99-67-2

• 常用中文名：2-甲基戊-4-烯酸
• 常用英文名：2-Allyl-4-Pentenoic acid
• CAS号：99-67-2
• 分子式：C₈H₁₂O₂
• 分子量：140.180
• 相关类别： 原料药 Anesthetic Agents Local anesthetics
• 发布时间：2018-09-12 18:38:34
• 更新时间：2024-01-05 12:34:57
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名称

• 中文名: 丙戊酸相关物质A
• 英文名: 2-allyl-4-pentenoic acid
• 中文别名: 1,6-庚二烯-4-羧酸
• 英文别名: Di-2-propenylacetic acid; prop-2-enyl pent-4-enoate; 4-Pentenoic acid, 2-(2-propen-1-yl)-; 2-prop-2-enylpent-4-enoic acid; 2-Allyl-4-pentenoic acid; 2-(2-Propenyl)-4-pentenoic acid; 2-allyl-4-pentenoicaci; bis-allyl acetic acid; 2-PROPENE-PENT-4-ENOICACID; pent-4-enoic acid allyl ester; 2-allylpent-4-enoic acid; 4-PENTENOICACID,2-ALLYL; diallylacetic acid; Diallyl-acetic acid

物化性质

• 密度: 1.0±0.1 g/cm3
• 沸点: 237.1±9.0 °C at 760 mmHg
• 熔点: 48ºC
• 分子式: C₈H₁₂O₂
• 分子量: 140.180
• 闪点: 134.4±13.9 °C
• 精确质量: 140.083725
• PSA: 37.30000
• LogP: 2.22
• 蒸汽压: 0.0±1.0 mmHg at 25°C
• 折射率: 1.462
• 储存条件: 2-8°C

毒性和生态

CHEMICAL IDENTIFICATION RTECS NUMBER : SB2890000 CHEMICAL NAME : 4-Pentenoic acid, 2-allyl- CAS REGISTRY NUMBER : 99-67-2 BEILSTEIN REFERENCE NO. : 1702223 LAST UPDATED : 199709 DATA ITEMS CITED : 2 MOLECULAR FORMULA : C8-H12-O2 MOLECULAR WEIGHT : 140.20 WISWESSER LINE NOTATION : 1U2YVQ2U1 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 570 mg/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) Nutritional and Gross Metabolic - weight loss or decreased weight gain REFERENCE : FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 2,327,1964 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 630 mg/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) Behavioral - food intake (animal) Skin and Appendages - hair REFERENCE : FEPRA7 Federation Proceedings, Federation of American Societies for Experimental Biology. (Bethesda, MD) V.1-46, 1942-87. Volume(issue)/page/year: 8,299,1949

安全

• 符号: GHS07
• 信号词: Warning
• 危害声明: H302
• 警示性声明: P301 + P312 + P330
• 危害码 (欧洲): Xn
• 风险声明 (欧洲): 22
• 危险品运输编码: NONH for all modes of transport
• 海关编码: 2916190090

合成路线

4372-31-0 ~99% 99-67-2

文献：Liu, Huili; Zheng, Kuan; Lu, Xiang; Wang, Xiaoxia; Hong, Ran Beilstein Journal of Organic Chemistry, 2013 , vol. 9, p. 983 - 990

3195-24-2 ~% 99-67-2

文献：Brace, Neal O. Journal of Fluorine Chemistry, 2005 , vol. 126, # 1 p. 7 - 15

18325-74-1 ~92% 99-67-2

文献：Beaulieu, Normand; Dickinson, Robert A.; Deslongchamps, Pierre Canadian Journal of Chemistry, 1980 , vol. 58, p. 2531 - 2536

2049-80-1 ~% 99-67-2

文献：Bouhadir, Kamal H.; Zhou, Jing-Lan; Shevlin, Philip B. Synthetic Communications, 2005 , vol. 35, # 7 p. 1003 - 1010

3508-77-8 ~% 99-67-2

文献：Wolff Chemische Berichte, 1877 , vol. 10, p. 1957 Justus Liebigs Annalen der Chemie, 1880 , vol. 201, p. 49 Full Text Show Details Reboul Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1877 , vol. 84, p. 1235 Bulletin de la Societe Chimique de France, 1878 , vol. <2>29, p. 228

3508-77-8 ~% 99-67-2 75265-80-4

文献：Wolff Justus Liebigs Annalen der Chemie, 1880 , vol. 201, p. 53

2049-80-1 106-95-6 ~% 99-67-2

文献：de Moura Campos,M.; do Amaral,L. Archiv der Pharmazie und Berichte der Deutschen Pharmazeutischen Gesellschaft, 1965 , vol. 298, # 2 p. 92 - 100

海关

海关编码	2916190090
中文概述	2916190090 其他不饱和无环一元羧酸（包括其酸酐、酰卤化物，过氧化物和过氧酸以及它们的衍生物）。监管条件:AB(入境货物通关单,出境货物通关单)。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%
申报要素	品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装
监管条件	A.入境货物通关单 B.出境货物通关单
检验检疫	R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验
Summary	2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%