| 中文名 | 水合三氯化铊(III) |
|---|---|
| 英文名 | thallium(3+),trichloride,hydrate |
| 中文别名 | 三氯化铊 |
| 英文别名 |
MFCD00049600
EINECS 236-625-2 thallium,ion hydrate trichloride |
| 沸点 | 100ºC at 760 mmHg |
|---|---|
| 熔点 | 37ºC |
| 分子式 | Cl3Tl |
| 分子量 | 310.74200 |
| 精确质量 | 309.88100 |
| LogP | 2.06850 |
| 外观性状 | 白色粉末 |
| 蒸汽压 | 24.5mmHg at 25°C |
| 储存条件 | 常温密闭，阴凉通风干燥 |
| 稳定性 | 常温常压下稳定 避免的物料 氧化物。 它在干燥空气中是稳定的且易溶于水(86.2g/100g水，17℃)。 |
| 水溶解性 | It is soluble in water 862g/L |
| 分子结构 | 1、摩尔折射率：无可用的 2、摩尔体积（cm3/mol）：无可用的 3、等张比容（90.2K）：无可用的 4、表面张力（dyne/cm）：无可用的 5、介电常数：无可用的 6、极化率（10-24cm3）：无可用的 7、单一同位素质量：309.880958 Da 8、标称质量：310 Da 9、平均质量：310.7423 Da |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:1 3.氢键受体数量:4 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积1 7.重原子数量:5 8.表面电荷:0 9.复杂度:0 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:5 |
| 更多 | 1. 性状：白色粉末，单斜晶体 2. 密度（g/mL,25/4℃）：未确定 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：37 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC,5.2kPa）：未确定 7. 折射率：未确定 8. 闪点（ºC）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：不适用的 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：易溶于水 |
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Section 1: Product Identification Chemical Name:Thallium (III) chloride hydrate (8% H2O) CAS Registry Number:13453-33-3 Formula:TlCl3.XH2O EINECS Number: Chemical Family:metal halide Synonym:Thallic chloride, hexahydrate
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound13453-33-3100%0.1mg/m30.1mg/m3 Section 3: Hazards Identification Toxic by inhalation and if swallowed. Irritating to skin, eyes and respiratory tract. Danger of cumulative effects. Emergency Overview: Primary Routes of Exposure:Ingestion Eye Contact:Contact with eyes causes irritation, redness, and pain. Skin Contact:Causes irritation to skin. Symptoms include redness, itching, and pain, pimples, boils, hives and blisters. Inhalation:Toxic by inhalation. Irritating to the nose, mucous membranes and respiratory tract. Toxic if swallowed. Ingestion of small amounts results in swelling of the feet and legs, mental confusion, pain, Ingestion: paralysis, and death. Toxic by inhalation and if swallowed. Acute poisoning results in swelling of the feet and legs, mental confusion, Acute Health Affects: angina-like pains, paralysis, weakness, and death. Danger of cumulative effects. Prolonged exposure to thallium compounds causes discoloration of the hair, Chronic Health Affects: which later falls out, joint pain, loss of appetite, fatigue, severe pain in the legs, albuminuria, and optic neuritis. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:None. Material is non-flammable. If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andnone Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite or other suitable Spill and Leak Procedures: inert material and swept up. SECTION 7: Handling and Storage Handling and Storage:Store solid in a tightly sealed container. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. Ventilation:solid may form a toxic fine dust. If possible, handle the solid in an efficient fume hood. If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators Respirator: requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:solid may form a toxic fine dust. If possible, handle the solid in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:white xtl. Molecular Weight:310.73 Melting Point:37° Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water: SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:active metals Decomposition Products:water, metal chloride SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Avoid release to groundwater or waterways. Toxic to aquatic organisms. May cause long-term adverse effects. Ecological Information: SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Thallium compounds, N.O.S. Hazard Class (CFR):6.1 Additional Hazard Class (CFR):NA Packaging Group (CFR):II UN ID Number (CFR):UN# 1707 Shipping Name (IATA):Thallium compound, N.O.S. Hazard Class (IATA):6.1 Additional Hazard Class (IATA):NA Packaging Group (IATA):II UN ID Number (IATA):UN# 1707 SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory SARA (Title 313):Title compound: See Category Code N760 for reporting. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
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毒理学数据: 1、急性毒性：主要的刺激性影响： 在皮肤上面：刺激皮肤和粘膜； 在眼睛上面：刺激的影响；没有已知的敏化影响。生态学数据: 对水体是极其有害的，即使小量产品也不能接触地下水，水道或污水系统, 若无政府许可，勿将材料排入周围环境
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| 危害码 (欧洲) | N: Dangerous for the environment;T+: Very toxic; |
|---|---|
| 风险声明 (欧洲) | R26/28 |
| 安全声明 (欧洲) | 13-28-45-61 |
| 危险品运输编码 | UN 1707 6 |
| WGK德国 | 3 |
| 包装等级 | II |
| 危险类别 | 6.1 |