2997-01-5

• 常用中文名：乙二醇双(3-氨丙基)醚
• 常用英文名：3,3'-ethylenedioxybis(propylamine)
• CAS号：2997-01-5
• 分子式：C₈H₂₀N₂O₂
• 分子量：176.25700
• 发布时间：2018-04-25 08:00:00
• 更新时间：2024-01-01 20:15:32
• 自组装材料,接触印刷材料

名称

• 中文名: 乙二醇双(3-胺丙基)醚
• 英文名: 3-[2-(3-aminopropoxy)ethoxy]propan-1-amine
• 中文别名: 乙二醇二(3-氨丙基)醚; 乙二醇双（3-氨丙基）醚; 3,3-(乙烷-1,2-二yl双(氧基))双(丙烷-1-胺)
• 英文别名: Jeffamine 176; 1,10-Diamino-4,7-dioxadecane; 4,7-Dioxadecane-1,10-diamine; 1,2-Bis(3-aminopropoxy)ethane; 3,3'-(Ethane-1,2-diylbis(oxy))bis(propan-1-amine); EINECS 221-067-4; Ethylene Glycol Bis(3-aMinopropyl) Ether

物化性质

• 密度: 0.975g/cm3
• 沸点: 275.9ºC at 760mmHg
• 分子式: C₈H₂₀N₂O₂
• 分子量: 176.25700
• 闪点: 121.5ºC
• 精确质量: 176.15200
• PSA: 70.50000
• LogP: 1.11780
• 外观性状: 液体;Colorless to Light yellow clear liquid
• 蒸汽压: 0.00495mmHg at 25°C
• 折射率: 1.46
• 储存条件:

  密闭于阴凉干燥环境中

• 稳定性:

  遵照规定使用和储存则不会分解。

• 分子结构:

  1、 摩尔折射率：49.67

  2、 摩尔体积（m³/mol）：180.6

  3、 等张比容（90.2K）：447.8

  4、 表面张力（dyne/cm）：37.7

  5、 极化率（10^-24cm³）：19.69

• 计算化学:

  1、 疏水参数计算参考值（XlogP）：-1.2

  2、 氢键供体数量：2

  3、 氢键受体数量：2

  4、 可旋转化学键数量：9

  5、 拓扑分子极性表面积（TPSA）：73.7

  6、 重原子数量：12

  7、 表面电荷：0

  8、 复杂度：71.5

  9、 同位素原子数量：0

  10、 确定原子立构中心数量：0

  11、 不确定原子立构中心数量：0

  12、 确定化学键立构中心数量：0

  13、 不确定化学键立构中心数量：0

  14、 共价键单元数量：1

• 更多:

  1. 性状：无可用

  2. 密度（g/mL,25/4℃）：0.9837

  3. 相对蒸汽密度（g/mL,空气=1）：无可用

  4. 熔点（ºC）：无可用

  5. 沸点（ºC,常压）：127-130

  6. 沸点（ºC,5.2kPa）：无可用

  7. 折射率：无可用

  8. 闪点（ºC）：无可用

  9. 比旋光度（º）：无可用

  10. 自燃点或引燃温度（ºC）：无可用

  11. 蒸气压（kPa,25ºC）：无可用

  12. 饱和蒸气压（kPa,60ºC）：无可用

  13. 燃烧热（KJ/mol）：无可用

  14. 临界温度（ºC）：无可用

  15. 临界压力（KPa）：无可用

  16. 油水（辛醇/水）分配系数的对数值：无可用

  17. 爆炸上限（%,V/V）：无可用

  18. 爆炸下限（%,V/V）：无可用

  19. 溶解性：无可用

MSDS

Name: 1 10-Diamino-4 7-dioxadecane Material Safety Data Sheet Synonym: CAS: 2997-01-5 Section 1 - Chemical Product MSDS Name:1 10-Diamino-4 7-dioxadecane Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 2997-01-5 1,10-Diamino-4,7-dioxadecane 221-067-4 Hazard Symbols: C Risk Phrases: 21 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful in contact with skin. Causes burns. Potential Health Effects Eye: Causes eye burns. Skin: Harmful if absorbed through the skin. Causes skin burns. Ingestion: Causes gastrointestinal tract burns. Inhalation: Causes chemical burns to the respiratory tract. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Corrosives area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 2997-01-5: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: yellow Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 127 - 130 deg C @7mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: 0.984 Molecular Formula: C8H20N2O2 Molecular Weight: 176.26 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents, strong acids. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 2997-01-5: UI2800000 LD50/LC50: CAS# 2997-01-5: Oral, rat: LD50 = 2830 uL/kg; Skin, rabbit: LD50 = 1250 uL/kg. Carcinogenicity: 1,10-Diamino-4,7-dioxadecane - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.* Hazard Class: 8 UN Number: 2735 Packing Group: III IMO Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S. Hazard Class: 8 UN Number: 2735 Packing Group: III RID/ADR Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S. Hazard Class: 8 UN Number: 2735 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 21 Harmful in contact with skin. R 34 Causes burns. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 2997-01-5: No information available. Canada CAS# 2997-01-5 is listed on Canada's NDSL List. CAS# 2997-01-5 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 2997-01-5 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。 CHEMICAL IDENTIFICATION RTECS NUMBER : UI2800000 CHEMICAL NAME : Propylamine, 3,3'-(ethylenedioxy)bis- CAS REGISTRY NUMBER : 2997-01-5 BEILSTEIN REFERENCE NO. : 1744355 LAST UPDATED : 199701 DATA ITEMS CITED : 3 MOLECULAR FORMULA : C8-H20-N2-O2 MOLECULAR WEIGHT : 176.30 WISWESSER LINE NOTATION : Z3O2O3Z HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 2830 uL/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 1250 uL/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969

安全

• 危害码 (欧洲): C
• 风险声明 (欧洲): 34-21
• 安全声明 (欧洲): S26;S45;S36/S37/S39
• 海关编码: 2922199090

合成路线

3386-87-6 7440-48-4 ~% 2997-01-5 108-10-1

文献：US6492559 B1, ;

61515-41-1 ~% 2997-01-5

文献：US4104302 A1, ;

3386-87-6 ~% 2997-01-5

文献：DE734475 , ; DRP/DRBP Org.Chem.

上下游产品

上游产品  3
3386-87-6 7440-48-4 61515-41-1
下游产品  1
117875-33-9

海关

海关编码	2922199090
中文概述	2922199090. 其他氨基醇及其醚，酯和它们的盐（但含一种以上含氧基的除外）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装
Summary	2922199090. other amino-alcohols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%