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| 中文名 | 三甲基硼-d9 |
|---|---|
| 英文名 | tris(trideuteriomethyl)borane |
| 英文别名 |
MFCD00145460
Trimethylboron-d9 Tris-<trideuterio-methyl>-boran trimethylborane-d9 tris-trideuteriomethyl-borane Tris-trideuteromethyl-bor d9-Trimethylboran |
| 沸点 | -20,2ºC |
|---|---|
| 熔点 | -161.5ºC |
| 分子式 | C3BD9 |
| 分子量 | 64.97000 |
| 精确质量 | 65.13620 |
| LogP | 1.37060 |
| 储存条件 | 密封于避光处保存，温度不宜超过52°C |
| 稳定性 | 常温常压下稳定，避免强氧化剂,卤素 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:0 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积0 7.重原子数量:4 8.表面电荷:0 9.复杂度:8 10.同位素原子数量:9 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：未确定 2. 密度（g/mLat 25°C）：未确定 3. 相对蒸汽密度（g/mL,空气=1）：2.3 4. 熔点（ºC）：-161.5 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC,760mmHg）：-20.2 7. 折射率（n20/D）：未确定 8. 闪点（ºC）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（mmHg,37ºC）：未确定 12. 饱和蒸气压（kPa,114.4 ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（MPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
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Date Updated: 12/FEB/2006
Version 1.2 Regulation (EC) No 1907/2006 ________________________________________________________________________ 1 - Product and Company Information ________________________________________________________________________ Product NameTRIMETHYLBORON-D9, 99 ATOM % D,
ELECTRON IC GRADE Product Number463426 Company Century Ba-Shi Building 22A-B, 200020 Shanghai Technical Phone #86-21-61415566 Fax 86-21-61415567 E-mail Address ________________________________________________________________________ 2 - Hazards Identification ________________________________________________________________________ SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT Spontaneously flammable in air. Causes burns. ________________________________________________________________________ 3 - Composition/Information on Ingredients ________________________________________________________________________ Product NameCAS #EC noAnnex I Index Number TRIMETHYLBORON-D9, 99 ATOM % D, 6063-55-4 None005-004-00-6 ELECTRONICGRADE FormulaC3 BD9 Molecular Weight 64,9900 AMU ________________________________________________________________________ 4 - First Aid Measures ________________________________________________________________________ AFTER INHALATION If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. AFTER SKIN CONTACT In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing and shoes. Call a physician. AFTER EYE CONTACT Contamination of the eyes should be treated by immediate and prolonged irrigation with copious amounts of water. AFTER INGESTION If swallowed, wash out mouth with water provided person is conscious. Call a physician immediately. GENERAL INFORMATION Contamination of the eyes should be treated by immediate and prolonged irrigation with copious amounts of water. ________________________________________________________________________ 5 - Fire Fighting Measures ________________________________________________________________________ SPECIAL RISKS Specific Hazard(s): Vapor may travel considerable distance to source of ignition and flash back. Pyrophoric material. Emits toxic fumes under fire conditions. Explosion Hazards: Vapor may travel considerable distance to source of ignition and flash back. Container explosion may occur under fire conditions. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. ________________________________________________________________________ 6 - Accidental Release Measures ________________________________________________________________________ PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL Evacuate area and keep personnel upwind. Shut off all sources of ignition. Shut off leak if there is no risk. PROCEDURE(S) OF PERSONAL PRECAUTION(S) Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves. METHODS FOR CLEANING UP Ventilate area and wash spill site after material pickup is complete. ________________________________________________________________________ 7 - Handling and Storage ________________________________________________________________________ HANDLING Directions for Safe Handling: Do not breathe gas. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE Conditions of Storage: Keep tightly closed. Keep away from heat, sparks, and open flame. Cylinder temperature should not exceed 125°F (52°C). SPECIAL REQUIREMENTS: Contents under pressure. ________________________________________________________________________ 8 - Exposure Controls / Personal Protection ________________________________________________________________________ ENGINEERING CONTROLS Use only in a chemical fume hood. Safety shower and eye bath. Use nonsparking tools. GENERAL HYGIENE MEASURES Wash thoroughly after handling. PERSONAL PROTECTIVE EQUIPMENT Special Protective Measures: Wear appropriate government approved respirator, chemical-resistant gloves, safety goggles, other protective clothing. ________________________________________________________________________ 9 - Physical and Chemical Properties ________________________________________________________________________ pH N/A BP/BP Range- 20,200 °C.760,000 mmHg MP/MP Range- 161,500 °C. Flash PointN/A FlammabilityN/A Autoignition TempN/A Oxidizing Properties N/A Explosive Properties N/A Explosion LimitsN/A Vapor PressureN/A Partition Coefficient N/A ViscosityN/A Vapor Density2,300 g/l Saturated Vapor Conc. N/A Evaporation RateN/A Bulk DensityN/A Decomposition Temp.N/A Solvent ContentN/A Water ContentN/A Surface TensionN/A ConductivityN/A Miscellaneous DataN/A SolubilityN/A ________________________________________________________________________ 10 - Stability and Reactivity ________________________________________________________________________ STABILITY Stable: Stable. Reactions to Avoid: Reacts violently with: Materials to Avoid: Water, Strong oxidizing agents, Halogens. HAZARDOUS DECOMPOSITION PRODUCTS Hazardous Decomposition Products: Borane/boron oxides, Methane gas. HAZARDOUS POLYMERIZATION Hazardous Polymerization: Will not occur ________________________________________________________________________ 11 - Toxicological Information ________________________________________________________________________ SIGNS AND SYMPTOMS OF EXPOSURE Coughing, chest pains, difficulty in breathing. Nausea, headache, and vomiting. Exposure can cause: ROUTE OF EXPOSURE Skin Contact: Thermal burns. Multiple Routes: Harmful if inhaled or absorbed through skin. ________________________________________________________________________ 12 - Ecological Information ________________________________________________________________________ No data available. ________________________________________________________________________ 13 - Disposal Considerations ________________________________________________________________________ SUBSTANCE DISPOSAL Observe all federal, state, and local environmental regulations. CONTAMINATED CONTAINER DISPOSAL Caution: no-return cylinder. Do not reuse. Empty cylinder will contain hazardous residue. Follow proper disposal techniques. ________________________________________________________________________ 14 - Transport Information ________________________________________________________________________ RID/ADR UN#: 3160 Class: 2.3 Subrisk: 2.1 Proper Shipping Name: Liquefied gas, toxic, flammable, n.o.s. IMDG UN#: 3160 Class: 2.3 Subrisk: 2.1 Proper Shipping Name: Liquefied gas, toxic, flammable, n.o.s. Marine Pollutant: No Severe Marine Pollutant: No Technical Name: Required IATA UN#: 3160 Class: 2.3 Subrisk: 2.1 Proper Shipping Name: Liquefied gas, toxic, flammable, n.o.s. Inhalation Packing Group I: No Technical Name: Required ________________________________________________________________________ 15 - Regulatory Information ________________________________________________________________________ CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES ANNEX I INDEX NUMBER: 005-004-00-6 NOTA: A INDICATION OF DANGER: F-C Highly Flammable. Corrosive. R-PHRASES: 17-34 Spontaneously flammable in air. Causes burns. S-PHRASES: 7-23-26-36/37/39-43-45 Keep container tightly closed. Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of fire, use dry powder. Never use water. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Caution: Substance not yet fully tested (EU). COUNTRY SPECIFIC INFORMATION Germany WGK: 1 Self-Classification ________________________________________________________________________ 16 - Other Information ________________________________________________________________________ WARRANTY The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. unlimitedpaper copies for internal use only. DISCLAIMER For R&D use only. Not for drug, household or other uses. 模块 15 - 法规信息 N/A 模块16 - 其他信息 N/A |
| 危害码 (欧洲) | F,C |
|---|---|
| 风险声明 (欧洲) | 17-34 |
| 安全声明 (欧洲) | S7-S23-S26-S43-S45-S36-S37-S39 |
| 危险品运输编码 | UN 3160 2.3 |