42003-39-4

• 常用中文名：氯甲基杂氮硅三烷
• 常用英文名：chloromethylsilatrane
• CAS号：42003-39-4
• 分子式：C₇H₁₄ClNO₃Si
• 分子量：223.730
• 相关类别： 化学试剂 硅烷试剂
• 发布时间：2018-08-14 19:16:18
• 更新时间：2024-01-04 18:13:07

名称

• 中文名: 氯甲基杂氮硅三烷
• 英文名: 5-(chloromethyl)-4,6,11-trioxa-1-aza-5-silabicyclo[3.3.3]undecane
• 英文别名: EINECS 255-621-1; 1-(Chloromethyl)-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane; 1-chloromethyl-2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3]undecane; 1-(Chloromethyl)silatrane; 2,8,9-Trioxa-5-aza-1-silabicyclo(3.3.3)undecane,1-(chloromethyl); Silimin; Chloromethylsilatrane; Mival; 5-chloromethyl-silitrane; (TB-5-23)-(2,2',2''-azanetriyl-tris-ethanolato(3-)-N,O,O',O'')-chloromethyl-silicon; 2,8,9-Trioxa-5-aza-1-silabicyclo[3.3.3]undecane, 1-(chloromethyl)-

物化性质

• 密度: 1.2±0.1 g/cm3
• 沸点: 263.1±40.0 °C at 760 mmHg
• 熔点: 221ºC
• 分子式: C₇H₁₄ClNO₃Si
• 分子量: 223.730
• 闪点: 112.9±27.3 °C
• 精确质量: 223.043152
• PSA: 30.93000
• LogP: 0.23
• 蒸汽压: 0.0±0.5 mmHg at 25°C
• 折射率: 1.502

毒性和生态

CHEMICAL IDENTIFICATION RTECS NUMBER : YJ9030500 CHEMICAL NAME : 2,8,9-Trioxa-5-aza-1-silabicyclo(3.3.3)undecane, 1-(chloromethyl) CAS REGISTRY NUMBER : 42003-39-4 LAST UPDATED : 199701 DATA ITEMS CITED : 2 MOLECULAR FORMULA : C7-H14-Cl-N-O3-Si MOLECULAR WEIGHT : 223.76 WISWESSER LINE NOTATION : T88 A B C AO DN GO-SI-OTJ H1G HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 3 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GWXXBX German Offenlegungsschrift Patent Document. (U.S. Patent and Trademark Office, Foreign Patents, Washington, DC 20231) Volume(issue)/page/year: #2530255

安全

• 海关编码: 2934999090

合成路线

5926-26-1 64-17-5 ~% 42003-39-4

文献：Voronkov; Mikhail Grigorievich; Dyakov; Valery Mikhailovich Patent: US4048206 A1, 1977 ;

15267-95-5 135718-12-6 ~82% 42003-39-4

文献：D'yakov, V. M.; Makarov, A. F. J. Gen. Chem. USSR (Engl. Transl.), 1992 , vol. 62, # 2.2 p. 359 - 363,291 - 294

15267-95-5 144967-53-3 ~80% 42003-39-4

文献：D'yakov, V. M.; Makarov, A. F. J. Gen. Chem. USSR (Engl. Transl.), 1992 , vol. 62, # 2.2 p. 359 - 363,291 - 294

15267-95-5 118162-82-6 ~80% 42003-39-4

文献：D'yakov, V. M.; Makarov, A. F. J. Gen. Chem. USSR (Engl. Transl.), 1992 , vol. 62, # 2.2 p. 359 - 363,291 - 294

15267-95-5 283-56-7 ~10% 42003-39-4

文献：Gevorgyan, Vladimir; Borisova, Larisa; Vyater, Armand; Ryabova, Victoria; Lukevics, Edmunds Journal of Organometallic Chemistry, 1997 , vol. 548, # 2 p. 149 - 155

102-71-6 1558-25-4 ~66% 42003-39-4

文献：Voronkov; Kuznetsova Russian Journal of General Chemistry, 2009 , vol. 79, # 5 p. 925 - 927

1558-25-4 20836-42-4 ~90% 42003-39-4 75-77-4

文献：Voronkov, M. G.; Kuznetsova, G. A.; Baryshok, V. P. J. Gen. Chem. USSR (Engl. Transl.), 1983 , vol. 53, # 7 p. 1682,1512 - 1513

102-71-6 15267-95-5 ~79% 42003-39-4

文献：Nies, J. Dirk; Bellama, Jon M.; Ben-Zvi, Nava Journal of Organometallic Chemistry, 1985 , vol. 296, p. 315 - 320

海关

海关编码	2934999090
中文概述	2934999090. 其他杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%