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| 中文名 | 2-[2-[4-(1,1,3,3-四甲基丁基)苯氧基]乙氧基]-乙醇 |
|---|---|
| 英文名 | 4-tert-Octylphenol Diethoxylate |
| 中文别名 | 2-{2-[4-(1,1,3,3-四甲基丁基)苯氧基]乙氧基}乙醇 |
| 英文别名 |
Ethanol, 2-[2-[4-(1,1,3,3-tetramethylbutyl)phenoxy]ethoxy]-
2-{2-[4-(2,4,4-Trimethyl-2-pentanyl)phenoxy]ethoxy}ethanol 2-{2-[4-(2,4,4-trimethylpentan-2-yl)phenoxy]ethoxy}ethanol 2-[2-[4-(2,4,4-trimethylpentan-2-yl)phenoxy]ethoxy]ethanol 2-{2-[4-(1,1,3,3-TETRAMETHYLBUTYL)PHENOXY]ETHOXY}ETHANOL |
| 密度 | 1.0±0.1 g/cm3 |
|---|---|
| 沸点 | 402.6±35.0 °C at 760 mmHg |
| 分子式 | C18H30O3 |
| 分子量 | 294.429 |
| 闪点 | 197.3±25.9 °C |
| 精确质量 | 294.219482 |
| PSA | 38.69000 |
| LogP | 4.53 |
| 蒸汽压 | 0.0±1.0 mmHg at 25°C |
| 折射率 | 1.493 |
| 储存条件 | ?20°C |
|
SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifiers Product name: 4-tert-Octylphenol diethoxylate solution REACH No.: A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.
CAS-No.: 2315-61-9 Relevant identified uses of the substance or mixture and uses advised against Identified uses: Laboratory chemicals, Manufacture of substances SECTION 2: Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Flammable liquids (Category 2), H225 Eye irritation (Category 2), H319 Specific target organ toxicity - single exposure (Category 3), H336 Chronic aquatic toxicity (Category 3), H412 For the full text of the H-Statements mentioned in this Section, see Section 16. Classification according to EU Directives 67/548/EEC or 1999/45/EC F Highly flammableR11 Xi IrritantR36 R66, R67 R52/53 For the full text of the R-phrases mentioned in this Section, see Section 16. Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal wordDanger Hazard statement(s) H225Highly flammable liquid and vapour. H319Causes serious eye irritation. H336May cause drowsiness or dizziness. H412Harmful to aquatic life with long lasting effects. Precautionary statement(s) P210Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P261Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P273Avoid release to the environment. P305 + P351 + P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Supplemental Hazard information (EU) EUH066Repeated exposure may cause skin dryness or cracking. According to European Directive 67/548/EEC as amended. Hazard symbol(s)F Highly flammable Xi Irritant R-phrase(s) R11Highly flammable. R36Irritating to eyes. R52/53Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R66Repeated exposure may cause skin dryness or cracking. R67Vapours may cause drowsiness and dizziness. S-phrase(s) S16Keep away from sources of ignition - No smoking. S26In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S61Avoid release to the environment. Refer to special instructions/ Safety data sheets. Other hazards - none SECTION 3: Composition/information on ingredients Mixtures Synonyms: 2-{2-[4-(1,1,3,3-Tetramethylbutyl)phenoxy]ethoxy}ethanol Formula: C18H30O3 C18H30O3 Molecular Weight: 294,43 g/mol Hazardous ingredients according to Regulation (EC) No 1272/2008 ComponentClassificationConcentration Acetone CAS-No.67-64-1Flam. Liq. 2; Eye Irrit. 2; STOT <= 100 % EC-No.200-662-2SE 3; H225, H319, H336, Index-No.606-001-00-8EUH066 4-tert-Octylphenol diethoxylate Included in the Candidate List of Substances of Very High Concern (SVHC) according to Regulation (EC) No. 1907/2006 (REACH) CAS-No.2315-61-9Skin Irrit. 2; Eye Irrit. 2; STOT 0,025 - 0,25 % SE 3; Aquatic Acute 1; Aquatic Chronic 1; H315, H319, H335, H410 Hazardous ingredients according to Directive 1999/45/EC ComponentClassificationConcentration Acetone CAS-No.67-64-1F, Xi, R11 - R36 - R66 - R67 <= 100 % EC-No.200-662-2 Index-No.606-001-00-8 4-tert-Octylphenol diethoxylate Included in the Candidate List of Substances of Very High Concern (SVHC) according to Regulation (EC) No. 1907/2006 (REACH) CAS-No.2315-61-9Xi, N, R36/37/38 - R50/530,025 - 0,25 % For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16 SECTION 4: First aid measures Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 Indication of any immediate medical attention and special treatment needed no data available SECTION 5: Firefighting measures Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture Carbon oxides Carbon oxides Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information Use water spray to cool unopened containers. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Reference to other sections For disposal see section 13. SECTION 7: Handling and storage Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature: -20 °C Specific end use(s) A part from the uses mentioned in section 1.2 no other specific uses are stipulated SECTION 8: Exposure controls/personal protection Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection impervious clothing, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties a) AppearanceForm: liquid, clear Colour: colourless b) Odourno data available c) Odour Thresholdno data available d) pHno data available e) Melting point/freezing-94,0 °C point f) Initial boiling point and 56,0 °C boiling range g) Flash point-17,0 °C - closed cup h) Evapouration rateno data available i) Flammability (solid, gas) no data available j) Upper/lowerUpper explosion limit: 13 %(V) flammability orLower explosion limit: 2 %(V) explosive limits k) Vapour pressure533,3 hPa at 39,5 °C 245,3 hPa at 20,0 °C l) Vapour densityno data available m) Relative density0,79 g/cm3 n) Water solubilitysoluble o) Partition coefficient: n- log Pow: -0,24 octanol/water p) Auto-ignition465,0 °C temperature q) Decompositionno data available temperature r) Viscosityno data available s) Explosive propertiesno data available t) Oxidizing propertiesno data available Other safety information no data available SECTION 10: Stability and reactivity Reactivity no data available Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions no data available Conditions to avoid Heat, flames and sparks. Extremes of temperature and direct sunlight. Incompatible materials Bases, Oxidizing agents, Reducing agents, Acetone reacts violently with phosphorous oxychloride. Hazardous decomposition products Other decomposition products - no data available In the event of fire: see section 5 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 Oral - rat - 5.800 mg/kg Remarks: Behavioral:Altered sleep time (including change in righting reflex). Behavioral:Tremor. LC50 Inhalation - rat - 8 h - 50.100 mg/m3 Inhalation: no data available LD50 Dermal - guinea pig - 7.426 mg/kg Skin corrosion/irritation Skin - rabbit Result: Mild skin irritation - 24 h Serious eye damage/eye irritation Eyes - rabbit Result: Eye irritation - 24 h Respiratory or skin sensitisation no data available Germ cell mutagenicity no data available Carcinogenicity This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA classification. IARC:No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure May cause drowsiness or dizziness. Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Additional Information RTECS: Not available To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Kidney - Irregularities - Based on Human Evidence SECTION 12: Ecological information Toxicity no data available Toxicity to daphnia andEC50 - Daphnia magna (Water flea) - 13.500,00 mg/l - 48 h other aquatic invertebrates Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted Other adverse effects Harmful to aquatic life with long lasting effects. no data available SECTION 13: Disposal considerations Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. SECTION 14: Transport information UN number ADR/RID: 1090IMDG: 1090IATA: 1090 UN proper shipping name ADR/RID: ACETONE, SOLUTION IMDG: ACETONE, SOLUTION IATA:Acetone, SOLUTION Transport hazard class(es) ADR/RID: 3IMDG: 3IATA: 3 Packaging group ADR/RID: IIIMDG: IIIATA: II Environmental hazards ADR/RID: noIMDG Marine pollutant: noIATA: no Special precautions for user no data available SECTION 15 - REGULATORY INFORMATION N/A SECTION 16 - ADDITIONAL INFORMATION N/A |
| 符号 |
GHS02, GHS07 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H225-H319-H336-H412 |
| 补充危害声明 | Repeated exposure may cause skin dryness or cracking. |
| 警示性声明 | P210-P261-P273-P305 + P351 + P338 |
| 个人防护装备 | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US) |
| 危害码 (欧洲) | F,Xi |
| 风险声明 (欧洲) | 11-36-52/53-66-67 |
| 安全声明 (欧洲) | 16-26-61-9 |
| 危险品运输编码 | UN1090 - class 3 - PG 2 - Acetone, solution |
| 海关编码 | 2909499000 |
| 上游产品 4 | |
|---|---|
| 下游产品 1 | |
| 海关编码 | 2909499000 |
|---|---|
| 中文概述 | 2909499000 其他醚醇及其卤化、磺化、硝化或亚硝化衍生物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2909499000. ether-alcohols and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:9.0%. . MFN tariff:5.5%. General tariff:30.0% |
![Ethanol, 2-[2-[2-[4-(1,1,3,3-tetramethylbutyl)phenoxy]ethoxy]ethoxy]-结构式](https://www.chemsrc.com/caspic/499/2315-62-0.png)