174500-20-0

174500-20-0结构式

常用中文名：2,6-双[|4S|-4-苯基-2-噁唑啉基]吡啶
常用英文名：2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine
CAS号：174500-20-0
分子式：C₂₃H₁₉N₃O₂
分子量：369.416
发布时间：2018-12-05 16:43:03
更新时间：2024-01-04 19:16:09

化源商城直购

中文名	2,6-二[(4S)-4-苯基-2-恶唑啉基]吡啶
英文名	(S,S)-2,2'-(2,6-Pyridinediyl)bis(4-phenyl-2-oxazoline)
中文别名	2,6-双[(4S)-4-苯基-2-噁唑啉基]吡啶 2,6-二[(4S)-4-苯基-2-噁唑啉基]吡啶 2,6-双[4S-4-苯基-2-噁唑啉基]吡啶 (-)-2,6-双((4S)-4-苯基-2-恶唑啉)吡啶 (S,S)-2,6-双(4,5-二氢-4-苯基-2-噁唑基)吡啶 2,6-双[(4S)-4-苯基-2-恶唑啉]吡啶 2,6-二[(4S)-4-苯基-2-恶唑啉基 2,6-双[(4S)-4-苯基-2-噁唑啉基]吡啶 (S,S)-2,6-双(4-苯基-2-恶唑啉-2-基)吡啶 (S,S)-2,6-双(4-苯基-2-噁唑啉基)吡啶 (S,S)-2,6-双(4-苯基-2-恶唑啉-2-基)吡啶 (S,S)-2,2'-(2,6-吡啶二基)双(4-苯基-2-恶唑啉
英文别名	2,6-Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)pyridine Pyridine, 2,6-bis[(4S)-4,5-dihydro-4-phenyl-2-oxazolyl]- 2,6-Bis[(4S)-phenyl-2-(oxazolin-2-yl)]pyridine 2,6-Bis[4S-4-phenyl-2-oxazolinyl]pyridine 2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine 2,6-Bis[(4S)-4-phenyl-4,5-dihydro-1,3-oxazol-2-yl]pyridine (S,S)-2,6-Bis(4,5-dihydro-4-phenyl-2-oxazolyl)pyridine (S,S)-2,6-Bis(4-phenyl-2-oxazolin-2-yl)pyridine (4S)-4-phenyl-2-[6-[(4S)-4-phenyl-4,5-dihydro-1,3-oxazol-2-yl]pyridin-2-yl]-4,5-dihydro-1,3-oxazole (S,S)-2,6-Bis(4-phenyl-2-oxazolinyl)pyridine MFCD01863586 2,6-Bis[(4S)-4-phenyl-2-oxazolinyl]pyridine

密度	1.3±0.1 g/cm3
沸点	600.4±55.0 °C at 760 mmHg
熔点	171-175 °C(lit.)
分子式	C₂₃H₁₉N₃O₂
分子量	369.416
闪点	316.9±31.5 °C
精确质量	369.147736
PSA	56.07000
LogP	3.43
外观性状	白色至灰白色结晶粉末
蒸汽压	0.0±1.6 mmHg at 25°C
折射率	1.674
储存条件	密封冷藏于干燥环境中
稳定性	遵照规定使用和储存则不会分解。
水溶解性	Insoluble
分子结构	1、摩尔折射率：107.74 2、摩尔体积（m³/mol）：287.2 3、等张比容（90.2K）：766.0 4、表面张力（dyne/cm）：50.6 5、极化率（10^-24cm³）：42.71
计算化学	1.疏水参数计算参考值（XlogP）:4 2.氢键供体数量:0 3.氢键受体数量:5 4.可旋转化学键数量:4 5.互变异构体数量:无 6.拓扑分子极性表面积56.1 7.重原子数量:28 8.表面电荷:0 9.复杂度:543 10.同位素原子数量:0 11.确定原子立构中心数量:2 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1
更多	1. 性状：无可用 2. 密度（g/mL,25/4℃）：无可用 3. 相对蒸汽密度（g/mL,空气=1）：无可用 4. 熔点（ºC）：171-175 5. 沸点（ºC,常压）：无可用 6. 沸点（ºC,5.2kPa）：无可用 7. 折射率：无可用 8. 闪点（ºC）：无可用 9. 比旋光度（º）：-224（ C=1, 氯仿） 10. 自燃点或引燃温度（ºC）：无可用 11. 蒸气压（kPa,25ºC）：无可用 12. 饱和蒸气压（kPa,60ºC）：无可用 13. 燃烧热（KJ/mol）：无可用 14. 临界温度（ºC）：无可用 15. 临界压力（KPa）：无可用 16. 油水（辛醇/水）分配系数的对数值：无可用 17. 爆炸上限（%,V/V）：无可用 18. 爆炸下限（%,V/V）：无可用 19. 溶解性：不溶于水

Name:	2 6-bis[(4s)-phenyl-2-oxazolin-2-yl]pyridine Material Safety Data Sheet
Synonym:
CAS:	174500-20-0

Section 1 - Chemical Product MSDS Name:2 6-bis[(4s)-phenyl-2-oxazolin-2-yl]pyridine Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
174500-20-0	2,6-bis[(4s)-phenyl-2-oxazolin-2-yl]py		unlisted

Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 174500-20-0: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystals
Color: white
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 171 - 175 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density:
Molecular Formula: C23H19N3O2
Molecular Weight: 369.42

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 174500-20-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,6-bis[(4s)-phenyl-2-oxazolin-2-yl]pyridine - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 174500-20-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 174500-20-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 174500-20-0 is not listed on the TSCA inventory.
It is for research and development use only.

SECTION 16 - ADDITIONAL INFORMATION
N/A

生态学数据:

该物质对环境可能有危害，对水体应给予特别注意。

符号	GHS07
信号词	Warning
危害声明	H315-H319-H335
警示性声明	P261-P305 + P351 + P338
个人防护装备	dust mask type N95 (US);Eyeshields;Gloves
危害码 (欧洲)	Xi:Irritant;
风险声明 (欧洲)	R36/37/38
安全声明 (欧洲)	S26-S36/37/39-S37/39
危险品运输编码	NONH for all modes of transport
WGK德国	3