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138687-69-1生产厂家

138687-69-1价格

138687-69-1

138687-69-1结构式
138687-69-1结构式

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中文名 五氟苯基二苯基磷酸酯
英文名 1-diphenylphosphoryloxy-2,3,4,5,6-pentafluorobenzene
中文别名 五氟苯基二苯基膦酸酯
英文别名 Phosphinic acid, P,P-diphenyl-, 2,3,4,5,6-pentafluorophenyl ester
diphenyl-phosphinic acid pentafluorophenyl ester
Pentafluorophenyl diphenylphosphinate
Diphenylphosphinic acid pentafluorophenyl ester
密度 1.5±0.1 g/cm3
沸点 413.1±55.0 °C at 760 mmHg
熔点 47-50ºC(lit.)
分子式 C18H10F5O2P
分子量 384.237
闪点 203.6±31.5 °C
精确质量 384.033844
PSA 36.11000
LogP 4.56
蒸汽压 0.0±0.9 mmHg at 25°C
折射率 1.556
储存条件 室温,干燥

Section1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
Product name: Pentafluorophenyl diphenylphosphinate

Section2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Not a dangerous substance according to GHS.
This substance is not classified as dangerous according to Directive 67/548/EEC.
Label elements
Caution - substance not yet tested completely.
Other hazards - none

Section3. COMPOSITION/INFORMATION ON INGREDIENTS
Formula: C18H10F5O2P
Molecular Weight: 384,24 g/mol
CAS-No.EC-No.Index-No.ClassificationConcentration
Pentafluorophenyl diphenylphosphinate
138687-69-1----

Section4. FIRST AID MEASURES
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
In case of skin contact
Wash off with soap and plenty of water.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water.

Section5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special protective equipment for fire-fighters
Wear self contained breathing apparatus for fire fighting if necessary.

Section6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Avoid dust formation. Avoid breathing vapors, mist or gas.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Sweep up and shovel. Keep in suitable, closed containers for disposal.

Section7. HANDLING AND STORAGE
Precautions for safe handling
Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire
protection.
Conditions for safe storage
Keep container tightly closed in a dry and well-ventilated place. Store in cool place.

Section8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Personal protective equipment
Respiratory protection
Respiratory protection is not required. Where protection from nuisance levels of dusts are desired, use
type N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and approved
under appropriate government standards such as NIOSH (US) or CEN (EU).
Hand protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without
touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves
after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the
standard EN 374 derived from it.
Eye protection
Use equipment for eye protection tested and approved under appropriate government standards such as
NIOSH (US) or EN 166(EU).
Skin and body protection
Choose body protection in relation to its type, to the concentration and amount of dangerous substances,
and to the specific work-place., The type of protective equipment must be selected according to the
concentration and amount of the dangerous substance at the specific workplace.
Hygiene measures
General industrial hygiene practice.

Section9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Formsolid
Safety data
pH no data available
Melting point47 - 50 °C - lit.
Boiling pointno data available
Flash pointno data available
Ignition temperatureno data available
Lower explosion limitno data available
Upper explosion limitno data available
Water solubilityno data available

Section10. STABILITY AND REACTIVITY
Chemical stability
Stable under recommended storage conditions.
Conditions to avoid
no data available
Materials to avoid
Strong oxidizing agents
Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides, Hydrogen fluoride

Section11. TOXICOLOGICAL INFORMATION
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
InhalationMay be harmful if inhaled. May cause respiratory tract irritation.
IngestionMay be harmful if swallowed.
SkinMay be harmful if absorbed through skin. May cause skin irritation.
EyesMay cause eye irritation.
Additional Information
RTECS: no data available

Section12. ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
PBT and vPvB assessment
no data available
Other adverse effects
no data available

Section13. DISPOSAL CONSIDERATIONS
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.

Section14. TRANSPORT INFORMATION
ADR/RID
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods



SECTION 15 - REGULATORY INFORMATION
N/A


SECTION 16 - ADDITIONAL INFORMATION
N/A
个人防护装备 Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
安全声明 (欧洲) 24/25
危险品运输编码 NONH for all modes of transport
WGK德国 3
海关编码 29319090

~97%

138687-69-1结构式

138687-69-1

文献:Chen, Shaoqing; Xu, Jiecheng Tetrahedron Letters, 1991 , vol. 32, # 46 p. 6711 - 6714