11136-36-0

11136-36-0结构式

常用中文名：双(五甲基环戊二烯基)二氯化钛
常用英文名：39570Bis(pentamethylcyclopentadienyl)titanium dichloride
CAS号：11136-36-0
分子式：C₂₀H₃₀Cl₂Ti
分子量：389.22500
相关类别：有机原料有机金属类化合物有机钛
发布时间：2018-07-18 20:29:09
更新时间：2024-01-06 18:20:18

化源商城直购

中文名	双(五甲基环戊烯)二氯化钛
英文名	bis(pentamethylcyclopentadienyl)titanium dichloride
中文别名	双(五甲基环戊二烯)二氯化钛
英文别名	1,2,3,5,5-pentamethylcyclopenta-1,3-diene,titanium(4+),dichloride MFCD00049153 Bis(pentamethylcyclopentadienyl)titanium dichloride

熔点	190 °C (dec.)(lit.)
分子式	C₂₀H₃₀Cl₂Ti
分子量	389.22500
精确质量	388.12000
LogP	7.32300
外观性状	红色或棕色晶体或针状
储存条件	密封于阴凉干燥处。
稳定性	遵照规格使用和储存则不会分解。
分子结构	1、摩尔折射率：无可用 2、摩尔体积（cm³/mol）：无可用 3、等张比容（90.2K）：无可用 4、表面张力（dyne/cm）：无可用
计算化学	1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:4 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积0 7.重原子数量:23 8.表面电荷:0 9.复杂度:484 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:5
更多	1. 性状：无可用 2. 密度（g/mL,25/4℃）：无可用 3. 相对蒸汽密度（g/mL,空气=1）：无可用 4. 熔点（ºC）：190 5. 沸点（ºC,常压）：无可用 6. 沸点（ºC,5.2kPa）：无可用 7. 折射率：无可用 8. 闪点（ºC）：无可用 9. 比旋光度（º）：无可用 10. 自燃点或引燃温度（ºC）：无可用 11. 蒸气压（kPa,25ºC）：无可用 12. 饱和蒸气压（kPa,60ºC）：无可用 13. 燃烧热（KJ/mol）：无可用 14. 临界温度（ºC）：无可用 15. 临界压力（KPa）：无可用 16. 油水（辛醇/水）分配系数的对数值：无可用 17. 爆炸上限（%,V/V）：无可用 18. 爆炸下限（%,V/V）：无可用 19. 溶解性：无可用

Section 1: Product Identification
Chemical Name:Bis(pentamethylcyclopentadienyl)titanium dichloride, 99%
CAS Registry Number:11136-36-0
Formula:[(CH3)5C5]2TiCl2
EINECS Number:none
Chemical Family:organometallic complex

Synonym:Dichlorobis(pentamethylcyclopentadienyl)titanium (IV)

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound11136-36-0100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes, and mucous membranes
Primary Routes of Exposure:Ingestion
Eye Contact:Severe irritant to the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:The material is a crystalline solid. Inhalation is an unlikely source of exposure.
Ingestion:No information is available on the physiological effects of ingestion.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:none
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam
Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
Special Fire Fighting Procedures:
and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
The material will degrade on prolonged exposure to moisture. Store under an inert atmosphere of nitrogen or
Handling and Storage:
argon. Keep bottle tightly sealed and away from heat and light.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:red-brown xtl.
Molecular Weight:389.23
Melting Point:no data
Boiling Point:decomposes
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:reacts with water

SECTION 10: Stability and Reactivity
Stability:moisture-sensitive solid
Hazardous Polymerization:none
Conditions to Avoid:exposure to moisture
Incompatibility:water, strong oxidizing agents
Decomposition Products:carbon dioxide, carbon monoxide, hydrochloric acid, organic fumes, and titanium oxide.

SECTION 11: Toxicological Information
RTECS Data:No data available in the RTECS files.
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:not listed on the TSCA inventory
SARA (Title 313):not regulated by Title 313
Second Ingredient:none

SECTION 16 - ADDITIONAL INFORMATION
N/A

生态学数据:

该物质对环境可能有危害，对水体应给予特别注意。

危害码 (欧洲)	Xn: Harmful;
风险声明 (欧洲)	R20/21/22
安全声明 (欧洲)	S26-S36
危险品运输编码	UN3261
WGK德国	3
包装等级	II
危险类别	8