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| 中文名 | 三(环戊二烯)化钐 |
|---|---|
| 英文名 | tris(cyclopentadienyl)samarium |
| 中文别名 | 三(环戊二烯)钐(III) |
| 英文别名 |
Samarium (III) tris(cyclopentadienyl)
samarium tris(cyclopentadienide) tris(eta5-cyclopenta-2,4-dien-1-yl)samarium tris(cyclopentadienyl)samarium(III) MFCD00013755 Samarium tricyclopentadienide EINECS 215-075-7 |
| 沸点 | 41.5ºC at 760 mmHg |
|---|---|
| 熔点 | 356ºC |
| 分子式 | C15H15Sm |
| 分子量 | 345.64000 |
| 精确质量 | 347.03700 |
| LogP | 3.06450 |
| 蒸汽压 | 418mmHg at 25°C |
| 储存条件 | 保持贮藏器密封、储存在阴凉、干燥的地方，确保工作间有良好的通风或排气装置 |
| 稳定性 | 如果遵照规格使用和储存则不会分解，未有已知危险反应，避免氧化物、水分/潮湿、空气 |
| 分子结构 | 1、摩尔折射率：无可用的 2、摩尔体积（cm3/mol）：无可用的 3、等张比容（90.2K）：无可用的 4、表面张力（dyne/cm）：无可用的 5、介电常数：无可用的 6、极化率（10-24cm3）：无可用的 7、单一同位素质量：347.037075 Da 8、标称质量：347 Da 9、平均质量：345.6396 Da |
| 计算化学 | 1、 氢键供体数量：0 2、 氢键受体数量：15 3、 可旋转化学键数量：0 4、 拓扑分子极性表面积（TPSA）：0 5、 重原子数量：16 6、 表面电荷：-15 7、 复杂度：58.1 8、 同位素原子数量：0 9、 确定原子立构中心数量：0 10、 不确定原子立构中心数量：0 11、 确定化学键立构中心数量：0 12、 不确定化学键立构中心数量：0 13、 共价键单元数量：4 |
| 更多 | 1. 性状：粉末 2. 密度（g/mL,25℃）：未确定 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：>350 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC,0.05mmHg）：未确定 7. 折射率（n20/D）：未确定 8. 闪点（ºF）：38 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（mmHg,20ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：与水反应 |
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Section 1: Product Identification Chemical Name:Tris(cyclopentadienyl)samarium(99.9%-Sm) (REO) CAS Registry Number:1298-55-1 Formula:(C5H5)3Sm EINECS Number:215-55-1 Chemical Family:metallocene Synonym:tris(eta5-2,4-cyclopentadien-1-yl)samarium
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound1298-55-1100%no datano data Section 3: Hazards Identification Emergency Overview:May be irritating to skin, eyes, and mucous membranes. May be harmful if swallowed. Primary Routes of Exposure:Ingestion, inhalation Eye Contact:May cause slight to mild irritation of the eyes. Skin Contact:May cause slight to mild irritation of the skin. Inhalation:(If dust) May be irritating to the nose, mucous membranes and respiratory tract. Ingestion:No information on the physiological effects of ingestion. Acute Health Affects:May be irritating to skin, eyes and respiratory tract. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in Inhalation: breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide or dry powder If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes. Decomposion Products: Unusual Fire or Explosion Hazards: Flammable solid. Dust may form explosive mixtures with air. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non-combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Store and handle the material under an inert atmosphere of dry nitrogen or argon. Keep away from heat, air Handling and Storage: and moisture. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear appropriate chemical resistant gloves and protective clothing. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:orange powder Molecular Weight:345.69 Melting Point:356° Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air sensitive, moisture sensitive Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:Air and moisture. Keep away from ignition sources. Incompatibility:halogens and oxidizing agents Decomposition Products:carbon monoxide, carbon dioxide, samarium oxide and organic fumes. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data available Mutagenic Effects:no data available Tetratogenic Effects:no data available SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Flammable solids, Organic, N.O.S. Hazard Class (CFR):4.1 Additional Hazard Class (CFR):NA Packaging Group (CFR):II UN ID Number (CFR):UN# 1325 Shipping Name (IATA):Flammable solid, Organic, N.O.S. Hazard Class (IATA):4.1 Additional Hazard Class (IATA):NA Packaging Group (IATA):II UN ID Number (IATA):UN# 1325 SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 对是水稍微有危害的不要让未稀释或大量的产品接触地下水、水道或者污水系统，若无政府许可，勿将材料排入周围环境。
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| 危害码 (欧洲) | F: Flammable; |
|---|---|
| 风险声明 (欧洲) | R11 |
| 安全声明 (欧洲) | 43-7/8 |
| 危险品运输编码 | UN 3395 4 |
| 包装等级 | III |
| 危险类别 | 4.1 |
| 海关编码 | 2902199090 |
| 海关编码 | 2902199090 |
|---|---|
| 中文概述 | 2902199090 其他环烷烃、环烯烃及环萜烯。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:2.0%。普通关税:30.0% |
| 申报要素 | 品名, 成分含量 |
| Summary | 2902199090 other cyclanes, cyclenes and cyclotherpenes。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0% |