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| 中文名 | 2-氨基-5-氰基噻唑 |
|---|---|
| 英文名 | 2-Amino-5-cyanothiazole |
| 中文别名 |
2-氨基噻唑-5-甲腈
2-氨基噻唑-5-腈 2-氨基-1,3-噻唑-5-腈 |
| 英文别名 |
2-amino-1,3-thiazole-5-carbonitrile
2-Aminothiazole-5-carbonitrile |
| 密度 | 1.45g/cm3 |
|---|---|
| 沸点 | 330.4ºC at 760mmHg |
| 熔点 | 185-187ºC |
| 分子式 | C4H3N3S |
| 分子量 | 125.15200 |
| 闪点 | 153.6ºC |
| 精确质量 | 125.00500 |
| PSA | 90.94000 |
| LogP | 1.17818 |
| 折射率 | 1.636 |
| 储存条件 | 2-8°C |
|
Material Safety Data Sheet
Section1. Identification of the substance 2-Amino-5-cyanothiazole Product Name: Synonyms:2-Aminothiazole-5-carbonitrile Section2. Hazards identification Harmful by inhalation, in contact with skin, and if swallowed.
H302:Harmful if swallowed H318:Causes serious eye damage P280:Wear protective gloves/protective clothing/eye protection/face protection P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing Section3. Composition/information on ingredients. Ingredient name:2-Amino-5-cyanothiazole CAS number:51640-52-9 Section4. First aid measures Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing contaminated clothing and shoes. If irritation persists, seek medical attention. Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical attention. Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention. Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention. Section5. Fire fighting measures In the event of a fire involving this material, alone or in combination with other materials, use dry powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus should be worn. Section6. Accidental release measures Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national standards. Respiratory precaution:Wear approved mask/respirator Hand precaution:Wear suitable gloves/gauntlets Skin protection:Wear suitable protective clothing Eye protection:Wear suitable eye protection Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container for disposal. See section 12. Environmental precautions: Do not allow material to enter drains or water courses. Section7. Handling and storage This product should be handled only by, or under the close supervision of, those properly qualified Handling: in the handling and use of potentially hazardous chemicals, who should take into account the fire, health and chemical hazard data given on this sheet. Storage:Store in closed vessels, refrigerated. Section8. Exposure Controls / Personal protection Engineering Controls: Use only in a chemical fume hood. Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles. General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse. Section9. Physical and chemical properties Appearance:Not specified Boiling point:No data Melting point:No data Flash point:No data Density:No data Molecular formula: C4H3N3S Molecular weight: 125.2 Section10. Stability and reactivity Conditions to avoid: Heat, flames and sparks. Materials to avoid: Oxidizing agents. Possible hazardous combustion products: Carbon monoxide, nitrogen oxides, sulfur oxides. Section11. Toxicological information No data. Section12. Ecological information No data. Section13. Disposal consideration Arrange disposal as special waste, by licensed disposal company, in consultation with local waste disposal authority, in accordance with national and regional regulations. Section14. Transportation information UN Number:UN3439Class: 6.1Packing group: III Proper shipping name: NITRILES, TOXIC, SOLID, N.O.S. (2-Amino-5-cyanothiazole) Section15. Regulatory information No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302, or have known CAS numbers that exceed the threshold reporting levels established by SARA Title III, Section 313. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 符号 |
GHS05, GHS07 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H302-H318 |
| 警示性声明 | P280-P305 + P351 + P338 |
| 危害码 (欧洲) | Xi |
| 风险声明 (欧洲) | 22-41 |
| 安全声明 (欧洲) | 26-39 |
| 危险品运输编码 | NONH for all modes of transport |
| 海关编码 | 2934100090 |
|
~81%
51640-52-9 |
| 文献：Institut Pasteur De Lille; Centre National De La Recherche Scientifique; Universite De Lille 2, Universite Du Droit Et De La Sante; Institut National De La Sante Et De La Recherche Medicale (Inserm) Patent: US2011/136823 A1, 2011 ; Location in patent: Page/Page column 43-44 ; |
|
~95%
51640-52-9 |
| 文献：ASTRAZENECA AB; ASTRAZENECA UK LIMITED Patent: WO2007/31745 A1, 2007 ; Location in patent: Page/Page column 102-103 ; WO 2007/031745 A1 |
|
~20%
51640-52-9 |
| 文献：Li, Song; Zhao, Guoming; Xia, Guangqiang; Wang, Lili; Zheng, Zhibing; Xie, Yunde; Zhong, Wu; Xiao, Junhai; Li, Xingzhou; Cui, Hao Patent: US2010/87448 A1, 2010 ; Location in patent: Page/Page column 21 ; |
|
~88%
51640-52-9 |
| 文献：Francisco, Gerardo D.; Li, Zhong; Albright, J. Donald; Eudy, Nancy H.; Katz, Alan H.; Petersen, Peter J.; Labthavikul, Pornpen; Singh, Guy; Yang, Youjun; Rasmussen, Beth A.; Lin, Yang-I.; Mansour, Tarek S. Bioorganic and Medicinal Chemistry Letters, 2004 , vol. 14, # 1 p. 235 - 238 |
|
~%
51640-52-9 |
| 文献：Zhao, Matthew; Yin, Jingjun; Huffman, Mark A.; McNamara, James M. Tetrahedron, 2006 , vol. 62, # 6 p. 1110 - 1115 |
| 上游产品 5 | |
|---|---|
| 下游产品 2 | |
| 海关编码 | 2934100090 |
|---|---|
| 中文概述 | 2934100090. 结构上含有一个非稠合噻唑环的化合物(不论是否氢化). 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2934100090 other compounds containing an unfused thiazole ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0% |
