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| 中文名 | 顺式-2,6-二甲基吗啉 |
|---|---|
| 英文名 | cis-2,6-Dimethylmorpholine |
| 中文别名 |
顺式2,6-二甲基吗啉
顺-2,6-二甲基吗啉 |
| 英文别名 |
(2R,6S)-2,6-Dimethylmorpholine
trans-2,6-dimethylmorpholine MFCD00078428 (2S,6R)-2,6-dimethylmorpholine MORPHOLINE, 2,6-DIMETHYL-, CIS- cis 2,6-dimethylmorpholine Morpholine, 2,6-dimethyl-, (2R,6S)- dimethylamine hydrochloride EINECS 229-353-0 2,6-cis-dimethylmorpholine R,R-2,6-dimethylmorpholine CIS-2,6-DIMETHYL MORPHOLINE |
| 密度 | 0.9±0.1 g/cm3 |
|---|---|
| 沸点 | 146.6±0.0 °C at 760 mmHg |
| 熔点 | -85ºC |
| 分子式 | C6H13NO |
| 分子量 | 115.174 |
| 闪点 | 48.9±0.0 °C |
| 精确质量 | 115.099716 |
| PSA | 21.26000 |
| LogP | -0.10 |
| 外观性状 | 无色和油性液体 |
| 蒸汽压 | 4.6±0.2 mmHg at 25°C |
| 折射率 | 1.406 |
| 储存条件 | Flammables area |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 10 21/22 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Flammable. Harmful in contact with skin and if swallowed. Causes burns.Moisture sensitive. Potential Health Effects Eye: Causes eye burns. Skin: Harmful if absorbed through the skin. Causes skin burns. Ingestion: Harmful if swallowed. Causes gastrointestinal tract burns. Inhalation: Causes chemical burns to the respiratory tract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. May cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Cover with sand, dry lime or soda ash and place in a closed container for disposal. Remove all sources of ignition. Use a spark-proof tool. Isolate area and deny entry. Section 7 - HANDLING and STORAGE Handling: Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Storage: Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Flammables-area. Store below 35C. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 6485-55-8: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: clear colorless Odor: Not available. pH: 11.8 (100 g/l (20C)) Vapor Pressure: 7mbar @20 deg C Viscosity: 5.3 mPa.s @20 deg C Boiling Point: 140 - 142 deg C @760mmHg Freezing/Melting Point: -85 deg C Autoignition Temperature: 280 deg C ( 536.00 deg F) Flash Point: 41 deg C ( 105.80 deg F) Explosion Limits, lower: 1.6 Vol % Explosion Limits, upper: 12.9 Vol % Decomposition Temperature: Solubility in water: Miscible. Specific Gravity/Density: 0.930 Molecular Formula: C6H13NO Molecular Weight: 115.18 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, ignition sources, exposure to moist air or water. Incompatibilities with Other Materials: Acids. Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 6485-55-8 unlisted. LD50/LC50: Not available. Carcinogenicity: cis-2,6-Dimethylmorpholine - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Other No information available. Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S.* Hazard Class: 8 (3) UN Number: 2734 Packing Group: II IMO Shipping Name: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. Hazard Class: 8 (3) UN Number: 2734 Packing Group: II RID/ADR Shipping Name: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. Hazard Class: 8 (3) UN Number: 2734 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 10 Flammable. R 21/22 Harmful in contact with skin and if swallowed. R 34 Causes burns. Safety Phrases: S 16 Keep away from sources of ignition - No smoking. S 23 Do not inhale gas/fumes/vapour/spray. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 6485-55-8: 1 Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 6485-55-8 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 6485-55-8 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 危害码 (欧洲) | C: Corrosive; |
|---|---|
| 风险声明 (欧洲) | R10;R21;R37/38;R41 |
| 安全声明 (欧洲) | S26-S36/37/39 |
| 危险品运输编码 | UN 1993 |
| RTECS号 | QE1750000 |
| 包装等级 | III |
| 危险类别 | 3 |
| 海关编码 | 2934999090 |
| 海关编码 | 2934999090 |
|---|---|
| 中文概述 | 2934999090. 其他杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0% |