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13520-92-8生产厂家

13520-92-8价格

相关CAS号：
13520-92-8 15461-27-5
12205-73-1 14456-34-9
7791-08-4 37961-19-6
7787-59-9 49848-29-5
1311-10-0 53801-45-9

13520-92-8

13520-92-8结构式
13520-92-8结构式
  • 常用中文名：氯氧化锆,八水
  • 常用英文名：Zirconyl chloride octahydrate
  • CAS号：13520-92-8
  • 分子式：Cl2H16O9Zr
  • 分子量：322.25200
  • 相关类别： 无机化工 无机盐 金属卤化物及卤酸盐 金属氯化物及盐
  • 发布时间：2018-09-17 15:55:13
  • 更新时间：2024-01-02 15:57:14
  • 用途一：用做制造二氧化锆原料。也用做橡胶添加剂、涂料干燥剂、耐火材料、陶瓷、釉药和纤维的处理剂。
    用途二：其它锆产品的中间体，也作橡胶添加剂，油漆催干剂等。
    用途三：用作润滑脂添加剂、防水剂和鞣剂等。
    用途四：广泛用于橡胶添加剂、油漆催干剂、耐火材料和陶瓷釉等。

化源商城直购

中文名 氧氯化锆
英文名 Zirconyl chloride octahydrate
中文别名 氯氧化锆,八水
次氯酸锆
八水氧氯化锆
英文别名 Zirconium(IV) oxychloride octahydrate
oxozirconium,octahydrate,dihydrochloride
EINECS 231-717-9
Zirconium(IV) oxide chloride
MFCD00149898
密度 1.91
熔点 400°C (dec.)
分子式 Cl2H16O9Zr
分子量 322.25200
精确质量 319.92200
PSA 90.91000
LogP 0.74580
外观性状 固体
折射率 1.552
储存条件

应贮存在通风、干燥的库房中。运输时，要防止雨淋受潮，防日光曝晒。

稳定性

常温常压下稳定

避免的物料 水分/潮湿氧化物 碱金属。在150℃失去6个结晶水，210℃变成无水物。溶于水、甲醇、乙醇和醚，微溶于盐酸，不溶于其他有机溶剂。在空气中稳定。可溶于冷水、乙醇。加热则脱水、分解而转变为氧化锆。
水溶解性 SOLUBLE
分子结构

1、摩尔折射率：无可用的

2、摩尔体积（cm3/mol）：无可用的

3、等张比容（90.2K）：无可用的

4、表面张力（dyne/cm）：无可用的

5、介电常数：无可用的

6、极化率（10-24cm3）：无可用的

7、单一同位素质量：319.921839 Da

8、标称质量：320 Da

9、平均质量：322.2516 Da
计算化学

1.疏水参数计算参考值（XlogP）:无

2.氢键供体数量:10

3.氢键受体数量:9

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积25.1

7.重原子数量:12

8.表面电荷:0

9.复杂度:6

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:11
更多

1. 性状：白色正方晶系晶体

2. 密度（g/mL,25/4℃）：1.91

3. 熔点（ºC）：400

4. 溶解性：可溶解的
Section1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
Product identifiers
Product name: Zirconium atomic spectroscopy standard
concentrate 1.00 g Zr
: Fluka

Section2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Skin corrosion (Category 1B)
Specific target organ toxicity - single exposure (Category 3)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Causes burns. Irritating to respiratory system.
Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Signal wordDanger
Hazard statement(s)
Causes severe skin burns and eye damage.
May cause respiratory irritation.
Precautionary statement(s)
Avoid breathing vapours.
Wear protective gloves/ protective clothing/ eye protection/ face
protection.
P305 + P351 + P338IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor/ physician.
Supplemental Hazardnone
Statements
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
R-phrase(s)
R34Causes burns.
R37Irritating to respiratory system.
S-phrase(s)
S26In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S36/37/39Wear suitable protective clothing, gloves and eye/face protection.
S45In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
Other hazards - none
Section3. COMPOSITION/INFORMATION ON INGREDIENTS
Mixtures
Synonyms: Zirconium(IV) oxychloridesolution
Molecular Weight: 178,13 g/mol
ComponentClassificationConcentration
Hydrochloric acid
CAS-No.7647-01-0Skin Corr. 1B; STOT SE 3;10 - 20 %
EC-No.231-595-7H314, H335
Index-No.017-002-01-XC, R34 - R37
Zirconium dichloride oxide
CAS-No.13520-92-8Skin Corr. 1B; H3145 - 10 %
EC-No.231-717-9C, R34
For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16
Section4. FIRST AID MEASURES
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a
physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
water. Consult a physician.
Most important symptoms and effects, both acute and delayed
Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and
skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi,
pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath,
Headache, Nausea
Indication of any immediate medical attention and special treatment needed
no data available
Section5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Hydrogen chloride gas, Zirconium oxides
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available
Section6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.
Evacuate personnel to safe areas.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed
containers for disposal.
Reference to other sections
For disposal see section 13.
Section7. HANDLING AND STORAGE
Precautions for safe handling
Avoid inhalation of vapour or mist.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
Specific end uses
no data available
Section8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection
tested and approved under appropriate government standards such as NIOSH (US) or EN
166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
Section9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
a) AppearanceForm: liquid
Colour: yellow
b) Odourno data available
c) Odour Thresholdno data available
d) pHno data available
e) Melting point/freezingno data available
point
f) Initial boiling point and no data available
boiling range
g) Flash pointnot applicable
h) Evaporation rateno data available
i) Flammability (solid, gas) no data available
j) Upper/lowerno data available
flammability or
explosive limits
k) Vapour pressureno data available
l) Vapour densityno data available
m) Relative densityno data available
n) Water solubilityno data available
o) Partition coefficient: n- no data available
octanol/water
p) Autoignitionno data available
temperature
q) Decompositionno data available
temperature
r) Viscosityno data available
s) Explosive propertiesno data available
t) Oxidizing propertiesno data available
Other safety information
no data available
Section10. STABILITY AND REACTIVITY
Reactivity
no data available
Chemical stability
no data available
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
Bases, Alkali metals, Strong oxidizing agents, Metals, Amines, permanganates, e.g. potassium
permanganate, Fluorine, hexalithium disilicide
Hazardous decomposition products
Other decomposition products - no data available
Section11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC:3 - Group 3: Not classifiable as to its carcinogenicity to humans (Hydrochloric acid)
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation
May be harmful if inhaled. Material is extremely destructive to the tissue of
the mucous membranes and upper respiratory tract.
IngestionMay be harmful if swallowed. Causes burns.
SkinMay be harmful if absorbed through skin. Causes skin burns.
Eyes
Causes eye burns.
Signs and Symptoms of Exposure
Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and
skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi,
pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath,
Headache, Nausea
Additional Information
RTECS: Not available
Section12. ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
no data available
Other adverse effects
no data available
Section13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.
Section14. TRANSPORT INFORMATION
UN number
ADR/RID: 3264IMDG: 3264IATA: 3264
UN proper shipping name
ADR/RID: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Hydrochloric acid, Zirconium dichloride
oxide)
IMDG: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Hydrochloric acid, Zirconium dichloride
oxide)
IATA:Corrosive liquid, acidic, inorganic, n.o.s. (Hydrochloric acid, Zirconium dichloride oxide)
Transport hazard class(es)
ADR/RID: 8IMDG: 8IATA: 8
Packaging group
ADR/RID: IIIIMDG: IIIIATA: III
Environmental hazards
ADR/RID: noIMDG Marine pollutant: noIATA: no
Special precautions for user
no data available
Section15. REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
Chemical Safety Assessment
Causes severe skin burns and eye damage.
May cause respiratory irritation.
Skin Corr.Skin corrosion
STOT SESpecific target organ toxicity - single exposure
CCorrosive
R34Causes burns.
R37Irritating to respiratory system.
Further information
only.
The above information is believed to be correct but does not purport to be all inclusive and shall be
used only as a guide. The information in this document is based on the present state of our knowledge
and is applicable to the product with regard to appropriate safety precautions. It does not represent any

SECTION 16 - ADDITIONAL INFORMATION
N/A

毒理学数据:

急性毒性：小鼠口经LD50：990 mg/kg。 主要的刺激性影响： 在皮肤上面：在皮肤和粘膜上造成腐蚀性影响，刺激皮肤和粘膜； 在眼睛上面：强烈的腐蚀性影响，刺激的影响；没有已知的敏化影响。

生态学数据:

通常对水体是稍微有害的，不要将未稀释或大量产品接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境。

CHEMICAL IDENTIFICATION

RTECS NUMBER :
ZH7250000
CHEMICAL NAME :
Zirconium chloride oxide octahydrate
CAS REGISTRY NUMBER :
13520-92-8
LAST UPDATED :
199712
DATA ITEMS CITED :
24
MOLECULAR FORMULA :
Cl2-O-Zr.8H2-O
MOLECULAR WEIGHT :
322.28
WISWESSER LINE NOTATION :
.ZR..O.G2 QH8

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intradermal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
800 ug/kg
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Sense Organs and Special Senses (Ear) - effect, not otherwise specified Musculoskeletal - tumors

MUTATION DATA

TEST SYSTEM :
Rodent - mouse
DOSE/DURATION :
220 mg/kg
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 243,29,1990 *** REVIEWS *** ACGIH TLV-TWA 5 mg(Zr)/m3; STEL 10 mg(Zr)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 5 mg(Zr)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,285,1971 OSHA PEL (Gen Indu):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 5 mg(Zr)/m3;STEL 10 mg(Zr)/m3 JAN 1993 OEL-BELGIUM:TWA 5 mg(Zr)/m3;STEL 10 mg(Zr)/m3 JAN 1993 OEL-DENMARK:TWA 5 mg(Zr)/m3 JAN 1993 OEL-FINLAND:TWA 5 mg(Zr)/m3 JAN 1993 OEL-GERMANY:TWA 5 mg(Zr)/m3 JAN 1993 OEL-HUNGARY:STEL 5 mg(Zr)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 5 mg(Zr)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 5 mg(Zr)/m3 JAN 1993 OEL-SWITZERLAND:TWA 5 mg(Zr)/m3 JAN 1993 OEL-TURKEY:TWA 5 mg(Zr)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(Zr)/m3;STEL 10 mg(Zr)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

符号 GHS05
GHS05
信号词 Danger
危害声明 H314
警示性声明 P280-P305 + P351 + P338-P310
个人防护装备 Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
危害码 (欧洲) C:Corrosive;
风险声明 (欧洲) R22;R34
安全声明 (欧洲) S26-S36/37/39-S45-S27
危险品运输编码 UN 3264 8/PG 3
WGK德国 1
RTECS号 ZH7250000
包装等级 III
危险类别 8
上游产品  0

下游产品  1

氢氧化锆盐酸法锆英石与烧碱熔融，漂洗、除硅之后与硫酸作用，再加入氨水，得到氢氧化锆沉淀，用盐酸溶解沉淀物，得到氯氧化锆，经蒸发浓缩、冷却结晶、晶体粉碎，制得二氯氧化锆成品。

将30g四氯化锆、15mL的36％的盐酸及200mL的水混合，置于水浴上加热浓缩以达到饱和。冷却该溶液即可析出八水合物，过滤，用丙酮洗涤除去过剩的盐酸。


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