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14017-47-1生产厂家

14017-47-1价格

14017-47-1

14017-47-1结构式
14017-47-1结构式

化源商城直购

中文名 六水高氯酸铈
英文名 cerium(3+),triperchlorate
中文别名 高氯酸铈(III)盐六水合物
高氯酸铈盐六水合物
英文别名 Cerous perchlorate
Perchloric acid,cerium(3+) salt
EINECS 237-836-2
MFCD00150205
Cerium(3+) perchlorate
CERIUM PERCHLORATE
cerium(3+) triperchlorate
密度 1.501 g/mL at 25 °C
分子式 CeCl3H12O18
分子量 546.55900
精确质量 544.81400
PSA 278.19000
LogP 0.25710
外观性状 crystal | white
储存条件

常温密闭避光,通风干燥

稳定性

常温常压下稳定

避免的物料:还原剂 易氧化材料 金属粉末 有机材料。吸湿。溶于水、乙醇。在真空下200℃失水。

分子结构

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:544.814357 Da

8、标称质量:545 Da

9、平均质量:546.5595 Da

计算化学

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:12

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积223

7.重原子数量:16

8.表面电荷:0

9.复杂度:95.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:4

更多

1. 性状:白色无味晶体

2. 密度(g/mL,25/4℃):未确定

3. 相对蒸汽密度(g/mL,空气=1):未确定

4. 熔点(ºC):未确定

5. 沸点(ºC,常压):未确定

6. 沸点(ºC,5.2kPa):未确定

7. 折射率:未确定

8. 闪点(ºC):未确定

9. 比旋光度(º):未确定

10. 自燃点或引燃温度(ºC):未确定

11. 蒸气压(kPa,25ºC):未确定

12. 饱和蒸气压(kPa,60ºC):未确定

13. 燃烧热(KJ/mol):未确定

14. 临界温度(ºC):未确定

15. 临界压力(KPa):未确定

16. 油水(辛醇/水)分配系数的对数值:未确定

17. 爆炸上限(%,V/V):未确定

18. 爆炸下限(%,V/V):未确定

19. 溶解性:可溶解的

Version 1.2
Regulation (EC) No 1907/2006

1 - Product and Company Information

Product NameCERIUM(III) PERCHLORATE, 99.5%, 40 WT.
% SOLUTION IN WATER

2 - Hazards Identification

SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Contact with combustible material may cause fire. Irritating to
eyes, respiratory system and skin.

3 - Composition/Information on Ingredients

Product NameCAS #EC noAnnex I
Index Number
CERIUM(III) PERCHLORATE, 99.5%, 14017-47-1 237-836-2 None
40 WT. %SOLUTION IN WATER
FormulaCe(ClO4)3
Molecular Weight 438,4700 AMU

4 - First Aid Measures

AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.

5 - Fire Fighting Measures

CONDITIONS OF FLAMMABILITY
May accelerate combustion.
EXTINGUISHING MEDIA
Suitable: Water spray.
SPECIAL RISKS
ALDRICHwww.molbase.com
Specific Hazard(s): Emits toxic fumes under fire conditions. May
accelerate combustion. Contact with other material may cause
fire.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.

6 - Accidental Release Measures

PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Cover with dry lime or soda ash, pick up, keep in a closed
container, and hold for waste disposal. Ventilate area and wash
spill site after material pickup is complete.

7 - Handling and Storage

HANDLING
Directions for Safe Handling: Do not breathe dust. Do not get in
eyes, on skin, on clothing. Avoid prolonged or repeated exposure.
STORAGE
Conditions of Storage: Keep tightly closed. Store in a cool dry
place.
Unsuitable: Do not store near, nor allow contact with, clothing
and other combustible material.

8 - Exposure Controls / Personal Protection

ENGINEERING CONTROLS
Use only in a chemical fume hood. Safety shower and eye bath.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling. Wash contaminated clothing before
reuse.
PERSONAL PROTECTIVE EQUIPMENT
Special Protective Measures: Wear appropriate government approved
respirator, chemical-resistant gloves, safety goggles, other
protective clothing.

9 - Physical and Chemical Properties

pH N/A
BP/BP RangeN/A
MP/MP RangeN/A
Flash PointN/A
FlammabilityN/A
Autoignition TempN/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion LimitsN/A
Vapor PressureN/A
ALDRICHwww.molbase.com
SG/Density1,5010 g/cm3
Partition Coefficient N/A
ViscosityN/A
Vapor DensityN/A
Saturated Vapor Conc. N/A
Evaporation RateN/A
Bulk DensityN/A
Decomposition Temp.N/A
Solvent ContentN/A
Water ContentN/A
Surface TensionN/A
ConductivityN/A
Miscellaneous DataN/A
SolubilityN/A

10 - Stability and Reactivity

STABILITY
Stable: Stable.
Materials to Avoid: Organic materials, Finely powdered metals,
Strong reducing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Chlorine.

11 - Toxicological Information

SIGNS AND SYMPTOMS OF EXPOSURE
To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
Rare earth compounds may cause delayed blood clotting leading to
hemorrhages. Inhalation of rare earths may cause sensitivity to
heat, itching, and increased awareness of odor and taste.
ROUTE OF EXPOSURE
Inhalation: Material is irritating to mucous membranes and upper
respiratory tract.
Multiple Routes: May be harmful by inhalation, ingestion, or
skin absorption. Causes eye and skin irritation.

12 - Ecological Information

No data available.

13 - Disposal Considerations

SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Observe all federal, state, and local
environmental regulations.

14 - Transport Information

RID/ADR
UN#: 3098
Class: 5.1
PG: II
Subrisk: 8
Proper Shipping Name: Oxidizing liquid, corrosive,
n.o.s.
ALDRICHwww.molbase.com
IMDG
UN#: 3098
Class: 5.1
PG: II
Subrisk: 8
Proper Shipping Name: OXIDIZING LIQUID, CORROSIVE,
N.O.S.
Marine Pollutant: No
Severe Marine Pollutant: No
Technical Name: Required
IATA
UN#: 3098
Class: 5.1
PG: II
Subrisk: 8
Proper Shipping Name: Oxidizing liquid, corrosive,
n.o.s.
Inhalation Packing Group I: No
Technical Name: Required

15 - Regulatory Information

CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
INDICATION OF DANGER: O-Xi
Oxidizing. Irritant.
R-PHRASES: 8-36/37/38
Contact with combustible material may cause fire. Irritating to
eyes, respiratory system and skin.
S-PHRASES: 17-26-36
Keep away from combustible material. In case of contact with
eyes, rinse immediately with plenty of water and seek medical
advice. Wear suitable protective clothing.

16 - Other Information

WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2010 Co. License granted to make
unlimitedpaper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
ALDRICHwww.molbase.com


SECTION 16 - ADDITIONAL INFORMATION
N/A

毒理学数据:

1、急性毒性:主要的刺激性影响:

在皮肤上面:刺激皮肤和粘膜;

在眼睛上面:刺激的影响;没有已知的敏化影响。

生态学数据:

通常对水体是稍微有害的,不要将未稀释或大量产品接触地下水,水道或污水系统,未经政府许可勿将材料排入周围环境。

危害码 (欧洲) O: Oxidizing agent;Xi: Irritant;
风险声明 (欧洲) R8
安全声明 (欧洲) 17-26-36
危险品运输编码 UN 3098 5.1/PG 2
包装等级 II
危险类别 5.1

计量的氧化铈(Ⅲ)用热的稀高氯酸溶液处理。过滤后将滤液用旋转蒸发器在水浴上蒸发至干。