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14267-08-4价格

14267-08-4

14267-08-4结构式
14267-08-4结构式

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中文名 二氯(N,N,N’,N’-四甲基乙二胺)钯
英文名 Dichloro(N,N,N′,N′-tetramethylethylenediamine)palladium(II)
中文别名 二氯(N,N,N',N'-四甲基乙二胺)钯
二氯(N,N,N',N'-四甲基乙二胺)钯
顺-二氯(N,N,N`,N`-四甲基乙烯二胺)钯(II)
英文别名 DICHLORO(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)PALLADIUM(II)
MFCD00075317
Palladium(2+) chloride - N,N,N',N'-tetramethyl-1,2-ethanediamine (1:2:1)
Palladium,dichloro(N,N,N',N'-tetramethyl-1,2-ethanediamine-N,N')-,(sp-4-2)
(N,N,N',N'-tetramethylethylenediamine)PdCl2
dichloro(N,N,N',N'-tetramethylethylene-diamine)pa
[Pd(tmen)Cl2]
N,N,N',N'-tetramethylethylenediamine palladium(II) chloride
Palladium,dichloro(N,N,N',N'-tetramethylethylenediamine)
cis-dichloro(N,N,N',N'-tetramethylethylenediamine)palladium(II)
Cl2Pd(II)(TMEDA)
1,2-Ethanediamine, N,N,N,N-tetramethyl-, palladium(2+) salt, hydrochloride (1:1:2)
(N,N,N',N'-tetramethylethylenediamine)dichloridopalladium(II)
沸点 121ºC at 760 mmHg
熔点 245ºC (dec.)(lit.)
分子式 C6H16Cl2N2Pd
分子量 293.531
闪点 10ºC
精确质量 291.972534
PSA 6.48000
LogP 1.48860
蒸汽压 14.9mmHg at 25°C
储存条件

密闭于阴凉干燥环境中

稳定性

遵照规定使用和储存则不会分解。

分子结构

1、摩尔折射率:无可用

2、 摩尔体积(cm3/mol):无可用

3、 等张比容(90.2K):无可用

4、 表面张力(dyne/cm):无可用

5、 极化率:无可用

计算化学

1、 疏水参数计算参考值(XlogP):无可用

2、 氢键供体数量:0

3、 氢键受体数量:2

4、 可旋转化学键数量:3

5、 拓扑分子极性表面积(TPSA):6.5

6、 重原子数量:11

7、 表面电荷:0

8、 复杂度:45.2

9、 同位素原子数量:0

10、 确定原子立构中心数量:0

11、 不确定原子立构中心数量:0

12、 确定化学键立构中心数量:0

13、 不确定化学键立构中心数量:0

14、 共价键单元数量:2

更多

1. 性状:无可用

2. 密度(g/mL,25/4℃):无可用

3. 相对蒸汽密度(g/mL,空气=1):无可用

4. 熔点(ºC):245

5. 沸点(ºC,常压):无可用

6. 沸点(ºC,5.2kPa):无可用

7. 折射率:无可用

8. 闪点(ºC):无可用

9. 比旋光度(º):无可用

10. 自燃点或引燃温度(ºC):无可用

11. 蒸气压(kPa,25ºC):无可用

12. 饱和蒸气压(kPa,60ºC):无可用

13. 燃烧热(KJ/mol):无可用

14. 临界温度(ºC):无可用

15. 临界压力(KPa):无可用

16. 油水(辛醇/水)分配系数的对数值:无可用

17. 爆炸上限(%,V/V):无可用

18. 爆炸下限(%,V/V):无可用

19. 溶解性:无可用


Section 1: Product Identification
Chemical Name:cis-Dichloro(N,N,N'N'-tetramethylethylenediamine)palladium(II), 99%
CAS Registry Number:14267-08-4
Formula:C6H16Cl2N2Pd
EINECS Number:none
Chemical Family:organometallic complex
Synonym:cis-ichloroN,N,N',N'-Tetramethyl-ethane-1,2-diamine)palladium(II)

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound14267-08-4100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure:Ingestion, inhalation
Eye Contact:Causes slight to mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information available on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide, dry powder or foam
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a tightly sealed container. Keep in a cool, dry, well ventilated place.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:yellow powder
Molecular Weight:293.53
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:not determined
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:strong oxidizing agents
Decomposition Products:carbon monoxide, carbon dioxide, palladium oxide and organic fumes

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory
SARA (Title 313):Title compound not listed
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

生态学数据:

该物质对环境可能有危害,对水体应给予特别注意。

符号 GHS07
GHS07
信号词 Warning
危害声明 H315-H319-H335
警示性声明 P261-P305 + P351 + P338
个人防护装备 dust mask type N95 (US);Eyeshields;Gloves
危害码 (欧洲) Xi: Irritant;
风险声明 (欧洲) R36/37/38
安全声明 (欧洲) 37/39-26
危险品运输编码 NONH for all modes of transport

~98%

14267-08-4结构式

14267-08-4

文献:Biscoe, Mark R.; Fors, Brett P.; Buchwald, Stephen L. Journal of the American Chemical Society, 2008 , vol. 130, # 21 p. 6686 - 6687

~97%

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文献:Zhao, Qing; Li, Chengxi; Senanayake, Chris H.; Tang, Wenjun Chemistry - A European Journal, 2013 , vol. 19, # 7 p. 2261 - 2265

~90%

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文献:Graaf, Wim de; Boersma, Jaap; Smeets, Wilberth J. J.; Spek, Anthony L.; Koten, Gerard van Organometallics, 1989 , vol. 8, p. 2907 - 2917

~97%

14267-08-4结构式

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文献:Jung, Miso; Suzaki, Yuji; Saito, Takashi; Shimada, Kyoichi; Osakada, Kohtaro Polyhedron, 2012 , vol. 40, # 1 p. 168 - 174

~%

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文献:Inorganic Chemistry, , vol. 31, p. 1090 - 1095

~%

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文献:Polyhedron, , vol. 19, # 8 p. 959 - 963

~%

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文献:Inorganica Chimica Acta, , vol. 188, p. 25 - 32

~%

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14267-08-4

文献:Inorganica Chimica Acta, , vol. 198 - 200, p. 187 - 192