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| 中文名 | 2-氰乙基 N,N-二异丙基氯代亚磷酰胺 |
|---|---|
| 英文名 | 2-Cyanoethyl N,N-diisopropylchlorophosphoramidite |
| 中文别名 |
2-氰乙基N,N-二异丙基氯亚磷酰胺
氯代(二异丙基氨基)-β-氰基乙氧基膦 2-氰基乙基二异丙基氯代亚磷酰胺 |
| 英文别名 |
Phosphoramidochloridous acid, N,N-bis(1-methylethyl)-, 2-cyanoethyl ester
2-CYANOETHYL N,N-DIISOPROPYLCHLOROPHOSPHORAMIDITE 2-cyanoethyl dipropan-2-ylphosphoramidochloridoite 2-Cyanoethyldiisopropylchlorophosphoramidite 2-Cyanoethyl diisopropylphosphoramidochloridoite 2-Cyanoethyl diisopropylamidochlorophosphite MFCD00011544 3-[chloro-[di(propan-2-yl)amino]phosphanyl]oxypropanenitrile |
| 密度 | 1.061 g/mL at 25 °C(lit.) |
|---|---|
| 沸点 | 343.8±0.0 °C at 760 mmHg |
| 分子式 | C9H18ClN2OP |
| 分子量 | 236.679 |
| 闪点 | 135.8±28.4 °C |
| 精确质量 | 236.084534 |
| PSA | 49.85000 |
| LogP | 3.46 |
| 蒸汽压 | 0.0±0.7 mmHg at 25°C |
| 折射率 | n20/D 1.479 |
| 储存条件 | -20°C冷藏、密闭、干燥处 |
| 稳定性 | 按规定使用和贮存的不会分解，避碱、酒精、热 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:2.3 2.氢键供体数量:0 3.氢键受体数量:3 4.可旋转化学键数量:6 5.互变异构体数量:无 6.拓扑分子极性表面积36.3 7.重原子数量:14 8.表面电荷:0 9.复杂度:194 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:1 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：浅黄色液体 2. 密度（g/mL25ºC）：1，061 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC 0,11 hPa）：103-105 7. 折射率：n20/D 1.479 8. 闪点（ºF）：110 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（kPa,）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（正辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
Synonym:Chloro(diisopropylamino)--cyanoethoxyphosphin Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 20/21/22 29 34 5 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Contact with water liberates toxic gas. Causes burns. Heating may cause an explosion. Potential Health Effects Eye: Causes eye burns. Skin: Harmful if absorbed through the skin. Causes skin burns. Ingestion: Harmful if swallowed. Causes gastrointestinal tract burns. Inhalation: Harmful if inhaled. Causes chemical burns to the respiratory tract. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. May explode when heated. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER! Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Use a spark-proof tool. Section 7 - HANDLING and STORAGE Handling: Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Storage: Store in a tightly closed container. Store in a dry area. Corrosives area. Deep freeze (below -20C). Store under nitrogen. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels. Exposure Limits CAS# 89992-70-1: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: 110 deg C ( 230.00 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: 1.061 Molecular Formula: C9H18ClN2OP Molecular Weight: 236.68 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Heating may cause an explosion. Moisture sensitive. Conditions to Avoid: Incompatible materials, exposure to moist air or water, heat. Incompatibilities with Other Materials: Strong oxidizing agents, strong bases, alcohols. Hazardous Decomposition Products: Hydrogen chloride, nitrogen oxides, carbon monoxide, oxides of phosphorus, carbon dioxide. Hazardous Polymerization: Will not occur. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 89992-70-1 unlisted. LD50/LC50: Not available. Carcinogenicity: 2-Cyanoethyl N,N-diisopropylchlorophosphoramidite - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.* Hazard Class: 8 UN Number: 3265 Packing Group: II IMO Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. Hazard Class: 8 UN Number: 3265 Packing Group: II RID/ADR Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. Hazard Class: 8 UN Number: 3265 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 29 Contact with water liberates toxic gas. R 34 Causes burns. R 5 Heating may cause an explosion. Safety Phrases: S 8 Keep container dry. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 89992-70-1: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 89992-70-1 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 89992-70-1 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 符号 |
GHS02, GHS05 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H250-H314 |
| 警示性声明 | P222-P231-P280-P305 + P351 + P338-P310-P422 |
| 个人防护装备 | Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| 危害码 (欧洲) | C:Corrosive; |
| 风险声明 (欧洲) | R20/21/22;R29;R34;R5 |
| 安全声明 (欧洲) | S26-S36/37/39-S45-S8 |
| 危险品运输编码 | UN 2845 4.2/PG 1 |
| WGK德国 | 3 |
| 包装等级 | II |
| 危险类别 | 8 |