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| 中文名 | 三(6,6,7,7,8,8,8-七氟-2,2-二甲基-3,5-辛烷二酮 |
|---|---|
| 英文名 | Lanthanum tris[(heptafluorodimethyl)octanedione] |
| 英文别名 |
MFCD00798418
TRIS(HEPTAFLUORO-2,2-DIMETHYL-3,5-OCTANE-DIONATO)LANTHANUM Lanthanum(lll) 6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionate EINECS 242-822-4 resolve-al tm lafod LA(FOD)3 LANTHANUM 6,6,7,7,8,8,8-HEPTAFLUORO-2,2-DIMETHYL-3,5-OCTANEDIONATE TRIS(6,6,7,7,8,8,8-HEPTAFLUORO-2,2-DIMETHYL-3,5-OCTANEDIONATO)LANTHANUM LANTHANUM FOD Tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionate |
| 沸点 | 172.7ºC at 760mmHg |
|---|---|
| 分子式 | C30H33F21LaO6 |
| 分子量 | 1027.45000 |
| 闪点 | 75.5ºC |
| 精确质量 | 1027.10000 |
| PSA | 102.42000 |
| LogP | 10.18110 |
| 外观性状 | Powder | white |
| 蒸汽压 | 0.0812mmHg at 25°C |
| 计算化学 | 1、 氢键供体数量：6 2、 氢键受体数量：21 3、 可旋转化学键数量：9 4、 拓扑分子极性表面积（TPSA）：6 5、 重原子数量：58 6、 表面电荷：6 7、 复杂度：1310 8、 同位素原子数量：0 9、 确定原子立构中心数量：0 10、 不确定原子立构中心数量：0 11、 确定化学键立构中心数量：0 12、 不确定化学键立构中心数量：0 13、 共价键单元数量：4 |
| 更多 | 1. 性状：不确定 2. 密度（g/mL,25/4℃）：不确定 3. 相对蒸汽密度（g/mL,空气=1）：不确定 4. 熔点（ºC）：不确定 5. 沸点（ºC,常压）：不确定 6. 沸点（ºC, 5.2kPa）：不确定 7. 折射率：不确定 8. 闪点（ºC）：不确定 9. 比旋光度（º）：不确定 10. 自燃点或引燃温度（ºC）：不确定 11. 蒸气压（kPa,25ºC）：不确定 12. 饱和蒸气压（kPa,60ºC）：不确定 13. 燃烧热（KJ/mol）：不确定 14. 临界温度（ºC）：不确定 15. 临界压力（KPa）：不确定 16. 油水（辛醇/水）分配系数的对数值：不确定 17. 爆炸上限（%,V/V）：不确定 18. 爆炸下限（%,V/V）：不确定 19. 溶解性：不确定 |
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Section 1: Product Identification Tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionate)lanthanum (III), 99% (99.9%-La) (REO) Chemical Name: La(FOD)3 CAS Registry Number:19106-89-9 Formula:La(C3F7COCHCOC4H9)3 EINECS Number:242-822-4
Chemical Family:metal fluorobeta-diketonate complexes Synonym:tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyloctane-4,6- dionato-O,O')lanthanum Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound19106-89-9100%no datano data Section 3: Hazards Identification Emergency Overview:Dust may be irritating to eyes, skin and respiratory tract. Harmful if swallowed. Primary Routes of Exposure:Ingestion, inhalation Eye Contact:May cause slight to mild irritation of the eyes. Skin Contact:May cause slight to mild irritation of the skin. Inhalation:May cause irritation to the nose, mucous membranes and respiratory tract. Ingestion:No information available on the effects of ingestion. Acute Health Affects:May be irritating to skin, eyes and respiratory tract. Product contains fluorine which under certain conditions of use, decomposition, or metabolism, may generate Chronic Health Affects:fluoride ion, causing, nausea, vomiting, labored breathing, hypocalcaemia, deterioration of bone and tooth structure, kidney and liver damage. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in Inhalation: breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, dry powder or foam. If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic and corrosive fumes of hydrogen fluoride Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a cool, dry place in a tightly sealed container. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothes and gloves. Consult glove manufacturer to determine the proper type of glove. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:white powder Molecular Weight:1024.44 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:strong oxidizing agents Decomposition Products:carbon monoxide, lanthanum salts, hydrogen fluoride, carbonyl fluoride and organic fumes. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data available Mutagenic Effects:no data available Tetratogenic Effects:no data available SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |