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| 中文名 | N,N-二乙基对苯二胺草酸盐 |
|---|---|
| 英文名 | N,N-Diethyl-p-phenylenediamine oxalate |
| 中文别名 | N,N-二乙基一对苯二胺 |
| 英文别名 |
DPD OXALATE
DIETHYL-P-PHENYLENEDIAMINE OXALATE MFCD00070242 N,N-DIETHYL-1,4-PHENYLENEDIAMINE OXALATE P-AMINO-N,N-DIETHYLANILINE OXALATE N,N-Diethylbenzene-1,4-diamine ethanedioate (1:1) N,N-Diethyl-1,4-benzenediamine ethanedioate (1:1) 1,4-Benzenediamine, N,N-diethyl-, ethanedioate (1:1) EINECS 263-662-1 1,4-Benzenediamine, N,N-diethyl-, ethanedioate (2:1) N,N-Diethylbenzene-1,4-diamine oxalic acid N,N-Diethyl-1,4-phenyldiamineoxalate bis(N,N-diethylbenzene-p-diamine) oxalate DIETHYL(N,N-)-P-PHENYLENEDIAMINE OXALATE N,N-DIETHYL-PHENYLENEDIAMINE OXALATE N,N-Diethyl-p-phenylenediamineoxalate |
| 沸点 | 261ºC at 760 mmHg |
|---|---|
| 熔点 | 145-150 °C(lit.) |
| 分子式 | C12H18N2O4 |
| 分子量 | 254.282 |
| 闪点 | 108.9ºC |
| 精确质量 | 254.126663 |
| PSA | 103.86000 |
| LogP | 1.85180 |
| 外观性状 | 灰白色晶体 |
| 储存条件 | 存放在密封容器内，并放在阴凉，干燥处。 |
| 稳定性 | 常温常压下稳定，远离氧化剂。 |
| 计算化学 | 1、 疏水参数计算参考值（XlogP）： 2、 氢键供体数量：4 3、 氢键受体数量：8 4、 可旋转化学键数量：7 5、 拓扑分子极性表面积（TPSA）：133 6、 重原子数量：30 7、 表面电荷：0 8、 复杂度：185 9、 同位素原子数量：0 10、 确定原子立构中心数量：0 11、 不确定原子立构中心数量：0 12、 确定化学键立构中心数量：0 13、 不确定化学键立构中心数量：0 14、 共价键单元数量：3 |
| 更多 | 1. 性状：灰色或者浅棕色粉末。 2. 密度（g/mL,25/4℃）：未确定 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：145-150 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC,5.2kPa）：未确定 7. 折射率：未确定 8. 闪点（ºC）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 。 |
Synonym:p-Amino-diethylaniline oxalate Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38 20 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Harmful by inhalation. Potential Health Effects Eye: Causes eye irritation. May cause chemical conjunctivitis. Skin: Causes skin irritation. The toxicological properties of this material have not been fully investigated. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. Inhalation: Dust is irritating to the respiratory tract. The toxicological properties of this substance have not been fully investigated. Can produce delayed pulmonary edema. Chronic: Effects may be delayed. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. Notes to Physician: Treat symptomatically and supportively. Antidote: The use of calcium gluconate to precipitate the oxalate should be determined by only qualified medical personnel. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use only in a well-ventilated area. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Handle under an inert atmosphere. Storage: Store in a cool, dry place. Store in a tightly closed container. Store under an inert atmosphere. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 62637-92-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: white to off-white Odor: weak odor pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 159 deg C Autoignition Temperature: Not applicable. Flash Point: Not applicable. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: > 160 deg C Solubility in water: 3.3% in water. Specific Gravity/Density: Not available. Molecular Formula: C22H34N4O4 Molecular Weight: 418.54 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Dust generation, excess heat, prolonged exposure to air. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 62637-92-7 unlisted. LD50/LC50: Not available. Carcinogenicity: N,N-Diethyl-P-Phenylenediamine Oxalate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20 Harmful by inhalation. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 22 Do not breathe dust. S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 62637-92-7: No information available. Canada CAS# 62637-92-7 is listed on Canada's DSL List. CAS# 62637-92-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 62637-92-7 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 通常对水是不危害的，若无政府许可，勿将材料排入周围环境。
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| 危害码 (欧洲) | Xn:Harmful; |
|---|---|
| 风险声明 (欧洲) | R21/22;R36 |
| 安全声明 (欧洲) | S26-S36 |
| 危险品运输编码 | UN 1673 6.1/PG 3 |
| WGK德国 | 3 |
| 包装等级 | III |
| 危险类别 | 6.1(b) |