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| 中文名 | 硒化汞 |
|---|---|
| 英文名 | mercury (ii) selenide |
| 英文别名 |
EINECS 243-910-5
MFCD00049743 |
| 密度 | 8.27 g/mL at 25 °C(lit.) |
|---|---|
| 分子式 | HHgSe |
| 分子量 | 280.55800 |
| 精确质量 | 282.89500 |
| 储存条件 | 保持贮藏器密封 放入紧密的贮藏器内，储存在阴凉，干燥的地方 |
| 稳定性 | 如果遵照规格使用和储存则不会分解 避免接触氧化物，酸 在氮、二氧化碳气氛中或真空加热至600℃时升华，升华物为紫黑色。不溶于水，溶于硒氢酸铵溶液。 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:0 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积0 7.重原子数量:2 8.表面电荷:0 9.复杂度:2 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1.性状：灰黑色立方晶体。有毒。 2.密度（g/mL,25/4℃）：8.266 3.相对蒸汽密度（g/mL,空气=1）：未确定 4.熔点（ºC）：600-650 5.沸点（ºC,常压）：未确定 6.沸点（ºC,5.2kPa）：未确定 7.折射率：未确定 8.闪点（ºC）：未确定 9.比旋光度（º）：未确定 10.自燃点或引燃温度（ºC）：未确定 11.蒸气压（kPa,25ºC）：未确定 12.饱和蒸气压（kPa,60ºC）：未确定 13.燃烧热（KJ/mol）：未确定 14.临界温度（ºC）：未确定 15.临界压力（KPa）：未确定 16.油水（辛醇/水）分配系数的对数值：未确定 17.爆炸上限（%,V/V）：未确定 18.爆炸下限（%,V/V）：未确定 19.溶解性：未确定 |
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Section 1: Product Identification Chemical Name:Mercury (II) selenide (99.99%-Hg) PURATREM CAS Registry Number:20601-83-6 Formula:HgSe EINECS Number:243-910-5 Chemical Family:metal chalcogenides Synonym:Mercuric selenide
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound20601-83-6100%0.025mg/m30.1mg/m3 Section 3: Hazards Identification Toxic by inhalation, in contact with skin and if swallowed. Possible risk of harm to the unborn child and Emergency Overview: impaired fertility. Danger of cumulative effects. Primary Routes of Exposure:Ingestion, Skin, inhalation of dust. Eye Contact:May cause mild to severe irritation of the eyes. May deposit mercury in the lens of the eye. Skin Contact:May cause mild to severe irritation of the skin. Toxic in contact with skin. Toxic by inhalation. Dust may cause severe respiratory and gastrointestinal distress and may damage the Inhalation: central nervous system. Toxic if swallowed. Lack of appetite, abdominal cramps, vomiting, kidney failure, paralysis. Mercury bonds to Ingestion: thiol groups of protein. Toxic by inhalation, in contact with skin and if swallowed. Possible risk of harm to the unborn child. Danger of Acute Health Affects: cumulative effects. The chronic effects of mercury poisoning include stomatitis, tremors, psychic disturbances, excessive Chronic Health Affects:salivation, dermatitis, and pain on chewing. Other effects include loss of memory, insomnia, irritability and depression, speech and gait impairment. May impair fertility. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self- contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic fumes containing mercury. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a cool, dry place in a tightly sealed container. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:gray pwdr. Molecular Weight:279.55 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:azides, fulminates, active metals, and strong oxidizing agents. Decomposition Products:mercury and selenium fumes SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data Mutagenic Effects:No data Tetratogenic Effects:No data SECTION 12: Ecological Information Avoid release to the environment. Very toxic to aquatic organisms May cause long-term adverse effects in the Ecological Information: aquatic environment. SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Mercury compounds, solid, N.O.S. Hazard Class (CFR):6.1 Additional Hazard Class (CFR):NA Packaging Group (CFR):II UN ID Number (CFR):UN# 2025 Shipping Name (IATA):Mercury compound, solid, N.O.S. Hazard Class (IATA):6.1 Additional Hazard Class (IATA):NA Packaging Group (IATA):II UN ID Number (IATA):UN# 2025 SECTION 15: Regulatory Information TSCA:Listed in the TSCA inventory. SARA (Title 313):Title compound: See category codes N458 and N725 for reporting. Second Ingredient:None SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 对水是极其危害的，若无政府许可，勿将材料排入周围环境
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| 危害码 (欧洲) | T: Toxic; |
|---|---|
| 风险声明 (欧洲) | 23/24/25-33-36/37/38 |
| 安全声明 (欧洲) | 22-26-36/37/39-45 |
| 危险品运输编码 | UN 2025 6.1/PG 2 |
| WGK德国 | 3 |
| 包装等级 | II |
| 危险类别 | 6.1 |