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1.用做白色皮革鞣革剂，使皮革表面细腻、丰富并富有弹性，也作为制备锆化合物的原料，可用做润滑剂、催化剂载体等
2.硫酸锆可用作铝合金氧化添加剂或其他电镀添加物质。
| 中文名 | 硫酸锆四水合物 |
|---|---|
| 英文名 | Zirconium sulfate tetrahydrate |
| 中文别名 | 硫酸锆 四水 |
| 英文别名 |
EINECS 238-694-4
MFCD00149267 zirconium(4+),disulfate,tetrahydrate |
| 密度 | 3.22 |
|---|---|
| 熔点 | 410 °C |
| 分子式 | H8O12S2Zr |
| 分子量 | 355.41000 |
| 精确质量 | 353.85000 |
| PSA | 214.20000 |
| 外观性状 | 淡黄色白色粒状的粉末淡粉红色粉末 |
| 储存条件 | 1.密封于阴凉干燥环境。 2.远离火种、 热源。防止阳光直射. 3.应与氧化剂、 碱类分开存放，切忌混贮. |
| 稳定性 | 1.如果遵照规格使用和储存则不会分解。易溶于水并放出大量溶解热，水溶液呈酸性，硫酸锆水解成二氧化锆水合物(ZrO2·nH2O)，它为白色絮状凝胶并具有胶体特性；不溶于醇，随着溶液浓度的下降和pH值的增高，可形成碱式硫酸锆，还具有良好的填充性和耐磨性。 |
| 分子结构 | 1、摩尔折射率：无可用 2、 摩尔体积（cm3/mol）： 无可用 3、 等张比容（90.2K）：无可用 4、 表面张力（dyne/cm）：无可用 5、 极化率：无可用 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:4 3.氢键受体数量:12 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积181 7.重原子数量:15 8.表面电荷:0 9.复杂度:62.2 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:7 |
| 更多 | 1. 性状：六角板状结晶粉末. 2. 密度（g/mL,25/4℃）：2.8 3. 相对蒸汽密度（g/mL,空气=1）：无可用 4. 熔点（ºC）：410 5. 沸点（ºC,常压）：无可用 6. 沸点（ºC,5.2kPa）： 无可用 7. 折射率： 无可用 8. 闪点（ºC）： 无可用 9. 比旋光度（º）：无可用 10. 自燃点或引燃温度（ºC）：无可用 11. 蒸气压（kPa,25ºC）：无可用 12. 饱和蒸气压（kPa,60ºC）：无可用 13. 燃烧热（KJ/mol）：无可用 14. 临界温度（ºC）：无可用 15. 临界压力（KPa）：无可用 16. 油水（辛醇/水）分配系数的对数值：无可用 17. 爆炸上限（%,V/V）：无可用 18. 爆炸下限（%,V/V）： 无可用 19. 溶解性：溶于水吗，不溶于醇。 |
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Section 1: Product Identification Chemical Name:Zirconium (IV) sulfate tetrahydrate (99.99+%-Zr) PURATREM CAS Registry Number:7446-31-3 Formula:Zr(SO4)2.4H2O EINECS Number:238-694-4 Chemical Family:metal sulfate Synonym:Sulfuric acid, zirconium(4+) salt (2:1), Zirconium sulfate
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound7446-31-3100%5mg/m3 (as Zr)5mg/m3 (as Zr) Section 3: Hazards Identification Irritating to skin, eyes and respiratory tract. This material partially hydrolyzes in water to form dilute sulfuric Emergency Overview: acid, a strong irritant. Primary Routes of Exposure:Ingestion, inhalation, skin, eyes Eye Contact:Dust is a moderate to severe irritant to the eyes. Skin Contact:Causes irritation to skin. Symptoms include redness, itching, and pain. Inhalation:Inhalation of dust may irritate the respiratory tract. Symptoms may include coughing, shortness of breath. Ingestion:Ingestion may lead to nausea, vomiting and diarrhea. Acute Health Affects:Acidic behavior causes irritation of skin, eyes and respiratory and gastrointestinal tracts. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:none required If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained Special Fire Fighting Procedures: breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic fumes of sulfur oxides. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with powdered sodium carbonate or ground limestone and swept up. SECTION 7: Handling and Storage Handling and Storage:Store material in a tightly sealed bottle away from moisture. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear appropriate chemical resistant gloves and protective clothing. Ventilation:If possible, handle the material in an efficient fume hood. In the absence of adequate ventilation a respirator should be worn. The use of a respiratory requires a Respirator: Respirator Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:white xtl. Molecular Weight:283.33 (355.39) Melting Point:100°C (-3H2O) Boiling Point:no data Vapor Pressure:not applicable Specific Gravity:no data Odor:none Solubility in Water:soluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:Strong bases Decomposition Products:In water, dilute sulfuric acid SECTION 11: Toxicological Information Oral (rat); LD50: 3500 mg/kg. Intraperitoneal (rat); LD50: 175 mg/kg. Subcutaneous (rat); LDLo: 500 mg/kg. RTECS Data: Intratesticular (rat); TDLo: 22667 ug/kg. Mouse Lymphocyte; Unscheduled DNA synthesis: 20 umol/L. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。
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| 危害码 (欧洲) | Xi:Irritant; |
|---|---|
| 风险声明 (欧洲) | R36/37/38 |
| 安全声明 (欧洲) | S37/39-S26 |
1.共熔法以锆英石、纯碱、硫酸为原料制备硫酸锆：将锆英石精矿粉碎后和碳酸钠按比例混合，投入焙烧炉中，于1100～1200 ℃反应生成锆酸钠和硅酸钠，经焙烧的熟料用60 ℃温水洗涤，洗去过量的碱，过滤，于80～100 ℃温度下用硫酸酸溶滤饼，然后经蒸发、浓缩或补加浓硫酸、结晶、过滤分离，于180 ℃下干燥脱水制得。
