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| 中文名 | 六氟乙酰丙酮铂(II) |
|---|---|
| 英文名 | (Z)-1,1,1,5,5,5-hexafluoro-4-hydroxypent-3-en-2-one,platinum |
| 英文别名 |
platinum hexafluoropentanedionate
platinum 1,1,1,5,5,5-hexafluoro-2,4-pentanedionate |
| 沸点 | 65ºC 0,1mm |
|---|---|
| 熔点 | 143-145ºC |
| 分子式 | C10H2F12O4Pt |
| 分子量 | 609.17900 |
| 闪点 | 22.8ºC |
| 精确质量 | 608.94100 |
| PSA | 52.60000 |
| LogP | 4.08730 |
| 外观性状 | crystal | orange |
| 储存条件 | 密闭于阴凉干燥环境中 |
| 稳定性 | 遵照规定使用和储存则不会分解。在65℃升华。可溶于许多有机溶剂中。 |
| 分子结构 | 1、摩尔折射率：无可用 2、 摩尔体积（cm3/mol）：无可用 3、 等张比容（90.2K）：无可用 4、 表面张力（dyne/cm）：无可用 5、 极化率：无可用 |
| 计算化学 | 1、 疏水参数计算参考值（XlogP）：6.8 2、 氢键供体数量：1 3、 氢键受体数量：3 4、 可旋转化学键数量：8 5、 拓扑分子极性表面积（TPSA）：32.7 6、 重原子数量：29 7、 表面电荷：0 8、 复杂度：493 9、 同位素原子数量：0 10、 确定原子立构中心数量：0 11、 不确定原子立构中心数量：0 12、 确定化学键立构中心数量：1 13、 不确定化学键立构中心数量：0 14、 共价键单元数量：1 |
| 更多 | 1. 性状：橘黄色晶体。 2. 密度（g/mL,25/4℃）：无可用 3. 相对蒸汽密度（g/mL,空气=1）：无可用 4. 熔点（ºC）：143-145 5. 沸点（ºC,常压）：无可用 6. 沸点（ºC,5.2kPa）：无可用 7. 折射率：无可用 8. 闪点（ºC）：无可用 9. 比旋光度（º）：无可用 10. 自燃点或引燃温度（ºC）：无可用 11. 蒸气压（kPa,25ºC）：无可用 12. 饱和蒸气压（kPa,60ºC）：无可用 13. 燃烧热（KJ/mol）：无可用 14. 临界温度（ºC）：无可用 15. 临界压力（KPa）：无可用 16. 油水（辛醇/水）分配系数的对数值：无可用 17. 爆炸上限（%,V/V）：无可用 18. 爆炸下限（%,V/V）：无可用 19. 溶解性：无可用 |
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Section 1: Product Identification Chemical Name:Platinum (II) hexafluoroacetylacetonate, 98% (99.9%-Pt) CAS Registry Number:65353-51-7 Formula:Pt(CF3COCHCOCF3)2 EINECS Number:None Chemical Family:metal fluorobeta-diketonate complexes Synonym:Bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)platinum (II)
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound65353-51-7100%2.5mg/m3 (as F)2.5mg/m3 (as F) Section 3: Hazards Identification Irritating to skin, eyes and respiratory tract. Exposure to platinum compounds has been shown to cause Emergency Overview: wheezing, coughing, and running of the nose. Inhalation or ingestion may cause fluoride poisoning. Primary Routes of Exposure:Ingestion, inhalation, skin, inhalation of dust. Eye Contact:Causes slight to mild irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation of the dust causes irritation of the nose, mucous membranes and respiratory tract, wheezing, Inhalation: coughing, shortness of breath. Ingestion:Ingestion may lead to fluoride poisoning, dizziness, abdominal cramps, and vomiting. Acute Health Affects:Irritating to skin, eyes, mucous membranes, and respiratory tract. Product contains fluorine which under certain conditions of use, decomposition, or metabolism, may generate Chronic Health Affects:fluoride ion, causing, nausea, vomiting, labored breathing, hypocalcaemia, deterioration of bone and tooth structure, kidney and liver damage. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self- contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a cool, dry place in a tightly sealed container. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:To minimize exposure, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:To minimize exposure, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:orange xtl. Molecular Weight:609.22 Melting Point:143-145° Boiling Point:subl. 65°C /0.1mm Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:oxidizing agents, halogens, and active metals Decomposition Products:carbon monoxide, carbon dioxide, carbonyl fluoride, hydrogen fluoride, organic fumes, and platinum salts. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data Mutagenic Effects:No data Tetratogenic Effects:No data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Not regulated by Title 313. Second Ingredient:None SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。
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| 危害码 (欧洲) | Xi: Irritant; |
|---|---|
| 风险声明 (欧洲) | R36/37/38 |
| 安全声明 (欧洲) | 26-36/37/39 |