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1.吗啉类杀菌剂，兼有保护、治疗和内吸作用，残效长，对作物无药害，用于防治大麦、小麦的白粉病，小麦叶锈病、条锈病，黄瓜、马铃薯、橡胶、豌豆的白粉病。
2.用作医药中间体
| 中文名 | 异十三吗啉 |
|---|---|
| 英文名 | Tridemorph |
| 中文别名 |
三缩吗吩醇
克啉菌 2,6-二甲基十三烷基吗啉 克啉菌,三缩吗吩醇 |
| 英文别名 |
TRIDEMORPN
2,6-Dimethyl-N-tridecylmorpholine N-Tridecyl-2,6-dimethylmorpholine bas2205-f e-236 BAFS 220F Morpholine, 2,6-dimethyl-4-tridecyl- Basf 220f CALAXIN 2,6-Dimethyl-4-tridecyltetrahydro-1,4-oxazine MFCD00055522 Calixine 2,6-Dimethyl-4-tridecylmorpholine EINECS 246-347-3 Kalinin 2,6-dimethyl-4-tridecyl-morpholine 2,6-dimethyl-N-tridecyl-morpholine CALIXIN |
| 密度 | 0.9±0.1 g/cm3 |
|---|---|
| 沸点 | 371.3±17.0 °C at 760 mmHg |
| 分子式 | C19H39NO |
| 分子量 | 297.519 |
| 闪点 | 109.5±23.3 °C |
| 精确质量 | 297.303162 |
| PSA | 12.47000 |
| LogP | 7.03 |
| 蒸汽压 | 0.0±0.8 mmHg at 25°C |
| 折射率 | 1.449 |
| 储存条件 | 库房通风低温干燥; 与食品原料分开储运 |
| 稳定性 | 纯品为无色油状液体，略有氨味。b.p.134℃/66.65Pa、 130～131℃/22.7Pa，蒸气压 1.27×10-2Pa (20℃)。能溶于丙酮、氯仿、苯、乙醇等有机溶剂，常温下在水中溶解度为0.01%。常温下贮存稳定。 |
| 分子结构 | 1、 摩尔折射率：93.32 2、 摩尔体积（cm3/mol）：347.6 3、 等张比容（90.2K）：804.2 4、 表面张力（dyne/cm）：28.6 5、 极化率（10-24cm3）：36.99 |
| 更多 | 1. 性状：无色油状液体，略有氨味。 2. 密度（g/mL,20℃）：不确定 3. 相对蒸汽密度（g/mL,空气=1）：不确定 4. 熔点（ºC）：134 5. 沸点（ºC）：不确定 6. 折射率：不确定 7. 闪点（ºC）：不确定 8. 比旋光度（ºC）：不确定 9. 自燃点或引燃温度（ºC）不确定 10. 蒸气压（kPa,25ºC）：1.27×10-2 11. 饱和蒸气压（kPa,60ºC）：不确定 12. 燃烧热（KJ/mol）：不确定 13. 临界温度（ºC）：不确定 14. 临界压力（KPa）：不确定 15. 油水（辛醇/水）分配系数的对数值：不确定 16. 爆炸上限（%,V/V）：不确定 17. 爆炸下限（%,V/V）：不确定 18. 溶解性：能溶于丙酮、氯仿、苯、乙醇等有机溶剂。 |
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Section1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE Product identifiers Product name: Tridemorph CAS-No.: 24602-86-6 Relevant identified uses of the substance or mixture and uses advised against Identified uses: Laboratory chemicals, Manufacture of substances Section2. HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Reproductive toxicity (Category 1B) Acute toxicity, Inhalation (Category 4) Acute toxicity, Oral (Category 4) Skin irritation (Category 2) Acute aquatic toxicity (Category 1) Chronic aquatic toxicity (Category 1) Classification according to EU Directives 67/548/EEC or 1999/45/EC May cause harm to the unborn child. Harmful by inhalation and if swallowed. Irritating to skin. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram Signal wordDanger Hazard statement(s) H315Causes skin irritation. H302Harmful if swallowed. H332Harmful if inhaled. H410Very toxic to aquatic life with long lasting effects. H360DMay damage the unborn child. Precautionary statement(s) P201Obtain special instructions before use. P273Avoid release to the environment. P308 + P313IF exposed or concerned: Get medical advice/ attention. P501Dispose of contents/ container to an approved waste disposal plant. Supplemental Hazardnone Statements According to European Directive 67/548/EEC as amended. Hazard symbol(s) R-phrase(s) R61May cause harm to the unborn child. R20/22Also harmful by inhalation and if swallowed. R38Irritating to skin. R50/53Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) S53Avoid exposure - obtain special instructions before use. S45In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S60This material and its container must be disposed of as hazardous waste. S61Avoid release to the environment. Refer to special instructions/ Safety data sheets. Restricted to professional users. Other hazards - none Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substances Formula: C19H39NO Molecular Weight: 297,52 g/mol ComponentConcentration Tridemorph CAS-No.24602-86-6- EC-No.246-347-3 Index-No.613-020-00-5 Section4. FIRST AID MEASURES Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed Indication of any immediate medical attention and special treatment needed no data available Section5. FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture Carbon oxides, nitrogen oxides (NOx) Carbon oxides, nitrogen oxides (NOx) Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information no data available Section6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. Reference to other sections For disposal see section 13. Section7. HANDLING AND STORAGE Precautions for safe handling Avoid exposure - obtain special instructions before use.Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Specific end uses no data available Section8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Section9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) AppearanceForm: liquid Colour: colourless b) Odourno data available c) Odour Thresholdno data available d) pHno data available e) Melting point/freezingno data available point f) Initial boiling point and 134 °C at 0,7 hPa boiling range g) Flash pointno data available h) Evaporation rateno data available i) Flammability (solid, gas) no data available j) Upper/lowerno data available flammability or explosive limits k) Vapour pressureno data available l) Vapour densityno data available m) Relative densityno data available n) Water solubilityinsoluble o) Partition coefficient: n- no data available octanol/water p) Autoignitionno data available temperature q) Decompositionno data available temperature r) Viscosityno data available s) Explosive propertiesno data available t) Oxidizing propertiesno data available Other safety information no data available Section10. STABILITY AND REACTIVITY Reactivity no data available Chemical stability no data available Possibility of hazardous reactions no data available Conditions to avoid no data available Incompatible materials Strong oxidizing agents Hazardous decomposition products Other decomposition products - no data available Section11. TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity LD50 Oral - rat - 650 mg/kg Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity IARC:No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity Presumed human reproductive toxicant Developmental Toxicity - rat - Oral Specific Developmental Abnormalities: Central nervous system. Specific Developmental Abnormalities: Urogenital system. Developmental Toxicity - rat - Oral Specific Developmental Abnormalities: Craniofacial (including nose and tongue). Developmental Toxicity - rat - Oral Specific Developmental Abnormalities: Cardiovascular (circulatory) system. Developmental Toxicity - rat - Oral Specific Developmental Abnormalities: Homeostasis Developmental Toxicity - mouse - Oral Specific Developmental Abnormalities: Craniofacial (including nose and tongue). Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects InhalationHarmful if inhaled. Causes respiratory tract irritation. Ingestion Harmful if swallowed. SkinMay be harmful if absorbed through skin. Causes skin irritation. Additional Information RTECS: QE2705000 Section12. ECOLOGICAL INFORMATION Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment no data available Other adverse effects Very toxic to aquatic life. Section13. DISPOSAL CONSIDERATIONS Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. Section14. TRANSPORT INFORMATION UN number ADR/RID: 3082IMDG: 3082IATA: 3082 UN proper shipping name ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Tridemorph) IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Tridemorph) IATA:Environmentally hazardous substance, liquid, n.o.s. (Tridemorph) Transport hazard class(es) ADR/RID: 9IMDG: 9IATA: 9 Packaging group ADR/RID: IIIIMDG: IIIIATA: III Environmental hazards ADR/RID: yesIMDG Marine pollutant: yesIATA: yes Special precautions for user Further information EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids. Section15. REGULATORY INFORMATION This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. Safety, health and environmental regulations/legislation specific for the substance or mixture no data available Chemical Safety Assessment no data available Section16. OTHER INFORMATION Further information Copyright 2012 Co. LLC. License granted to make unlimited paper copies for internal use only. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Corporation and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. See and/or the reverse side of invoice or packing slip for additional terms and conditions of sale. |
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毒理学数据: 大鼠急性经口LD50>1000mg/kg（558mg/kg，原油），兔急性经口LD50750mg/kg。大鼠急性经皮LD50>4000mg/kg，急性吸入LC504.5mg/L。大鼠亚慢性无作用剂量为50mg/kg，狗为800mg/kg。大鼠慢性无作用剂量为80mg/kg，小鼠为90mg/kg。将大鼠置于十三吗啉饱和的空气，8h后未见死亡。大剂量（220L/kg)有致畸和繁殖毒性，低剂量（24L/kg)无影响。没有致突变和致癌作用。
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATA
|
| 符号 |
GHS07, GHS08, GHS09 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H302-H315-H332-H360D-H410 |
| 警示性声明 | P201-P273-P308 + P313-P501 |
| 个人防护装备 | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| 危害码 (欧洲) | T:Toxic; N:Dangerous for the environment; |
| 风险声明 (欧洲) | R20/22;R38;R50/53;R61 |
| 安全声明 (欧洲) | S45-S53-S60-S61 |
| 危险品运输编码 | UN 3082 |
| RTECS号 | QE2705000 |
| 包装等级 | III |
| 危险类别 | 6.1(b) |
| 海关编码 | 2934999035 |
| 海关编码 | 2934999035 |
|---|---|
| 中文概述 | 2934999035 十二环吗啉,十三吗啉。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:20.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| 监管条件 | S.进出口农药登记证明 |
| Summary | 2934999035 2,6-dimethyl-4-tridecylmorpholine。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:20.0% |