| 中文名 | 六水草酸铁 |
|---|---|
| 英文名 | Iron(III) oxalate hexahydrate |
| 中文别名 | 草酸铁六水化物 |
| 熔点 | 100°C (rough estimate) |
|---|---|
| 分子式 | C6H12Fe2O18 |
| 分子量 | 483.83900 |
| 精确质量 | 483.87200 |
| PSA | 296.16000 |
| 外观性状 | Powder | yellow |
| 稳定性 | 25℃在水中溶解度0.0346mg。加热到约190℃丢去1个水分子。 |
| 水溶解性 | soluble H2O, acids; insoluble alkalies [HAW93] |
| 更多 | 1. 性状：黄色粉状结晶，在强光照射下分解而变为绿色。 2. 密度（g/mL,25/4℃）：不确定 3. 相对蒸汽密度（g/mL,空气=1）：不确定 4. 熔点（ºC）：不确定 5. 沸点（ºC,常压）：不确定 6. 沸点（ºC, 5.2kPa）：不确定 7. 折射率：不确定 8. 闪点（ºC）：不确定 9. 比旋光度（º）：不确定 10. 自燃点或引燃温度（ºC）：不确定 11. 蒸气压（kPa,25ºC）：不确定 12. 饱和蒸气压（kPa,60ºC）：不确定 13. 燃烧热（KJ/mol）：不确定 14. 临界温度（ºC）：不确定 15. 临界压力（KPa）：不确定 16. 油水（辛醇/水）分配系数的对数值：不确定 17. 爆炸上限（%,V/V）：不确定 18. 爆炸下限（%,V/V）：不确定 19. 溶解性：不确定 |
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Section 1: Product Identification Chemical Name:Iron (III) oxalate hexahydrate, tech. gr. CAS Registry Number:19469-07-9 Formula:Fe2(C2O4)3.6H2O EINECS Number:none Chemical Family:salt of an organic acid Synonym:iron oxalate, Oxalic acid, iron (III) salt
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound19469-07-9100%1mg/m3no data Section 3: Hazards Identification Soluble oxalates are harmful if swallowed. They precipitate calcium from the bloodstream causing violent Emergency Overview: muscular stimulation, convulsions, collapse, and death. Irritating to skin, eyes and respiratory tract. Primary Routes of Exposure:Ingestion, Inhalation of dust. Eye Contact:Causes moderate to severe irritation of the eyes. Skin Contact:Causes moderate to severe irritation of the skin. Inhalation:Dust is severely irritating to the nose, mucous membranes and respiratory tract. Harmful if swallowed. Ingestion may cause vomiting, pain, violent muscular stimulation, convulsions, collapse, Ingestion: and death. Irritating to skin, eyes and respiratory tract. Soluble oxalates remove calcium from the bloodstream. This Acute Health Affects: interferes with the central nervous system causing violent convulsions and death. Prolonged exposure to oxalates can lead to kidney failure resulting from calcium oxalate precipitation in renal Chronic Health Affects: tubes NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical Skin Exposure: assistance if irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Antidotes are said to be soluble calcium given orally, and calcium gluconate given intravenously, to be Ingestion: administered by trained medical personnel. Keep the victim calm. Give the victim water (only if conscious). SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, dry powder or foam If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained Special Fire Fighting Procedures: breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a sealed container. Keep away from heat and moisture. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear appropriate chemical resistant gloves and protective clothing. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators Respirator: requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:yellow pwdr. Molecular Weight:375.76 (483.86) Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:very soluble SECTION 10: Stability and Reactivity Stability:air and moisture stable solid Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:oxidizing agents and active metals Decomposition Products:Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files, Carcinogenic Effects:No data available Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Toxic solid, Inorganic, N.O.S. Hazard Class (CFR):6.1 Additional Hazard Class (CFR):NA Packaging Group (CFR):III UN ID Number (CFR):UN# 3288 Shipping Name (IATA):Toxic solid, Inorganic, N.O.S. Hazard Class (IATA):6.1 Additional Hazard Class (IATA):NA Packaging Group (IATA):III UN ID Number (IATA):UN# 3288 SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
