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176763-62-5

176763-62-5结构式

常用中文名：(R,R)-(-)-N,N'-双(3,5-二-叔丁基亚水杨基)-1,2-环己二胺钴(II)
常用英文名：(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)
CAS号：176763-62-5
分子式：C₃₆H₅₂CoN₂O₂
分子量：605.759
相关类别：有机原料有机金属类化合物有机铋、钴、镨、钆、镓、铱、铼、钇、铽等
发布时间：2018-12-29 05:30:37
更新时间：2024-01-02 08:15:02

中文名	(R,R)-(-)-N,N'-双(3,5-二叔丁基亚水杨基)-1,2-环己二胺钴(II)
英文名	(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)
中文别名	(R,R)-(-)-N,N'-双(3,5-二叔丁基亚水杨基)-1,2-环己基二胺钴 (1R,2R)-(-)-1,2-环己烷二氨基-N,N'-双(3,5-二丁基亚水杨基)钴(Ⅱ) (R,R)-(-)-N,N'-双(3,5-二叔丁基亚水杨基)-1,2-环己基二胺钴 (1R,2R)-环己二胺-N,N-双(3,5-二叔丁基水杨烯)钴 (R,R)-(-)-N,N'-双(3,5-二叔丁基亚水杨基)-1,2-环己二胺钴(II)
英文别名	2,2'-{(1R,2R)-1,2-Cyclohexanediylbis[nitrilo(E)methylylidene]}bis[4,6-bis(2-methyl-2-propanyl)phenol] - cobalt (1:1) (R,R)-(-)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) Phenol, 2,2'-[(1R,2R)-1,2-cyclohexanediylbis[nitrilo(E)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)-, cobalt salt (1:1) MFCD01631277 (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II)

熔点	>350ºC(lit.)
分子式	C₃₆H₅₂CoN₂O₂
分子量	605.759
精确质量	605.351746
PSA	43.18000
LogP	8.28320
外观性状	橙色至红色-棕色粉末
储存条件	保存方法：密闭，阴凉，干燥处
稳定性	避氧化物
计算化学	1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:2 3.氢键受体数量:4 4.可旋转化学键数量:4 5.互变异构体数量:6 6.拓扑分子极性表面积58.2 7.重原子数量:41 8.表面电荷:0 9.复杂度:1120 10.同位素原子数量:0 11.确定原子立构中心数量:2 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:2 14.不确定化学键立构中心数量:0 15.共价键单元数量:2
更多	1. 性状：橘黄色到棕色粉末 2. 密度（g/mL, 20 ℃ ）：未确定 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：>350 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC4 mmHg）：未确定 7. 折射率：未确定 8. 闪点（ºF4 mmHg）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：不能溶解于水

Section 1: Product Identification
Chemical Name:(1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)cobalt (II)
CAS Registry Number:176763-62-5
Formula:C36H52CoN2O2
EINECS Number:none
Chemical Family:organometallic complexes

Synonym:none

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound176763-62-5100%0.02mg/m3 (as Co)no data

Section 3: Hazards Identification
Causes irritation of eyes, skin, and respiratory tract. May cause lung disease, polycythemia, congestive failure,
Emergency Overview:
and enlargement of the thyroid. Limited evidence of a carcinogenic effect.
Primary Routes of Exposure:Skin and eyes, ingestion and dust inhalation.
Eye Contact:Causes irritation, redness, and pain.
Skin Contact:May cause dermatitis. Causes irritation to skin. Symptoms include redness, itching, and pain.
Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath, nausea,
Inhalation:
respiratory hypersensitivity, asthma.
Causes abdominal pain, nausea, vomiting, flushing of the face and ears, mild hypo tension, rash, and ringing
Ingestion:
in the ears.
Irritating to skin, eyes and respiratory tract. Causes abdominal pain, nausea, vomiting, coughing, and
Acute Health Affects:
shortness of breath.
Repeated oral administration of cobalt salts may reduce thyroid activity, cause blood disease, and damage
Chronic Health Affects:kidney, heart and lungs. Prolonged or repeated skin exposure may cause dermatitis. Limited evidence of a
carcinogenic effect.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self- contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
Spill and Leak Procedures:
swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a tightly sealed container away from heat and direct sunlight.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:red-brown pwdr.
Molecular Weight:603.76
Melting Point:406-412°C
Boiling Point:no data
Vapor Pressure:not applicable
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:oxidizing agents
Decomposition Products:carbon dioxide, carbon monoxide, nitrogen oxides, organic fumes, and cobalt oxide.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:Possible carcinogen
Mutagenic Effects:No data
Tetratogenic Effects:No data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound: See category N096 for reporting.
Second Ingredient:None

SECTION 16 - ADDITIONAL INFORMATION
N/A

符号	GHS07
信号词	Warning
危害声明	H302-H312-H332
警示性声明	P280
个人防护装备	dust mask type N95 (US);Eyeshields;Gloves
危害码 (欧洲)	Xn: Harmful;
风险声明 (欧洲)	R20/21/22
安全声明 (欧洲)	36/37/39
危险品运输编码	NONH for all modes of transport
WGK德国	3