing Group: II IMO Shipping Name: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. Hazard Class: 8 (3) UN Number: 2734 Packing Group: II RID/ADR Shipping Name: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. Hazard Class: 8 (3) UN Number: 2734 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 10 Flammable. R 22 Harmful if swallowed. R 34 Causes burns. Safety Phrases: S 16 Keep away from sources of ignition - No smoking. S 25 Avoid contact with eyes. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 3405-45-6: No information available. Canada CAS# 3405-45-6 is listed on Canada's NDSL List. CAS# 3405-45-6 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 3405-45-6 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
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毒理学数据: 急性毒性： 大鼠口经LD50：540uL/kg； 大鼠吸入LCLo： 250 ppm/4H； 兔子皮肤注射LD50：880uL/kg。 生态学数据: 该物质对环境可能有危害，对水体应给予特别注意
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATA
|
| 符号 |
GHS02, GHS05, GHS06 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H226-H302 + H332-H311-H314 |
| 警示性声明 | P280-P305 + P351 + P338-P310 |
| 个人防护装备 | Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| 危害码 (欧洲) | C,F,Xi |
| 风险声明 (欧洲) | R10 |
| 安全声明 (欧洲) | S16;S26;S27;S45;S36/S37/S39 |
| 危险品运输编码 | UN 2734 8/PG 2 |
| RTECS号 | HR8225000 |
| 包装等级 | II |
| 海关编码 | 2921199090 |
| 上游产品 10 | |
|---|---|
| 下游产品 10 | |
| 海关编码 | 2921199090 |
|---|---|
| 中文概述 | 2921199090 其他无环单胺及其衍生物及其盐。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2921199090 other acyclic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0% |
