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10025-83-9生产厂家

10025-83-9价格

10025-83-9

10025-83-9结构式
10025-83-9结构式

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中文名 氯化铱(III)
英文名 Iridium(III) chloride
中文别名 三氯化铱
英文别名 Iridous chloride
IRIDIUM TRICHLORIDE extrapure
MFCD00011063
Iridium trichloride
Iridium(3+) trichloride
IRIDIUM CHLORIDE
EINECS 233-044-6
密度 5,3 g/cm3
熔点 763ºC
分子式 Cl3Ir
分子量 298.576
精确质量 297.869446
外观性状 棕色粉末
蒸汽压 33900mmHg at 25°C
储存条件 室温,干燥
稳定性

α-IrCl3具有AlCl3类型的结构,为棕色片状固体,在空气中稳定,在600℃加热转变为β-IrCl3。β-IrCl3与α-IrCl3的结构相似,但金属原子在晶格的八面体空隙中的分布方式不同。β-IrCl3是深红色的结晶,在763℃时分解。也存在有一暗橄榄绿色的变体。IrCl3的密度为5.3g/cm3,不溶于水、碱和酸,但可溶于王水中形成[IrCl]2+。

水溶解性 insoluble
分子结构

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:297.869458 Da

8、标称质量:298 Da

9、平均质量:298.576 Da

计算化学

1、 疏水参数计算参考值(XlogP):未确定

2、 氢键供体数量:0

3、 氢键受体数量:3

4、 可旋转化学键数量:0

5、 拓扑分子极性表面积(TPSA):0

6、 重原子数量: 4

7、 表面电荷:0

8、 复杂度:0

9、 同位素原子数量:0

10、 确定原子立构中心数量:0

11、 不确定原子立构中心数量:0

12、 确定化学键立构中心数量:0

13、 不确定化学键立构中心数量:0

14、 共价键单元数量:4

更多

1. 性状:棕色无气味粉末。

2. 密度(g/mL,25℃):5.3

3. 相对蒸汽密度(g/mL,空气=1):1未确定

4. 熔点(ºC):763

5. 沸点(ºC,常压):未确定

6. 沸点(ºC,5.2kPa):未确定

7. 折射率:未确定

8. 闪点(ºC):未确定

9. 比旋光度(º):未确定

10. 自燃点或引燃温度(ºC):未确定

11. 蒸气压(kPa,20ºC):未确定

12. 饱和蒸气压(kPa,60ºC):未确定

13. 燃烧热(KJ/mol):未确定

14. 临界温度(ºC):未确定

15. 临界压力(KPa):未确定

16. 油水(辛醇/水)分配系数的对数值:未确定

17. 爆炸上限(%,V/V):未确定

18. 爆炸下限(%,V/V):未确定

19. 溶解性:不溶于水

Name: Iridium(III) Chloride Material Safety Data Sheet
Synonym: Iridium Muriate
CAS: 10025-83-9
Section 1 - Chemical Product MSDS Name:Iridium(III) Chloride Material Safety Data Sheet
Synonym:Iridium Muriate

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
10025-83-9 Iridium(III) Chloride ca 100 233-044-6
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Moisture sensitive.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use extinguishing media appropriate to the surrounding fire. Substance is noncombustible.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Do NOT get water inside containers. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation. Do not get water inside containers.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Do not allow contact with water. Keep from contact with moist air and steam.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Storage under a nitrogen blanket has been recommended. Store protected from moisture.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 10025-83-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystals
Color: dark brown - grey
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 763 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: Cl3Ir
Molecular Weight: 298.56

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at normal temperatures in tightly closed containers under an inert atmosphere.
Conditions to Avoid:
Incompatible materials, dust generation, moisture, excess heat.
Incompatibilities with Other Materials:
Moisture, strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 10025-83-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Iridium(III) Chloride - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 10025-83-9: 2
Canada
CAS# 10025-83-9 is listed on Canada's DSL List.
CAS# 10025-83-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10025-83-9 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

生态学数据:

通常对水体是稍微有害的,不要将未稀释或大量产品接触地下水,水道或污水系统,未经政府许可勿将材料排入周围环境。

符号 GHS07
GHS07
信号词 Warning
危害声明 H315-H319-H335
警示性声明 P261-P305 + P351 + P338
个人防护装备 dust mask type N95 (US);Eyeshields;Gloves
危害码 (欧洲) Xi:Irritant
风险声明 (欧洲) R36/37/38
安全声明 (欧洲) S26-S36
危险品运输编码 UN 1759
WGK德国 3

~%

10025-83-9结构式

10025-83-9

文献:Journal of the Chemical Society, Chemical Communications, , # 18 p. 1429 - 1430

~%

10025-83-9结构式

10025-83-9

文献:Nippon Kagaku Kaishi (Journal of the Chemical Society of Japan), , vol. 63, p. 1938 - 1943
上游产品  2

下游产品  1

将金属铱粉置于瓷舟中,然后放入燃烧管。把燃烧管的一端拉细作为气体导入端,而另一端则装上上磨口的接头。往管中通入不含氧、但混有少量一氧化碳的氯气;并用喷灯火焰将燃烧管加热至600℃左右,然后用太阳光直接照射,或用镁条的强光照射。氯化过程大约15min即告结束。