2417-73-4

• 常用中文名：2-溴甲基苯甲酸甲酯
• 常用英文名：Methyl 2-bromomethylbenzoate
• CAS号：2417-73-4
• 分子式：C₉H₉BrO₂
• 分子量：229.071
• 相关类别： 化学试剂 有机试剂 芳烃
• 发布时间：2018-03-14 08:00:00
• 更新时间：2024-01-04 16:23:25

名称

• 中文名: 2-溴甲基苯甲酸甲酯
• 英文名: methyl 2-(bromomethyl)benzoate
• 中文别名: 邻溴甲基苯甲酸甲酯; 2-(溴甲基)苯甲酸甲酯
• 英文别名: Methyl 2-bromomethyl benzoate; Benzoic acid, 2-(bromomethyl)-, methyl ester; Methyl 2-bromomethylbenzoate; 2-(Bromomethyl)-benzoic acid methyl ester; methyl o-bromomethylbenzoate; MFCD00090420; Methyl 2-(bromomethyl)benzoate; Benzoic acid,2-(bromomethyl)-,methyl ester; methyl 2-(1-bromomethyl)-benzoate; methyl ortho-bromomethylbenzoate; Methyl-2-(brommethyl)benzolcarboxylat; 2-methoxycarbonylbenzyl bromide

物化性质

• 密度: 1.5±0.1 g/cm3
• 沸点: 293.9±23.0 °C at 760 mmHg
• 熔点: 30-35°C
• 分子式: C₉H₉BrO₂
• 分子量: 229.071
• 闪点: 131.5±22.6 °C
• 精确质量: 227.978592
• PSA: 26.30000
• LogP: 2.90
• 蒸汽压: 0.0±0.6 mmHg at 25°C
• 折射率: 1.560
• 储存条件: 2~8℃

MSDS

Name: Methyl 2-(bromomethyl)benzoate Material Safety Data Sheet Synonym: CAS: 2417-73-4 Section 1 - Chemical Product MSDS Name:Methyl 2-(bromomethyl)benzoate Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 2417-73-4 Methyl 2-(bromomethyl)benzoate unlisted Hazard Symbols: C Risk Phrases: 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Causes burns. Potential Health Effects Eye: Causes eye burns. Lachrymator (substance which increases the flow of tears). Skin: Causes skin burns. Ingestion: Causes gastrointestinal tract burns. Inhalation: Causes chemical burns to the respiratory tract. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Corrosives area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 2417-73-4: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 153 deg C @4mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C9H9BrO2 Molecular Weight: 229.07 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents, strong bases. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, hydrogen bromide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 2417-73-4 unlisted. LD50/LC50: Not available. Carcinogenicity: Methyl 2-(bromomethyl)benzoate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: CORROSIVE LIQUID, TOXIC, N.O.S.* Hazard Class: 8 (6.1) UN Number: 2922 Packing Group: II IMO Shipping Name: CORROSIVE LIQUID, TOXIC, N.O.S. Hazard Class: 8 (6.1) UN Number: 2922 Packing Group: II RID/ADR Shipping Name: CORROSIVE LIQUID, TOXIC, N.O.S. Hazard Class: 8 (6.1) UN Number: 2922 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 34 Causes burns. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 2417-73-4: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 2417-73-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 2417-73-4 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi
• 海关编码: 2916399090

合成路线

89-71-4 ~99% 2417-73-4

文献：SUZHOU RIBO LIFE SCIENCE CO., LTD Patent: US2011/237786 A1, 2011 ; Location in patent: Page/Page column 7 ;

2094-98-6 89-71-4 ~76% 2417-73-4

文献：Chen, Gang; Crawford, Jason; Skerlj, Renato Patent: US2005/154201 A1, 2005 ;

89-71-4 74-95-3 ~% 2417-73-4

文献：US2003/13743 A1, ; US 20030013743 A1

89-71-4 ~% 2417-73-4 244219-99-6

文献：US6410561 B1, ;

118-90-1 ~% 2417-73-4

文献：Journal of Organic Chemistry, , vol. 17, p. 1252,1255

933-88-0 ~% 2417-73-4

文献：US2011/237786 A1, ;

67-56-1 40819-28-1 ~% 2417-73-4

文献：Norman, Mark H.; Minick, Douglas J.; Rigdon, Greg C. Journal of Medicinal Chemistry, 1996 , vol. 39, # 1 p. 149 - 157

186581-53-3 7115-89-1 ~% 2417-73-4

文献：Journal of Organic Chemistry, , vol. 17, p. 1252,1255

7115-89-1 ~% 2417-73-4

文献：Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, , vol. 46, p. 510 Chem. Zentralbl., , vol. 85, # II p. 1271

上下游产品

上游产品  9
89-71-4 2094-98-6 74-95-3 118-90-1
933-88-0 67-56-1 40819-28-1 186581-53-3
7115-89-1
下游产品  10
1046494-85-2 55453-87-7 55453-89-9 15196-54-0
468751-38-4 39221-42-6 21733-94-8 203047-36-3
1966-89-8 87-41-2

海关

海关编码	2916399090
中文概述	2916399090 其他芳香一元羧酸. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
申报要素	品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装
Summary	2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%