3124-01-4

• 常用中文名：六苯基二铅
• 常用英文名：Diplumbane,1,1,1,2,2,2-hexaphenyl-
• CAS号：3124-01-4
• 分子式：C₃₆H₃₀Pb₂
• 分子量：877.02300
• 发布时间：2018-09-02 21:06:45
• 更新时间：2024-01-03 16:36:28

名称

• 中文名: 六苯基二铅
• 英文名: triphenyllead
• 英文别名: Diplumbane,hexaphenyl; Dilead,hexaphenyl; Hexaphenyldiblei; hexaphenylphenyldilead; MFCD00014066; Hexaphenyldilead; Hexaphenyldiplumban; Lead,hexaphenyldi; EINECS 221-505-4; Hexaphenyldilead(IV); hexaphenyldiplumbane

物化性质

• 熔点: 149-151ºC
• 分子式: C₃₆H₃₀Pb₂
• 分子量: 877.02300
• 精确质量: 878.18800
• LogP: 8.15920
• 储存条件:

  密闭于阴凉干燥环境中

• 稳定性:

  遵照规定使用和储存则不会分解。

• 分子结构:

  1、摩尔折射率：无可用

  2、 摩尔体积（cm³/mol）：无可用

  3、 等张比容（90.2K）：无可用

  4、 表面张力（dyne/cm）：无可用

  5、 极化率：无可用

• 计算化学:

  1、 疏水参数计算参考值（XlogP）：无可用

  2、 氢键供体数量：0

  3、 氢键受体数量：0

  4、 可旋转化学键数量：6

  5、 拓扑分子极性表面积（TPSA）：0

  6、 重原子数量：38

  7、 表面电荷：0

  8、 复杂度：457

  9、 同位素原子数量：0

  10、 确定原子立构中心数量：0

  11、 不确定原子立构中心数量：0

  12、 确定化学键立构中心数量：0

  13、 不确定化学键立构中心数量：0

  14、 共价键单元数量：2

• 更多:

  1. 性状：无可用

  2. 密度（g/mL,25/4℃）：无可用

  3. 相对蒸汽密度（g/mL,空气=1）：无可用

  4. 熔点（ºC）：175

  5. 沸点（ºC,常压）：无可用

  6. 沸点（ºC,5.2kPa）：无可用

  7. 折射率：无可用

  8. 闪点（ºC）：无可用

  9. 比旋光度（º）：无可用

  10. 自燃点或引燃温度（ºC）：无可用

  11. 蒸气压（kPa,25ºC）：无可用

  12. 饱和蒸气压（kPa,60ºC）：无可用

  13. 燃烧热（KJ/mol）：无可用

  14. 临界温度（ºC）：无可用

  15. 临界压力（KPa）：无可用

  16. 油水（辛醇/水）分配系数的对数值：无可用

  17. 爆炸上限（%,V/V）：无可用

  18. 爆炸下限（%,V/V）：无可用

  19. 溶解性：无可用

MSDS

Section 1: Product Identification Chemical Name:Hexaphenyldilead, min. 98% CAS Registry Number:3124-01-4 Formula:(C6H5)3PbPb(C6H5)3 EINECS Number:221-505-4 Chemical Family:organolead compound Synonym:Diplumbane, hexaphenyl- Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound3124-01-4100%0.05mg/m3 (as Pb)0.05mg/m3 (as Pb) Section 3: Hazards Identification Harmful by inhalation and if swallowed. Possible risk of impaired fertility and harm to the unborn child. Emergency Overview: Possible risk of irreversible effects. May cause cancer. Primary Routes of Exposure:Ingestion, skin, inhalation of dust. Eye Contact:May cause slight to mild irritation of the eyes. Skin Contact:May cause slight to mild irritation of the skin. May cause sensitization by skin contact. Harmful by inhalation. Large dust exposure may cause encephalopathy, seizures, coma and cardiorespiratory Inhalation: distress. Harmful if swallowed. Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, metallic Ingestion: tast, weakness and convulsions. Acute Health Affects:Harmful by inhalation and if swallowed. Possible risk of harm to the unborn child. The chronic effects of lead poisoning include diarrhea, loss of appetite, muscle pain, headache, dizziness, Chronic Health Affects: anemia, brain damage, and reproductive disorders. Possible risk of impaired fertility and irreversible effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:carbon dioxide or dry powder. Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus Special Fire Fighting Procedures: and full protective clothing. Hazardous Combustion andCombustible. If involved in a fire this material may emit toxic lead oxide dust. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Handling and Storage:Store material in a cool dry place in a tightly sealed container. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. Ventilation:Handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:white xtl. Molecular Weight:877.04 Melting Point:170° dec. Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:oxidizing agents Decomposition Products:carbon monoxide, carbon dioxide, lead salts, and organic fumes. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:Carcinogen (as Pb) Mutagenic Effects:Possible mutagen Tetratogenic Effects:Possible reproductive effector SECTION 12: Ecological Information Avoid release to the environment. Very toxic to aquatic organisms. May cause long-term adverse effects in the Ecological Information: aquatic environment. SECTION 13: Disposal Considerations Disposal:Dispose of according to federal, state, and local regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Listed in the TSCA inventory. SARA (Title 313):Title compound: See category N420 for reporting. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。

安全

• 危害码 (欧洲): T: Toxic;
• 风险声明 (欧洲): 60-20/21/22-33
• 安全声明 (欧洲): 53-36/37/39-45
• 危险品运输编码: UN 3282
• 包装等级: III
• 危险类别: 6.1
• 海关编码: 2902909090

合成路线

27810-47-5 1802-69-3 ~27% 3124-01-4

文献：Journal of Organometallic Chemistry, , vol. 293, p. 323 - 342

1153-06-6 ~% 3124-01-4

文献：Journal of the American Chemical Society, , vol. 61, p. 1685

595-89-1 ~% 3124-01-4

文献：Journal of the American Chemical Society, , vol. 61, p. 1685

591-51-5 ~% 3124-01-4

文献：Journal of Organic Chemistry, , vol. 24, p. 1222,1225

上下游产品

上游产品  5
27810-47-5 1802-69-3 1153-06-6 595-89-1
591-51-5
下游产品  10
595-89-1 2117-69-3 3910-39-2 2654-42-4
24925-18-6 16002-63-4 27980-18-3 591-51-5
15590-75-7 15590-77-9

海关

海关编码	2902909090
中文概述	2902909090. 其他芳香烃. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:2.0%. 普通关税:30.0%
申报要素	品名, 成分含量
Summary	2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%