中文名 | 苯磺酸锌 |
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英文名 | zinc phenolsulfonate |
中文别名 |
苯酚磺酸锌
苯酚磺酸锌 |
英文别名 |
Zinc bis(4-hydroxybenzenesulfonate)
4-Hydroxybenzenesulfonic acid phenozin zincsulfophenate ZINC SULFOCARBOLATE Zinephenolsulphonate universalzps wellno921a ZINC P-PHENOL SULFONATE Benzenesulfonic acid, 4-hydroxy-, zinc salt (2:1) zinc-1,4-phenolsulfonate ZINCSULPHOCARBOLATE |
分子式 | C12H10O8S2Zn |
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分子量 | 411.742 |
精确质量 | 409.910858 |
PSA | 171.62000 |
LogP | 2.75170 |
外观性状 | 无色至白色结晶固体 |
储存条件 | 储存于阴凉干燥处。 |
稳定性 | 1.在干燥空气中风化,约于120℃失去全部结晶水. 2.水溶液对石蕊试纸呈酸性,ph值约为4. |
计算化学 | 1.疏水参数计算参考值(XlogP):无 2.氢键供体数量:2 3.氢键受体数量:8 4.可旋转化学键数量:0 5.互变异构体数量:3 6.拓扑分子极性表面积172 7.重原子数量:23 8.表面电荷:0 9.复杂度:194 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:3 |
更多 | 1.性状:无色或白色结晶或结晶性粉末。易变成粉红色。 2.溶解性:易溶于水合醇。 |
Section 1. Chemical Product and Company Identification Zinc phenolsulfonateCatalog Z1087, Z1089 Common Name/ Number(s). Trade Name CAS#127-82-2 [anhydrous CAS
no.] Manufacturer Commercial Name(s) Zinc phenolsulfonate Section 3. Hazards Identification Potential Acute Health Effects Hazardous in case of eye contact (irritant). Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation. Potential Chronic HealthCARCINOGENIC EFFECTS: Not available. EffectsMUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition. Section 4. First Aid Measures Eye ContactCheck for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention. Skin ContactWash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water may be used. Serious Skin ContactNot available. InhalationIf inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Serious InhalationNot available. IngestionDo NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. Serious IngestionNot available. Section 5. Fire and Explosion Data Flammability of the Product May be combustible at high temperature. Auto-Ignition Temperature Not available. Flash PointsNot available. Flammable LimitsNot available. These products are carbon oxides (CO, CO2), sulfur oxides (SO2, SO3...). Some metallic oxides. Products of Combustion Fire Hazards in Presence of Slightly flammable to flammable in presence of heat. Various Substances Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available. of Various SubstancesRisks of explosion of the product in presence of static discharge: Not available. Fire Fighting MediaSMALL FIRE: Use DRY chemical powder. and InstructionsLARGE FIRE: Use water spray, fog or foam. Do not use water jet. Special Remarks onWhen heated to decomposition it emits irritating and toxic fumes of sulfur oxides and zinc. Fire Hazards Special Remarks on Explosion Not available. Hazards Zinc phenolsulfonate Section 6. Accidental Release Measures Small SpillUse appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Large SpillUse a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Section 7. Handling and Storage PrecautionsKeep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe dust. Avoid contact with eyes. Wear suitable protective clothing. If ingested, seek medical advice immediately and show the container or the label. StorageKeep container tightly closed. Keep container in a cool, well-ventilated area. Air Sensitive Sensitive to light. Store in light-resistant containers. Section 8. Exposure Controls/Personal Protection Engineering ControlsUse process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Personal ProtectionSplash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used a Large Spillto avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure LimitsNot available. Section 9. Physical and Chemical Properties Physical state and appearance Solid. (Crystalline solid.)OdorOdorless. Astringent Metallic Taste Molecular Weight555.86 g/mole White. Color pH (1% soln/water)Not available. Boiling PointDecomposes. Melting PointNot available. Critical TemperatureNot available. Specific Gravity>1 (Water = 1) Not applicable. Vapor Pressure Vapor DensityNot available. Not available. Volatility Odor ThresholdNot available. Water/Oil Dist. Coeff.Not available. Ionicity (in Water)Not available. Dispersion PropertiesSee solubility in water. SolubilityEasily soluble in cold water, hot water. Zinc phenolsulfonate Section 10. Stability and Reactivity Data The product is stable. Stability Instability TemperatureNot available. Excess heat, incompatible materials, dust generation Conditions of Instability Not available. Incompatibility with various substances CorrosivityNon-corrosive in presence of glass. Special Remarks onEffloresces in dry air. ReactivityLoses all water at about 120 deg. C. Air and light sensitive. Turns pink on extended exposure to light and air. Incompatible with alkali soaps and ferric salts. Ferric salts turn material red or violet. Not available. Special Remarks on Corrosivity PolymerizationWill not occur. Section 11. Toxicological Information Routes of EntryInhalation. Ingestion. Toxicity to AnimalsAcute oral toxicity (LD50): 1800 mg/kg [Rat]. Chronic Effects on Humans Not available. Other Toxic Effects onSlightly hazardous in case of skin contact (irritant), of ingestion, of inhalation. Humans Special Remarks onLethal Dose/Conc: Toxicity to AnimalsLC [Rat] - Route: Inhalation; Dose: >208 gm/m3/1H LD[Guinea Pig] - Route: Skin; Dose: >3000 mg/kg Special Remarks onNot available. Chronic Effects on Humans Special Remarks on otherAcute Potentia Health Effects: Toxic Effects on HumansSkin: May cause skin irritation. Eyes: Can cause moderate eye irritation with possible pain. May cause corneal damage Inhalation: Inhalation of dust may cause nose, throat, respiratory tract irritation. Symptoms may include coughing, sneezing, wheezing. Ingestion: May be harmful if swallowed. Ingestion of large amounts may cause nausea, vomiting, diarrhea, and astringent actions (contacting blood vessels or shrinking mucous membranes. Section 12. Ecological Information EcotoxicityNot available. Not available. BOD5 and COD Products of BiodegradationPossibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the ProductsThe products of degradation are less toxic than the product itself. of Biodegradation Special Remarks on theNot available. Products of Biodegradation Zinc phenolsulfonate Section 13. Disposal Considerations Waste DisposalWaste must be disposed of in accordance with federal, state and local environmental control regulations. Section 14. Transport Information DOT ClassificationNot a DOT controlled material (United States). Not applicable. Identification Not applicable. Special Provisions for Transport DOT (Pictograms) Section 15. Other Regulatory Information and Pictograms For Zinc Phenolsulfonate (anhydrous CAS no. 127-82-2): Federal and State Connecticut hazardous material survey.: Zinc phenolsulfonate Regulations Illinois chemical safety act: Zinc phenolsulfonate New York release reporting list: Zinc phenolsulfonate Pennsylvania RTK: Zinc phenolsulfonate Massachusetts RTK: Zinc phenolsulfonate Massachusetts spill list: Zinc phenolsulfonate New Jersey: Zinc phenolsulfonate New Jersey spill list: Zinc phenolsulfonate Louisiana RTK reporting list: Zinc phenolsulfonate California Director's List of Hazardous Substances: Zinc phenolsulfonate SARA 313 toxic chemical notification and release reporting: Zinc phenolsulfonate (listed as Zinc compounds) CERCLA: Hazardous substances.: Zinc phenolsulfonate: 5000 lbs. (2268 kg) Zinc Phenolsulfonate, octahydrate is exempt from TSCA Inventory 8(b) listing. However, the anhydrous form (CAS no. 127-82-2) is on the TSCA 8(b) inventory. CaliforniaCalifornia prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: No products were found. Proposition 65 Warnings California prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: No products were found. Other RegulationsFor Zinc Phenolsulfonate (anhydrous CAS no. 127-82-2): EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No. 204-867-8). Canada: Listed on Canadian Domestic Substance List (DSL). China: Listed on National Inventory. Japan: Listed on National Inventory (ENCS). Korea: Not listed on National Inventory (KECI). Philippines: Not listed on National Inventory (PICCS). Australia: Listed on AICS. WHMIS (Canada) Not controlled under WHMIS (Canada). Other Classifications DSCL (EEC)R22- Harmful if swallowed.S26- In case of contact with eyes, rinse R36- Irritating to eyes.immediately with plenty of water and seek medical advice. S46- If swallowed, seek medical advice immediately and show this container or label. Zinc phenolsulfonate Health Hazard HMIS (U.S.A.)2 National Fire Protection 1 Flammability 1 Association (U.S.A.) Fire Hazard 2 0 Reactivity Health Reactivity 0 Specific hazard Personal Protection E WHMIS (Canada) (Pictograms) DSCL (Europe) (Pictograms) TDG (Canada) (Pictograms) ADR (Europe) (Pictograms) Protective Equipment Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles. SECTION 16 - ADDITIONAL INFORMATION N/A |
毒理学数据: 1、皮肤/眼睛刺激:兔子眼睛标准德雷兹染眼实验:3mg 对眼睛有中等强度的刺激作用。 2、急性毒性:大鼠经口LD5O:1800mg/kg 大鼠吸入LD50:>208gm/m3/1H 大鼠经腹膜LD5O:225mg/kg 小鼠经口LC5O:3gm/kg 小鼠经腹膜LC5O:172mg/kg 豚鼠皮肤LD:>3gm/kg 3、其他多剂量毒性:大鼠吸入TDLO:20mg/m 3/4H/13W-I 豚鼠吸入TCLO:45mg/m 3/3H/13W-I
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATA
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