10138-32-6

• 常用中文名：5-降冰片烯-2-羧酸乙酯
• 常用英文名：5-Norbornene-2-carboxylic acid, ethyl ester
• CAS号：10138-32-6
• 分子式：C₁₀H₁₄O₂
• 分子量：166.217
• 发布时间：2018-04-21 08:00:00
• 更新时间：2024-01-07 19:19:29

名称

• 中文名: 5-降冰片烯-2-羧酸乙酯
• 英文名: DiMethyl 5-norbornene-2,3-dicarboxylate
• 中文别名: 5-酒石酸-2-羧酸乙酯
• 英文别名: bicyclo[2.2.1]hept-5-ene-2-endo-carboxylic acid ethyl ester; Norborna-5-ene-2-carboxylic acid ethyl ester; ethyl bicyclo<2.2.1>hept-2-ene-5-carboxylate; 5-Norbornenecarboxylic acid ethyl ester; ETHYL 5-NORBORNENE-2-CARBOXYLATE (MIXTURE OF ENDO AND EXO); Ethyl bicyclo[2.2.1]-5-heptene-2-carboxylate; Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, ethyl ester; bicyclo[2.2.1]hept-5-ene-2-carboxylic acid,ethyl ester; ethyl endo-5-norbornene-2-carboxylate; 5-Norbornene-2-carboxylic acid,ethyl ester; Ethyl bicyclo[2.2.1]hept-5-ene-2-carboxylate; ethyl exo-5-norbornene-2-carboxylate; L55 A CUTJ FVO2; ethyl bicyclo[2.2.1]hept-5-ene-2-carboxlyate; 5-Norbornene-2-carboxylic acid, ethyl ester

物化性质

• 密度: 1.1±0.1 g/cm3
• 沸点: 216.2±19.0 °C at 760 mmHg
• 分子式: C₁₀H₁₄O₂
• 分子量: 166.217
• 闪点: 75.3±9.0 °C
• 精确质量: 166.099380
• PSA: 26.30000
• LogP: 2.27
• 蒸汽压: 0.1±0.4 mmHg at 25°C
• 折射率: 1.508
• 储存条件: 室温，干燥，密封
• 计算化学:

  1.疏水参数计算参考值（XlogP）:1.9

  2.氢键供体数量:0

  3.氢键受体数量:2

  4.可旋转化学键数量:3

  5.互变异构体数量:无

  6.拓扑分子极性表面积:26.3

  7.重原子数量:12

  8.表面电荷:0

  9.复杂度:220

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:3

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

毒性和生态

CHEMICAL IDENTIFICATION RTECS NUMBER : DT5200000 CHEMICAL NAME : Bicyclo(2.2.1)hept-5-ene-2-carboxylic acid, ethyl ester CAS REGISTRY NUMBER : 10138-32-6 LAST UPDATED : 199612 DATA ITEMS CITED : 2 MOLECULAR FORMULA : C10-H14-O2 MOLECULAR WEIGHT : 166.24 WISWESSER LINE NOTATION : L55 A CUTJ FVO2 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 4290 uL/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : >5 mL/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962

安全

• 危害码 (欧洲): Xi
• 海关编码: 2916209090

合成路线

542-92-7 140-88-5 ~93% 10138-32-6

文献：Grieco, Paul A.; Nunes, Joseph J.; Gaul, Micheal D. Journal of the American Chemical Society, 1990 , vol. 112, # 11 p. 4595 - 4596

42216-96-6 542-92-7 ~83% 10138-32-6

文献：Gassman, Paul G.; Chavan, Subhash P. Journal of Organic Chemistry, 1988 , vol. 53, # 10 p. 2392 - 2394

64-17-5 ~% 10138-32-6

文献：Russian Journal of Applied Chemistry, , vol. 79, # 10 p. 1621 - 1625

上下游产品

上游产品  4
542-92-7 140-88-5 42216-96-6 64-17-5
下游产品  1
27063-48-5

海关

海关编码	2916209090
中文概述	2916209090 其他（环烷、环烯、环萜烯）一元羧酸（包括酸酐、酰卤化物，过氧化物和过氧酸及该税号的衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:AB(入境货物通关单,出境货物通关单) 最惠国关税:6.5% 普通关税:30.0%
申报要素	品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装
监管条件	A.入境货物通关单 B.出境货物通关单
检验检疫	R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验
Summary	2916209090 other cyclanic, cyclenic or cyclotherpenic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0%