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| 中文名 | 2-硝基-Alpha,Alpha,Alpha-三氟甲苯 |
|---|---|
| 英文名 | 2-Nitrobenzotrifluoride |
| 中文别名 |
2-硝基三氟甲苯
2-硝基三氟甲基苯 邻硝基三氟甲苯 |
| 英文别名 |
Benzene, 1-nitro-2-(trifluoromethyl)-
α,α,α-Trifluoronitrotoluene 2-Nitro-α,α,α-trifluorotoluene 1-Nitro-2-trifluoromethyl-benzene 1-Nitro-2-(trifluoromethyl)benzene MFCD00007145 EINECS 206-855-8 |
| 密度 | 1.4±0.1 g/cm3 |
|---|---|
| 沸点 | 217.4±0.0 °C at 760 mmHg |
| 熔点 | 32ºC |
| 分子式 | C7H4F3NO2 |
| 分子量 | 191.107 |
| 闪点 | 95.6±0.0 °C |
| 精确质量 | 191.019409 |
| PSA | 45.82000 |
| LogP | 2.58 |
| 外观性状 | 黄色晶体 |
| 蒸汽压 | 0.2±0.4 mmHg at 25°C |
| 折射率 | 1.473 |
| 水溶解性 | insoluble |
Synonym:2-Nitrobenzotrifluorid Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 22 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes, respiratory system and skin. Potential Health Effects The toxicological properties of this material have not been investigated. Use appropriate procedures to prevent opportunities for direct contact with the skin or eyes and to prevent inhalation. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Sweep up, then place into a suitable container for disposal. Section 7 - HANDLING and STORAGE Handling: Not available. Storage: Not available. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits CAS# 384-22-5: United States OSHA: 2.5 mg/m3 TWA (as F) (listed under Fluorides Personal Protective Equipment Eyes: Wear safety glasses and chemical goggles if splashing is possible. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Respirators: Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: colorless Odor: None reported. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 104.0 - 105.0 deg C @ 20.00mm Freezing/Melting Point: 31.00 - 32.00 deg C Autoignition Temperature: Not available. Flash Point: 95 deg C ( 203.00 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C7H4F3NO2 Molecular Weight: 191.11 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Not available. Incompatibilities with Other Materials: Strong oxidizing agents - strong bases - strong reducing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride gas, nitrogen. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 384-22-5 unlisted. LD50/LC50: Not available. Carcinogenicity: 2-Nitro-_,_,_-trifluorotoluene, 99% - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: NITROBENZOTRIFLUORIDES Hazard Class: 6.1 UN Number: 2306 Packing Group: II IMO Shipping Name: NITROBENZOTRIFLUORIDES, LIQUID or SOLID Hazard Class: 6.1 UN Number: 2306 Packing Group: II RID/ADR Shipping Name: NITROBENZOTRIFLUORIDES Hazard Class: 6.1 UN Number: 2306 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 22 Harmful if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 384-22-5: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 384-22-5 is listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 384-22-5 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 危害码 (欧洲) | Xn:Harmful; |
|---|---|
| 风险声明 (欧洲) | R22;R36/37/38 |
| 安全声明 (欧洲) | S24/25 |
| 危险品运输编码 | UN 2306 |
| RTECS号 | XT3480000 |
| 包装等级 | III |
| 危险类别 | 6.1(b) |
| 海关编码 | 2904909090 |
| 上游产品 10 | |
|---|---|
| 下游产品 10 | |
| 海关编码 | 2904909090 |
|---|---|
| 中文概述 | 2904909090 其他烃的磺化、硝化、亚硝化衍生物（不论是否卤化）. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0% |
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