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| 中文名 | (R)-1-[(S)-2-( 二环己基膦基)二茂铁基]乙基二环己基膦 |
|---|---|
| 英文名 | (r)-1-[(1s)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine |
| 中文别名 | (1R)-1-(二环己基膦)-2-[(1R)-1-(二环己基膦)乙基]二茂铁 |
| 英文别名 |
MFCD01074441
(1R)-1-(Dicyclohexylphosphino)-2-[(1R)-1-(dicyclohexylphosphino)ethyl]ferrocene Iron(2+) 2,4-cyclopentadienide 2-(dicyclohexylphosphino)-1-[(1R)-1-(dicyclohexylphosphino)ethyl]-2,4-cyclopentadienide (1:1:1) (R)-(-)-1-[(S)-2-Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine cyclopentane,dicyclohexyl-[(1R)-1-(2-dicyclohexylphosphanylcyclopentyl)ethyl]phosphane,iron |
| 分子式 | C36H56FeP2 |
|---|---|
| 分子量 | 606.622 |
| 精确质量 | 606.320679 |
| PSA | 27.18000 |
| LogP | 11.13510 |
| 储存条件 | 保存方法：干燥、阴凉、密闭惰性气体的环境中 |
| 稳定性 | 避避氧化剂、空气 |
| 更多 | 1. 性状：固体 2. 密度（g/mL）：未确定 3. 相对蒸汽密度（g/mL,空气=1）未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC15mmHg）：未确定 7. 折射率：未确定 8. 闪点（ºF）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
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Section 1: Product Identification Chemical Name:(R)-(-)-1- (S)-2-(Dicylclohexylphosphino)ferrocenyl ethyldicyclohexylphosphine, min. 97% CAS Registry Number:167416-28-6 Formula:C36H56FeP2 EINECS Number:None Chemical Family:organophosphine ligand Synonym:[(S)-1-(R)-(-)-2(Dicyclohexylphosphanylethyl)dicyclohexyl phosphanylferrocene
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound167416-28-6100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and mucous membranes. May be harmful if swallowed. Primary Routes of Exposure:Ingestion, eyes Eye Contact:Causes slight to mild irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion:No information available on the physiological effects of ingestion. Acute Health Affects:Irritating to skin, eyes and respiratory tract. The toxicological properties of this compound have not been thoroughly investigated. Unrecognized hazards Chronic Health Affects: may be present. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self- contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes and vapors of phosphorus pentoxide. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Keep material in a tightly sealed container. Prolonged exposure to the air will result in degradation of the Handling and Storage: product. Handle and store material under an inert atmosphere of nitrogen or argon. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:orange powder Molecular Weight:606.64 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:Insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:exposure to oxygen, contact with strong oxidizing agents Incompatibility:Oxidizing agents and halogens Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, phosphorus oxides, and iron oxide. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data Mutagenic Effects:No data Tetratogenic Effects:No data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:None SECTION 16 - ADDITIONAL INFORMATION N/A |