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| 中文名 | 四丙基高氯酸铵 |
|---|---|
| 英文名 | Tetrapropylammonium perchlorate |
| 英文别名 |
tetrapropylazanium,perchlorate
n,n,n-tripropylpropan-1-aminium perchlorate MFCD00041979 N,N,N-Tripropyl-1-propanaminium perchlorate EINECS 239-874-5 |
| 熔点 | 238-240ºC |
|---|---|
| 分子式 | C12H28ClNO4 |
| 分子量 | 285.808 |
| 精确质量 | 285.170685 |
| PSA | 74.27000 |
| LogP | 3.65750 |
| 外观性状 | 白色至灰白色晶体 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:4 4.可旋转化学键数量:8 5.互变异构体数量:无 6.拓扑分子极性表面积74.3 7.重原子数量:18 8.表面电荷:0 9.复杂度:176 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:2 |
| 更多 | 1.性状：未确定 2.密度（g/mL,25/4℃）：未确定 3.相对蒸汽密度（g/mL,空气=1）：未确定 4.熔点（ºC）：238-240 5.沸点（ºC,常压）：未确定 6.沸点（ºC,5.2kPa）：未确定 7.折射率：未确定 8.闪点（ºC）：未确定 9.比旋光度（º）：未确定 10.自燃点或引燃温度（ºC）：未确定 11.蒸气压（kPa,25ºC）：未确定 12.饱和蒸气压（kPa,60ºC）：未确定 13.燃烧热（KJ/mol）：未确定 14.临界温度（ºC）：未确定 15.临界压力（KPa）：未确定 16.油水（辛醇/水）分配系数的对数值：未确定 17.爆炸上限（%,V/V）：未确定 18.爆炸下限（%,V/V）：未确定 19.溶解性：未确定 |
Synonym:1-Propanaminium, N,N,N-Tripropyl-, Perchlorate Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 8 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Contact with combustible material may cause fire.The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water with caution and in flooding amounts. Extinguishing Media: Use agent most appropriate to extinguish fire. Contact professional fire-fighters immediately. Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid contact with clothing and other combustible materials. Avoid ingestion and inhalation. Storage: Keep away from heat, sparks, and flame. Do not store near combustible materials. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 15780-02-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear a chemical apron. Wear appropriate protective clothing to prevent skin exposure. Respirators: Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: almost white Odor: ammonia-like pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 240-242C Autoignition Temperature: Not applicable. Flash Point: Not applicable. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C12H28ClNO4 Molecular Weight: 285.80 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable. Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, ignition sources, dust generation, combustible materials, reducing agents, strong oxidants. Incompatibilities with Other Materials: Reducing agents, finely powdered metals, organic materials, strong acids. Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide, oxides of chlorine. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 15780-02-6 unlisted. LD50/LC50: Not available. Carcinogenicity: 1-Propanaminium, N,N,N-Tripropyl-, Perchlorate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: OXIDIZING SOLID, N.O.S.* Hazard Class: 5.1 UN Number: 1479 Packing Group: III IMO Shipping Name: OXIDIZING SOLID, N.O.S. Hazard Class: 5.1 UN Number: 1479 Packing Group: III RID/ADR Shipping Name: OXIDIZING SOLID, N.O.S. Hazard Class: 5.1 UN Number: 1479 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: O Risk Phrases: R 8 Contact with combustible material may cause fire. Safety Phrases: S 17 Keep away from combustible material. S 28A After contact with skin, wash immediately with plenty of water. S 37 Wear suitable gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 15780-02-6: No information available. Canada CAS# 15780-02-6 is listed on Canada's DSL List. CAS# 15780-02-6 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 15780-02-6 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 危害码 (欧洲) | Xi: Irritant;O: Oxidizing agent; |
|---|---|
| 风险声明 (欧洲) | R8;R36/37/38 |
| 安全声明 (欧洲) | 37/39-26-17 |
| 危险品运输编码 | UN 1479 |
| 包装等级 | III |
| 危险类别 | 5.1 |
| 海关编码 | 2923900090 |
|
~%
15780-02-6 |
| 文献：Collection of Czechoslovak Chemical Communications, , vol. 50, # 11 p. 2525 - 2534 |
|
~%
15780-02-6 |
| 文献：Journal of Chemical and Engineering Data, , vol. 55, # 5 p. 1887 - 1892 |
| 海关编码 | 2923900090 |
|---|---|
| 中文概述 | 2923900090 其他季铵盐及季铵碱。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2923900090 other quaternary ammonium salts and hydroxides。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0% |
