54557-81-2

• 常用中文名：4-[3,4-(乙烯二氧基)苯基]-4-氧代丁酸
• 常用英文名：4-[3,4-(ethylenedioxy)phenyl]-4-oxobutyric acid
• CAS号：54557-81-2
• 分子式：C₁₂H₁₂O₅
• 分子量：236.22100
• 发布时间：2018-12-22 18:54:50
• 更新时间：2025-08-26 10:17:25

名称

• 中文名: 4-(2,3-二氢-1,4-苯并二氧-6-基)-4-氧丁酸
• 英文名: 4-(2,3-dihydro-1,4-benzodioxin-6-yl)-4-oxobutanoic acid
• 英文别名: 4-(2H,3H-benzo[3,4-e]1,4-dioxin-6-yl)-4-oxobutanoic acid; 4-[3,4-(Ethylenedioxy)Phenyl]-4-Oxobutyric Acid; 4-(2,3-Dihydro-benzo[1,4]dioxin-6-yl)-4-oxo-buttersaeure; MFCD00168683; 4-(2,3-Dihydro-benzo[1,4]dioxin-6-yl)-4-oxo-butyric acid; 3-(6-<1,4>benzodioxanylcarbonyl)propionic acid

物化性质

• 密度: 1.33g/cm3
• 沸点: 475.6ºC at 760 mmHg
• 熔点: 138ºC
• 分子式: C₁₂H₁₂O₅
• 分子量: 236.22100
• 闪点: 189.1ºC
• 精确质量: 236.06800
• PSA: 72.83000
• LogP: 1.50530
• 折射率: 1.565
• 储存条件: 室温，干燥，密封

MSDS

Name: 4-(2 3-Dihydro-1 4-benzodioxin-6-yl)-4-oxobutanoic acid 97% Material Safety Data Sheet Synonym: 3-(3,4-Ethylenedioxybenzoyl)propionic aci CAS: 54557-81-2 Section 1 - Chemical Product MSDS Name:4-(2 3-Dihydro-1 4-benzodioxin-6-yl)-4-oxobutanoic acid 97% Material Safety Data Sheet Synonym:3-(3,4-Ethylenedioxybenzoyl)propionic aci Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 54557-81-2 4-(2,3-Dihydro-1,4-benzodioxin-6-yl)-4 97% unlisted Hazard Symbols: None Listed. Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Not available. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 54557-81-2: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 137 - 139 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C12H12O5 Molecular Weight: 236 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 54557-81-2 unlisted. LD50/LC50: Not available. Carcinogenicity: 4-(2,3-Dihydro-1,4-benzodioxin-6-yl)-4-oxobutanoic acid - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 54557-81-2: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 54557-81-2 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 54557-81-2 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi
• 海关编码: 2932999099

合成路线

951889-31-9 ~91% 54557-81-2

文献：Harrak; Rosell; Daidone; Plescia; Schillaci; Pujol Bioorganic and Medicinal Chemistry, 2007 , vol. 15, # 14 p. 4876 - 4890

108-30-5 493-09-4 ~% 54557-81-2

文献：Journal of the University of Bombay, Science: Physical Sciences, Mathematics, Biological Sciences and Medicine, , vol. 18/5 A, p. 1,4

上下游产品

上游产品  2
108-30-5 493-09-4
下游产品  0

海关

海关编码	2932999099
中文概述	2932999099. 其他仅含氧杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%