| 中文名 | 六氟-乙酰丙酮锆 |
|---|---|
| 英文名 | zirconium hexafluoroacetylacetonate |
| 英文别名 |
MFCD00079660
zirconium hexafluoroacetonylacetonate ZIRCONIUM(IV) HEXAFLUORO-2,4-PENTANEDIONATE ZirconiuM(IV) hexafluoroacetylacetonate,Zr(CF3COCHCOCF3)4 Zirconium(lV) hexafluoroacetylacetonate ZIRCONIUM HEXAFLUOROPENTANEDIONATE ZIRCONIUM(IV)HEXAFLUOROACETYLACETONATE Zirconiumhexafluoroacetylacetonate |
| 沸点 | 225ºC |
|---|---|
| 熔点 | 41-43ºC |
| 分子式 | C20H4F24O8Zr |
| 分子量 | 919.42700 |
| 闪点 | 225ºC |
| 精确质量 | 917.85700 |
| PSA | 105.20000 |
| LogP | 8.17960 |
| 外观性状 | Crystalline | Off-white |
| 蒸汽压 | 131mmHg at 25°C |
| 储存条件 | 常温密闭避光，通风干燥 |
| 稳定性 | 常温常压下稳定 避免的物料:氧化物。溶于苯、乙醚等有机溶剂。 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:32 4.可旋转化学键数量:0 5.互变异构体数量:5 6.拓扑分子极性表面积137 7.重原子数量:53 8.表面电荷:0 9.复杂度:1010 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:5 |
| 更多 | 1. 性状：无色晶体，具吸湿性。 2. 密度（g/mL,25/4℃）：不确定 3. 相对蒸汽密度（g/mL,空气=1）：不确定 4. 熔点（ºC）：41-43 5. 沸点（ºC,常压）：225 6. 沸点（ºC, 5.2kPa）：不确定 7. 折射率：不确定 8. 闪点（ºC）：225 9. 比旋光度（º）：不确定 10. 自燃点或引燃温度（ºC）：不确定 11. 蒸气压（kPa,25ºC）：不确定 12. 饱和蒸气压（kPa,60ºC）：不确定 13. 燃烧热（KJ/mol）：不确定 14. 临界温度（ºC）：不确定 15. 临界压力（KPa）：不确定 16. 油水（辛醇/水）分配系数的对数值：不确定 17. 爆炸上限（%,V/V）：不确定 18. 爆炸下限（%,V/V）：不确定 19. 溶解性：不确定 |
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Section 1: Product Identification Chemical Name:Zirconium (IV) hexafluoroacetylacetonate CAS Registry Number:19530-02-0 Formula:Zr(CF3COCHCOCF3)4 EINECS Number:none Chemical Family:metal fluorobeta-diketonate complexes Synonym:Zirconium hexafluoro 2,4-pentanedionate
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title compound19530-02-0100%5mg/m3 (as Zr)5mg/m3 (as Zr) Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes, and respiratory tract. Primary Routes of Exposure:Contact with skin and eyes. Inhalation of dust. Eye Contact:Causes mild to moderate irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Dust is irritating to the nose, mucous membranes and respiratory tract. Ingestion:No information is available on the physiological effects of ingestion. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Product contains fluorine which under certain conditions of use, decomposition, or metabolism, may generate Chronic Health Affects:fluoride ion, causing nausea, vomiting, labored breathing, hypocalcaemia, deterioration of bone and tooth structure, kidney and liver damage. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in Inhalation: breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus. Hazardous Combustion andIf involved in a fire this material may release toxic and corrosive fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Sweep up the solids and dispose of properly. SECTION 7: Handling and Storage Handling and Storage:Store the material in a sealed container. Keep away from heat and moisture. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:white to off-white xtl. Molecular Weight:919.47 Melting Point:41-43° Boiling Point:225°C Vapor Pressure:no data Specific Gravity:no data Odor:not determined Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:hygroscopic Hazardous Polymerization:No hazardous polymerization. Conditions to Avoid:none Incompatibility:strong oxidizing agents Decomposition Products:hydrogen fluoride, organic fumes, carbon monoxide, carbon dioxide and zirconium oxide. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 通常对水体是稍微有害的，不要将未稀释或大量产品接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境。
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