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2081-12-1生产厂家

2081-12-1价格

2081-12-1

2081-12-1结构式
2081-12-1结构式

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中文名 叔丁醇锆
英文名 zirconium(iv) tert-butoxide
中文别名 四叔丁氧化锆
英文别名 Zirconium(4+) tetrakis(2-methyl-2-propanolate)
ZIRKONIUM(IV) TERT-BUTOXIDE
Zirconium tert-butanolate
Tetra-tert-butoxyzirconium,Tetra-tert-butyl zirconate,ZTB
ZIRKON(IV)-TERT-BUTOXID
zirconium tetra(tert-butoxide)
MFCD00075085
ZIRCONIUM TETRA-T-BUTOXIDE
ZIRCONIUM T-BUTOXIDE
zirconium tetrabutoxide
ZIRCONIUM(IV)T-BUTOXIDE
zirconium tert-butoxide
Tetra-tert-butoxyzirconium
Zr(tert-butoxide)4
Zirconium(4+) tetrakis(2-methylpropan-2-olate)
TETRA-TERT-BUTYL ZIRCONATE
2-Propanol, 2-methyl-, zirconium(4+) salt (4:1)
密度 0.985 g/mL at 25 °C(lit.)
沸点 81 °C3 mm Hg(lit.)
熔点 3°C
分子式 C16H36O4Zr
分子量 383.679
闪点 185 °F
精确质量 382.166077
PSA 36.92000
LogP 5.06320
外观性状 无色或黄色冒烟的透明液体
折射率 n20/D 1.424(lit.)
储存条件

储存的地方必须远离氧化剂,将容器密封,储存密封的储藏器内,并放在阴凉,干爽的地方

稳定性

避免与氧化物接触,危险分解产品为一氧化碳和二氧化碳

分子结构

1. 密度(g/mL ,25℃):0.985

2. 折射率(nD20):1.424

3. 闪点(°F):185

4. 储存(ºC):2-8

5. 沸点(ºC,3mmHg):81

更多

1. 性状:气味类似酒精的黄色液体

2. 密度(g/mL,20 ºC):0.96

3. 相对蒸汽密度(g/mL,空气=1):未确定

4. 熔点(ºC):未确定

5. 沸点(ºC,常压):未确定

6. 沸点(ºC,3mm Hg ):81

7. 折射率:1.424

8. 闪点(ºC):185

9. 比旋光度(º):未确定

10. 自燃点或引燃温度(ºC):未确定

11. 蒸气压(kPa,25ºC):未确定

12. 饱和蒸气压(kPa,20ºC): 6.65hPa

13. 燃烧热(KJ/mol):未确定

14. 临界温度(ºC):未确定

15. 临界压力(KPa):未确定

16. 油水(辛醇/水)分配系数的对数值:未确定

17. 爆炸上限(%,V/V):未确定

18. 爆炸下限(%,V/V):未确定

19. 溶解性:未确定


Section 1: Product Identification
Chemical Name:Zirconium (IV) t-butoxide, 99%
CAS Registry Number:2081-12-1
Formula:Zr(OC4H9)4
EINECS Number:
Chemical Family:metal alkoxide
Synonym:zirconium t-butylate; t-butanol, zirconium salt.

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound2081-12-1100%5mg/m3 (as Zr)5mg/m3 (as Zr)

Section 3: Hazards Identification
Emergency Overview:Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed.
Primary Routes of Exposure:Inhalation, ingestion, contact with skin and eyes.
Eye Contact:Causes slight to mild irritation of the eyes
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to skin, eyes and respiratory tract.
Ingestion:Ingestion may cause gastrointestinal distress, nausea, vomiting and headache.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
No data is available for this product. In animal studies, t-butanol in high doses has acted as a reproductive
Chronic Health Affects:
effector.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical
Skin Exposure:
assistance if irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion:Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious).

SECTION 5: Fire Fighting Measures
Flash Point:185 °F
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide, dry powder or foam
If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes and zirconia dust.
Decomposion Products:
Unusual Fire or Explosion Hazards: Combustible. No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Avoid contact with water. Small spills may be adsorbed into diatomaceous earth, sand, or other suitable
Spill and Leak Procedures:
adsorbent, and swept up.

SECTION 7: Handling and Storage
Store in a tightly sealed container in a dry place. If container is left open, product may adsorb moisture from
Handling and Storage:
the atmosphere and release t-butanol vapor.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Material may form a vapor upon exposure to air. if possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a vapor upon exposure to air. if possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:slightly yellow liq.
Molecular Weight:383.68
Melting Point:no data
Boiling Point:90°C /5 mm
Vapor Pressure:no data
Specific Gravity:0.96
Odor:sweet odor
Solubility in Water:reacts with water

SECTION 10: Stability and Reactivity
Stability:moisture sensitive liquid, (store cold)
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:contact with moisture
Incompatibility:halogens
Decomposition Products:Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates.

SECTION 11: Toxicological Information
No information available in the RTECS files. t-butanol, hydrolysis product: skin (rbt) Draize: 500 ul/24h mild;
RTECS Data:eye (rbt) Draize 100 ul/24h: severe; oral (rat) LD50: 2743 mg/kg; inhalation (rat) LC50: >10000 ppm/4h;
Intraperitoneal (mouse) LD50: 399 mg/kg. oral (rbt) LD50: 3559 mg/kg; inhalation (rat) TCLo (reprod): 2000.
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

毒理学数据:

主要的刺激性影响:

在皮肤上面:刺激皮肤和粘膜

在眼睛上面: 刺激的影响

致敏作用:没有已知的敏化作用

生态学数据:

对水是稍微有害的,不要让未稀释或大量的产品接触地下水,水道或者污水系统,若无政府许可,勿将材料排入周围环境

符号 GHS07
GHS07
信号词 Warning
危害声明 H315-H319-H335
警示性声明 P261-P305 + P351 + P338
个人防护装备 Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
危害码 (欧洲) Xi: Irritant;
风险声明 (欧洲) R36/37/38
安全声明 (欧洲) S26-S36
危险品运输编码 1993
WGK德国 3
包装等级 III
危险类别 3
海关编码 2909199090
海关编码 2909199090
中文概述 2909199090. 其他无环醚及其卤化衍生物(包括磺化,硝化或亚硝化衍生物). 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%
申报要素 品名, 成分含量, 用途
Summary 2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%