76121-99-8

• 常用中文名：(6,6,7,7,8,8,8-七氟-2,2-二甲基-3,5-辛二酮)银
• 常用英文名：Silver,(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato-kO3,kO5)-
• CAS号：76121-99-8
• 分子式：C₁₀H₁₀AgF₇O₂
• 分子量：403.04200
• 相关类别： 有机原料 有机金属类化合物 有机铪、汞、银、铂等
• 发布时间：2018-12-29 18:17:53
• 更新时间：2025-08-25 20:58:04
• 下载msds

名称

• 中文名: (6,6,7,7,8,8,8-七氟-2,2-二甲基-3,5-辛二酮酸)银
• 英文名: (6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)silver
• 英文别名: MFCD00010348; SILVER(I)-FOD; 6,6,7,7,8,8,8-Heptafluoro-2,2-dimethyl-3,5-octaned; AG(FOD); silver heptafluorodimethyloctanedionate; 6,6,7,7,8,8,8-HEPTAFLUORO-2,2-DIMETHYL*3,5-OCTANEDI; RESOLVE-AL AGFOD; [Ag(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)]; (6,6,7,7,8,8,8-HEPTAFLUORO-2,2-DIME.-3,5-OCTANEDION.)SILVER; RESOLVE-AL(TM) AGFOD

物化性质

• 沸点: 172.7ºC at 760 mmHg
• 熔点: 160ºC (dec.)(lit.)
• 分子式: C₁₀H₁₀AgF₇O₂
• 分子量: 403.04200
• 闪点: 75.5ºC
• 精确质量: 401.96200
• PSA: 26.30000
• LogP: 3.79930
• 外观性状: Fine Crystalline Powder | Green-brown to brown
• 储存条件:

  密闭于阴凉干燥环境中

• 稳定性:

  遵照规定使用和储存则不会分解。

• 分子结构:

  1、摩尔折射率：无可用

  2、 摩尔体积（cm³/mol）：无可用

  3、 等张比容（90.2K）：无可用

  4、 表面张力（dyne/cm）：无可用

  5、 极化率：无可用

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:9

  4.可旋转化学键数量:3

  5.互变异构体数量:3

  6.拓扑分子极性表面积34.1

  7.重原子数量:20

  8.表面电荷:0

  9.复杂度:382

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:2

• 更多:

  1. 性状：无可用

  2. 密度（g/mL,25/4℃）：无可用

  3. 相对蒸汽密度（g/mL,空气=1）：无可用

  4. 熔点（ºC）：160

  5. 沸点（ºC,常压）：无可用

  6. 沸点（ºC,5.2kPa）：无可用

  7. 折射率：无可用

  8. 闪点（ºC）：无可用

  9. 比旋光度（º）：无可用

  10. 自燃点或引燃温度（ºC）：无可用

  11. 蒸气压（kPa,25ºC）：无可用

  12. 饱和蒸气压（kPa,60ºC）：无可用

  13. 燃烧热（KJ/mol）：无可用

  14. 临界温度（ºC）：无可用

  15. 临界压力（KPa）：无可用

  16. 油水（辛醇/水）分配系数的对数值：无可用

  17. 爆炸上限（%,V/V）：无可用

  18. 爆炸下限（%,V/V）：无可用

  19. 溶解性：无可用

MSDS

Name: (6 6 7 7 8 8 8-Heptafluoro-2 2-dimethyl -3 5-octanedionato)silver Material Safety Data Sheet Synonym: Ag(fod) CAS: 76121-99-8 Section 1 - Chemical Product MSDS Name:(6 6 7 7 8 8 8-Heptafluoro-2 2-dimethyl -3 5-octanedionato)silver Material Safety Data Sheet Synonym:Ag(fod) Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 76121-99-8 (6,6,7,7,8,8,8-Heptafluoro-2,2-dimethy >99 unlisted Hazard Symbols: None Listed. Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: Chronic inhalation or ingestion of silver salts may cause argyria characterized by a permanent blue-gray discoloration of the eyes, skin, mucous membranes, and internal organs. This malady results from the accumulation of silver in the body. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. Do not let this chemical enter the environment. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 76121-99-8: United Kingdom, WEL - TWA: (listed as silver soluble compounds): mg/m3 TWA (as Ag) United Kingdom, WEL - STEL: (listed as silver soluble compounds): 0.03 mg/m3 STEL (as Ag) United States OSHA: 0.01 mg/m3 TWA (listed under Silver soluble compounds). Belgium - TWA: (listed as silver soluble compounds): 0.01 mg/m3 V (as Ag) France - VME: (listed as silver soluble compounds): 0.01 mg/m3 VM (as Ag) Germany: (listed as silver soluble compounds): 0.01 mg/m3 VME (as Japan: (listed as silver compounds): 0.01 mg/m3 OEL (as Ag) Malaysia: (listed as silver soluble compounds): 0.01 mg/m3 TWA (a Ag) Netherlands: (listed as silver soluble compounds): 0.01 mg/m3 MAC Ag) Spain: (listed as silver soluble compounds): 0.01 mg/m3 VLA-ED (a Ag) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder Color: brown or brown grey Odor: none reported pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 160 deg C(dec) Autoignition Temperature: Not applicable. Flash Point: Not applicable. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: > 160 deg C Solubility in water: Not available. Specific Gravity/Density: Not available. Molecular Formula: C10H10F7O2Ag Molecular Weight: 403.04 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Dust generation. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, hydrogen fluoride gas, silver fumes, oxides of silver. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 76121-99-8 unlisted. LD50/LC50: Not available. Carcinogenicity: (6,6,7,7,8,8,8-Heptafluoro-2,2-dimethyl-3,5-octanedionato)silver - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 76121-99-8: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 76121-99-8 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 76121-99-8 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。

安全

• 个人防护装备: Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
• 风险声明 (欧洲): 36/37/38
• 安全声明 (欧洲): 24/25
• 危险品运输编码: NONH for all modes of transport
• WGK德国: 3
• 海关编码: 2914700090

海关

海关编码	2914700090
中文概述	2914700090 其他酮及醌的卤化、磺化衍生物（包括硝化和亚硝化衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0%
申报要素	品名, 成分含量, 用途, 丙酮报明包装
Summary	HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%