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| 中文名 | 五羰基氯铼(I) |
|---|---|
| 英文名 | Rhenium pentacarbonyl chloride |
| 中文别名 |
氯化五羰基铼
五羰基氯化铼(I) 氯代五羰基铼(I) |
| 英文别名 |
MFCD00013296
carbon monoxide,chlororhenium Chloropentacarbonylrhenium(I) EINECS 237-948-1 |
| 分子式 | C5ClO5Re |
|---|---|
| 分子量 | 361.71000 |
| 精确质量 | 361.89900 |
| 外观性状 | crystal | off-white |
| 储存条件 | 常温密闭避光，通风干燥 |
| 稳定性 | 常温常压下稳定 避免的物料：水分/潮湿 空气 氧化物 |
| 水溶解性 | Insoluble in water. |
| 分子结构 | 1、摩尔折射率：无可用的 2、摩尔体积（cm3/mol）：无可用的 3、等张比容（90.2K）：无可用的 4、表面张力（dyne/cm）：无可用的 5、介电常数：无可用的 6、极化率（10-24cm3）：无可用的 7、单一同位素质量：361.899026 Da 8、标称质量：362 Da 9、平均质量：361.7105 Da |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:5 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积5 7.重原子数量:12 8.表面电荷:0 9.复杂度:12 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:6 |
| 更多 | 1. 性状：米色粉末 2. 密度（g/mL,25/4℃）：未确定 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC,5.2kPa）：未确定 7. 折射率：未确定 8. 闪点（ºC）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
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Section 1: Product Identification Chemical Name:Rhenium pentacarbonyl chloride, 98% CAS Registry Number:14099-01-5 Formula:Re(CO)5Cl EINECS Number:237-948-1 Chemical Family:metal carbonyl complexes Synonym:none
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound14099-01-5100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and respiratory tract. Primary Routes of Exposure:Inhalation Eye Contact:May cause mild irritation to the eyes. Skin Contact:Causes mild irritation to the skin. Inhalation:Irritating to the nose mucous membranes and respiratory tract. Ingestion:No specific information is available on the physiological effects of ingestion. May be harmful if swallowed. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Inhalation could lead to headache and dizziness. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 15 minutes. A victim will need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area immediately with water. Remove contaminated clothing if necessary. Seek medical Skin Exposure: assistance if irritation persists. Remove victim to fresh air immediately. Keep the victim lying down and warm. Give oxygen as soon as Inhalation: possible. If shock occurs, respond with appropriate first aid. Transport the victim to a hospital. Seek medical attention immediately. Keep the victim calm. Give water to dilute the toxin (only if conscious). Ingestion: Induce vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:carbon dioxide, dry chemical or foam If involved in a fire, fire fighters should be equipped with a NIOSH-approved positive pressure self-contained Special Fire Fighting Procedures: breathing apparatus. Hazardous Combustion andcarbon monoxide, carbon dioxide, and rhenium oxide dust. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small quantities can be mixed with sodium carbonate or vermiculite and swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a cool, dry, well-ventilated area away from heat and direct sunlight. Keep containers tightly sealed. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling chemical substances. Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. Ventilation:This product should be handled in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance 29 CFR 1910.134. Ventilation:This product should be handled in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:off-white xtl. Molecular Weight:361.71 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:oxidizing agents, halogens and active metals Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, hydrogen chloride, and rhenium oxide. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data available Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No information available. SECTION 13: Disposal Considerations Disposal:Dispose of this material according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
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毒理学数据: 1、急性毒性：主要的刺激性影响： 在皮肤上面：刺激皮肤和粘膜； 在眼睛上面：刺激的影响；没有已知的敏化影响。 生态学数据: 通常对水体是稍微有害的，不要将未稀释或大量产品接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境。
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| 危害码 (欧洲) | T: Toxic; |
|---|---|
| 风险声明 (欧洲) | 23/24/25-36/37/38 |
| 安全声明 (欧洲) | 26-28-36/37/39-45 |
| 危险品运输编码 | UN 3288 6.1/PG 3 |
| WGK德国 | 3 |
| 包装等级 | II |
| 危险类别 | 6.1 |
| 海关编码 | 28369917 |
