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| 中文名 | 氘代3-氨基-5-吗啉-4-甲基-恶唑-2-啉酮 |
|---|---|
| 英文名 | Tris(Trimethylsilyl)Phosphine |
| 中文别名 | 三(三甲硅烷基)膦 |
| 英文别名 |
Tris(trimethylsilyl)phosphane
Phosphine, tris(trimethylsilyl)- [Tris(trimethylsilyl)]phosphine Tris(trimethylsilyl)phosphine MFCD00015487 1,1,1,3,3,3-Hexamethyl-2-(trimethylsilyl)disilaphosphane |
| 密度 | 0.863 g/mL at 25 °C(lit.) |
|---|---|
| 沸点 | 243.5±0.0 °C at 760 mmHg |
| 熔点 | 24 °C |
| 分子式 | C9H27PSi3 |
| 分子量 | 250.541 |
| 闪点 | 87.1±22.6 °C |
| 精确质量 | 250.115814 |
| PSA | 13.59000 |
| LogP | 4.82 |
| 外观性状 | 无色至淡黄色液体 |
| 蒸汽压 | 0.1±0.4 mmHg at 25°C |
| 折射率 | n20/D 1.502(lit.) |
| 储存条件 | 常温密闭避光，通风干燥惰性气体下 |
| 稳定性 | 常温常压下稳定 避免的物料： 氧化物 空气 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:0 4.可旋转化学键数量:3 5.互变异构体数量:无 6.拓扑分子极性表面积0 7.重原子数量:13 8.表面电荷:0 9.复杂度:138 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1.性状：未确定 2.密度（g/mL,25/4℃）：0.863 3.相对蒸汽密度（g/mL,空气=1）：未确定 4.熔点（ºC）：24 5.沸点（ºC,常压）：243-244 6.沸点（ºC,5.2kPa）：未确定 7.折射率：1.502 8.闪点（ºC）：-18 9.比旋光度（º）：未确定 10.自燃点或引燃温度（ºC）：未确定 11.蒸气压（kPa,25ºC）：未确定 12.饱和蒸气压（kPa,60ºC）：未确定 13.燃烧热（KJ/mol）：未确定 14.临界温度（ºC）：未确定 15.临界压力（KPa）：未确定 16.油水（辛醇/水）分配系数的对数值：未确定 17.爆炸上限（%,V/V）：未确定 18.爆炸下限（%,V/V）：未确定 19.溶解性：未确定 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 17 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Spontaneously flammable in air.Highly flammable. Potential Health Effects Eye: May cause chemical conjunctivitis and corneal damage. Skin: May cause irritation and dermatitis. May cause cyanosis of the extremities. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Ingestion of large amounts may cause CNS depression. Inhalation: Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. May cause burning sensation in the chest. Chronic: Effects may be delayed. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: Evacuate area and fight fire from a safe distance. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air. Vapors can travel to a source of ignition and flash back. May burn with invisible flame. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. Spontaneously ignitable in air. Will be easily ignited by heat, sparks or flame. Containers may explode if exposed to fire. Extinguishing Media: Use dry sand or earth to smother fire. For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Water may be ineffective. Water may spread fire. If water is the only media available, use in flooding amounts. For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water. Contact professional fire-fighters immediately. Cool containers with flooding quantities of water until well after fire is out. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Remove all sources of ignition. Use a spark-proof tool. Isolate area and deny entry. Place under an inert atmosphere. Do not use combustible materials such as paper towels to clean up spill. A vapor suppressing foam may be used to reduce vapors. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Minimize dust generation and accumulation. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Avoid contact with skin and eyes. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Handle under an inert atmosphere. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Storage: Keep away from heat, sparks, and flame. Keep away from heat and flame. Keep away from sources of ignition. Store in a cool, dry place. Keep container closed when not in use. Flammables-area. Keep refrigerated. (Store below 4C/39F.) Keep containers tightly closed. Do not expose to air. Store under an inert atmosphere. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use explosion-proof ventilation equipment. Use adequate ventilation to keep airborne concentrations low. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels. Exposure Limits CAS# 15573-38-3: United Kingdom, WEL - TWA: (listed as silica, amorphous): 6 mg/m3 (inhalable dust); 2.4 mg/m3 TWA (respirable dust) United Kingdom, WEL - STEL: (listed as silica, amorphous): 18 mg/ STEL (inhalable dust); 7.2 mg/m3 STEL (respirable dust) Russia: (listed as silica, amorphous): 1 mg/m3 TWA Personal Protective Equipment Eyes: Wear safety glasses and chemical goggles if splashing is possible. Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Respirators: Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Clear liquid Color: clear, colorless Odor: None reported. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 243.0 - 244.0 deg C Freezing/Melting Point: 24 deg C Autoignition Temperature: 20 deg C ( 68.00 deg F) Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: .8630g/cm3 Molecular Formula: C9H27PSi3 Molecular Weight: 250.54 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Powder or liquid is pyrophoric. Conditions to Avoid: Incompatible materials, ignition sources, dust generation, exposure to air, excess heat, strong oxidants. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 15573-38-3 unlisted. LD50/LC50: Not available. Carcinogenicity: [Tris(trimethylsilyl)]phosphine, 98% - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: FLAMMABLE LIQUID, N.O.S.* Hazard Class: 3 UN Number: 1993 Packing Group: II IMO Shipping Name: FLAMMABLE LIQUID, N.O.S. Hazard Class: 3.2 UN Number: 1993 Packing Group: II RID/ADR Shipping Name: FLAMMABLE LIQUID, N.O.S. Hazard Class: 3 UN Number: 1993 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: F Risk Phrases: R 17 Spontaneously flammable in air. Safety Phrases: S 9 Keep container in a well-ventilated place. S 16 Keep away from sources of ignition - No smoking. S 33 Take precautionary measures against static discharges. WGK (Water Danger/Protection) CAS# 15573-38-3: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 15573-38-3 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 15573-38-3 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 通常对水是不危害的，若无政府许可，勿将材料排入周围环境。
|
| 符号 |
GHS02, GHS07 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H250-H315-H319-H335 |
| 警示性声明 | P210-P280-P302 + P334-P305 + P351 + P338-P370 + P378-P422 |
| 个人防护装备 | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| 危害码 (欧洲) | F,Xi |
| 风险声明 (欧洲) | R17 |
| 安全声明 (欧洲) | S16-S26-S27-S28-S36/37/39-S39-S37-S36 |
| 危险品运输编码 | UN 2845 4.2/PG 1 |
| WGK德国 | 3 |
| 包装等级 | I |
| 危险类别 | 4.2 |
|
~75%
15573-38-3 |
| 文献：Askham, Fredric R.; Stanley, George G.; Marques, Edward C. Journal of the American Chemical Society, 1985 , vol. 107, # 25 p. 7423 - 7431 |
|
~86%
15573-38-3 |
| 文献：Cossairt, Brandi M.; Cummins, Christopher C. New Journal of Chemistry, 2010 , vol. 34, # 8 p. 1533 - 1536 |
|
~0%
15573-38-3
详细
|
| 文献：Hassler, K.; Katzenbeisser, U. Journal of Organometallic Chemistry, 1990 , vol. 399, # 3 p. C18 - C20 |
|
~%
15573-38-3 |
| 文献：Journal of the American Chemical Society, , vol. 81, p. 6273 |
|
~0%
15573-38-3 |
| 文献：Koelle, Peter; Linti, Gerald; Noeth, Heinrich; Wood, Gary L.; Narula, Chaitanya K.; Paine, Robert T. Chemische Berichte, 1988 , vol. 121, p. 871 - 880 |
|
~0%
15573-38-3 |
| 文献：Koelle, Peter; Linti, Gerald; Noeth, Heinrich; Wood, Gary L.; Narula, Chaitanya K.; Paine, Robert T. Chemische Berichte, 1988 , vol. 121, p. 871 - 880 |
|
~0%
15573-38-3 |
| 文献：Koelle, Peter; Linti, Gerald; Noeth, Heinrich; Wood, Gary L.; Narula, Chaitanya K.; Paine, Robert T. Chemische Berichte, 1988 , vol. 121, p. 871 - 880 |
|
~0%
15573-38-3 |
| 文献：Weber, Lothar; Meine, Georg; Boese, Roland; Blaeser, Dieter Chemische Berichte, 1988 , vol. 121, p. 853 - 858 |
|
~%
15573-38-3 |
| 文献：Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, , vol. 35, # 5 p. 594 - 598 |
