Russian Journal of General Chemistry

Direct synthesis of 1-organylsilatranes from organyltrichlorosilanes and tris (2-hydroxyethyl) amine

MG Voronkov, GA Kuznetsova

文献索引：Voronkov; Kuznetsova Russian Journal of General Chemistry, 2009 , vol. 79, # 5 p. 925 - 927

被引用次数: 1

摘要

Abstract A direct method of synthesis of 1-organylsilatranes by the reaction of organyltrichlorosilanes with tris (2-hydroxyethyl) amine was developed. 1-Organylsilatranes RSi (OCH 2 CH 2) 3 N with R= Me, Et, Ph, ClCH 2, ICH 2, Cl (CH 2) 3 were prepared by this method in up to 72% yield.

~51%

~66%

~50%

~39%

~32%

~55%

A novel route to pentacoordinated organylsilanes and-germane...

[Gevorgyan, Vladimir; Borisova, Larisa; Vyater, Armand; Ryabova, Victoria; Lukevics, Edmunds Journal of Organometallic Chemistry, 1997 , vol. 548, # 2 p. 149 - 155]