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| 中文名 | 3,5-二溴苄基溴 |
|---|---|
| 英文名 | 3,5-Dibromobenzyl bromide |
| 中文别名 |
3,5-二溴溴苄
3,5-二溴苄溴 α,3,5-三溴甲苯 |
| 英文别名 |
Benzene, 1,3-dibromo-5-(bromomethyl)-
MFCD00052415 1,3-Dibromo-5-(bromomethyl)benzene |
| 密度 | 2.2±0.1 g/cm3 |
|---|---|
| 沸点 | 316.5±27.0 °C at 760 mmHg |
| 熔点 | 93-97 °C |
| 分子式 | C7H5Br3 |
| 分子量 | 328.827 |
| 闪点 | 142.2±18.5 °C |
| 精确质量 | 325.794128 |
| LogP | 4.42 |
| 外观性状 | 白色至米色-褐色粉末 |
| 蒸汽压 | 0.0±0.6 mmHg at 25°C |
| 折射率 | 1.637 |
| 储存条件 | 保持贮藏器密封、储存在阴凉、干燥的地方，确保工作间有良好的通风或排气装置 |
| 稳定性 | 如果遵照规格使用和储存则不会分解，未有已知危险反应 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:3.9 2.氢键供体数量:0 3.氢键受体数量:0 4.可旋转化学键数量:1 5.互变异构体数量:无 6.拓扑分子极性表面积0 7.重原子数量:10 8.表面电荷:0 9.复杂度:95 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：固体 2. 密度（g/mL,15ºC）：未确定 3. 相对蒸汽密度（g/mL,空气=1）： 未确定 4. 熔点（ºC）：88-90 5. 沸点（ºC）：未确定 6. 沸点（ºC，10mmHg）：未确定 7. 折射率：未确定 8. 闪点（°F）：未确定 9. 比旋光度（ºC）：未确定 10. 自燃点或引燃温度（ºC）： 未确定 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
Synonym:alpha,3,5-Tribromobenzyl bromide; 1,3-Dibromo-5-(bromomethyl)benzen Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 11 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Highly flammable. Causes burns. Potential Health Effects Eye: Causes eye burns. Lachrymator (substance which increases the flow of tears). Skin: Causes skin burns. Ingestion: Causes gastrointestinal tract burns. Inhalation: Causes chemical burns to the respiratory tract. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Flammable solid. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Remove all sources of ignition. Use a spark-proof tool. Section 7 - HANDLING and STORAGE Handling: Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Storage: Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Flammables-area. Corrosives area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels. Exposure Limits CAS# 56908-88-4: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: white crystalline solid Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 88 - 90 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C7H5Br3 Molecular Weight: 329 Section 10 - STABILITY AND REACTIVITY Chemical Stability: No information found. Conditions to Avoid: Incompatible materials, exposure to moist air or water. Incompatibilities with Other Materials: Water, oxidizing agents, bases, alcohols, amines, steel. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, hydrogen bromide, bromine. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 56908-88-4 unlisted. LD50/LC50: Not available. Carcinogenicity: 3,5-Dibromobenzyl bromide - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. Hazard Class: 8 UN Number: 3261 Packing Group: II IMO Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. Hazard Class: 8 UN Number: 3261 Packing Group: II RID/ADR Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. Hazard Class: 8 UN Number: 3261 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: F C Risk Phrases: R 11 Highly flammable. R 34 Causes burns. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 56908-88-4: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 56908-88-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 56908-88-4 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 对水是稍微有危害的不要让未稀释或大量的产品接触地下水、水道或者污水系统，若无政府许可，勿将材料排入周围环境
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| 危害码 (欧洲) | F:Flammable;C:Corrosive; |
|---|---|
| 风险声明 (欧洲) | R11;R34 |
| 安全声明 (欧洲) | S45-S36/37/39-S26 |
| 危险品运输编码 | 1759 |
| 包装等级 | III |
| 危险类别 | 8 |
| 海关编码 | 2903999090 |
|
~99%
56908-88-4 |
| 文献：Urbani, Maxence; Ohkubo, Kei; Islam, D. M. Shafiqul; Fukuzumi, Shunichi; Langa, Fernando Chemistry - A European Journal, 2012 , vol. 18, # 24 p. 7473 - 7485 |
|
~47%
56908-88-4 |
| 文献：Pola Chemical Industries, Inc. Patent: US6586633 B1, 2003 ; |
|
~93%
56908-88-4 |
| 文献：Liu, Simin; Whisenhunt-Ioup, Sarah E.; Gibb, Corinne L. D.; Gibb, Bruce C. Supramolecular Chemistry, 2011 , vol. 23, # 6 p. 480 - 485 |
|
~54%
56908-88-4 |
| 文献：Diez-Barra; Garcia-Martinez; Merino; Del Rey; Rodriguez-Lopez; Sanchez-Verdu; Tejeda Journal of Organic Chemistry, 2001 , vol. 66, # 17 p. 5664 - 5670 |
| 上游产品 3 | |
|---|---|
| 下游产品 3 | |
| 海关编码 | 2903999090 |
|---|---|
| 中文概述 | 2903999090 其他芳烃卤化衍生物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0% |
