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| 中文名 | 2,4-二硝基苯肼盐酸盐 |
|---|---|
| 英文名 | 2,4-dinitrophenylhydrazine hydrochloride |
| 英文别名 |
EINECS 259-888-5
2,4-Dinitrophenyl hydrazine hydrochloride (2,4-dinitrophenyl)hydrazine,hydrochloride Hydrazine, (2,4-dinitrophenyl)-, hydrochloride (1:1) (2,4-Dinitrophenyl)hydrazine hydrochloride (1:1) |
| 沸点 | 378.6ºC at 760mmHg |
|---|---|
| 分子式 | C6H7ClN4O4 |
| 分子量 | 234.597 |
| 闪点 | 182.8ºC |
| 精确质量 | 234.015579 |
| PSA | 129.69000 |
| LogP | 3.41030 |
| 外观性状 | 固体;White to Yellow to Orange powder to crystal |
| 储存条件 | 存放于惰性气体之中;避免空气,湿气 (吸湿) |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:3 3.氢键受体数量:6 4.可旋转化学键数量:1 5.互变异构体数量:无 6.拓扑分子极性表面积130 7.重原子数量:15 8.表面电荷:0 9.复杂度:235 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:2 |
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Section I.Chemical Product and Company Identification Chemical Name2,4-Dinitrophenylhydrazine Hydrochloride [for HPLC Labeling] Portland OR 2,4-Dinitrophenylhydrazine Hydrochloride (for HPLC Synonym labeling)
Chemical FormulaC6H6N4O4.HCl 55907-61-4 CAS Number Section II.Composition and Information on Ingredients Chemical NameCAS Number Percent (%)TLV/PELToxicology Data 2,4-Dinitrophenylhydrazine Hydrochloride55907-61-4Min. 98.0 Not available.Not available. [for HPLC Labeling] (HPLC,T) Section III. Hazards Identification No specific information is available in our data base regarding the toxic effects of this material for humans. However, Acute Health Effects exposure to any chemical should be kept to a minimum. Skin and eye contact may result in irritation. May be harmful if inhaled or ingested. Always follow safe industrial hygiene practices and wear proper protective equipment when handling this compound. CARCINOGENIC EFFECTS : Not available. Chronic Health Effects MUTAGENIC EFFECTS : Not available. TERATOGENIC EFFECTS : Not available. DEVELOPMENTAL TOXICITY: Not available. There is no known effect from chronic exposure to this product. Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions. Section IV.First Aid Measures Eye ContactCheck for and remove any contact lenses. DO NOT use an eye ointment. Flush eyes with running water for a minimum of 15 minutes, occasionally lifting the upper and lower eyelids. Seek medical attention. Treat symptomatically and supportively. Skin ContactAfter contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cover the irritated skin with an emollient. Seek medical attention. Treat symptomatically and supportively. Wash any contaminated clothing before reusing. If the victim is not breathing, perform artificial respiration. Loosen tight clothing such as a collar, tie, belt or waistband. If Inhalation breathing is difficult, oxygen can be administered. Seek medical attention. Treat symptomatically and supportively. INDUCE VOMITING by sticking finger in throat. Lower the head so that the vomit will not reenter the mouth and throat. Ingestion Loosen tight clothing such as a collar, tie, belt, or waistband. If the victim is not breathing, administer artificial respiration. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the toxic material was ingested; the absence of such signs, however, is not conclusive. Seek immediate medical attention and, if possible, show the chemical label. Treat symptomatically and supportively. Section V.Fire and Explosion Data Not available. Flammable.Auto-Ignition Flammability Flash PointsFlammable LimitsNot available. Not available. These products are toxic carbon oxides (CO, CO2), nitrogen oxides (NO, NO2), halogenated compounds. Combustion Products WARNING: Highly toxic HCl gas is produced during combustion. Fire Hazards No specific information is available regarding the flammability of this compound in the presence of various materials. Explosion HazardsRisks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. No additional information is available regarding the risks of explosion. Fire Fighting Media SMALL FIRE: Use DRY chemicals, CO2, water spray or foam. LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet. and Instructions Continued on Next Page 2,4-Dinitrophenylhydrazine Hydrochloride [for HPLC Labeling] Section VI.Accidental Release Measures Spill CleanupFlammable solid. In case of a spill and/or a leak, always shut off any sources of ignition, ventilate the area, and exercise caution. Use a Instructions shovel to put the material into a convenient waste disposal container. Finish cleaning the spill by rinsing any contaminated surfaces with copious amounts of water. Consult federal, state, and/or local authorities for assistance on disposal. Section VII. Handling and Storage Handling and StorageFLAMMABLE SOLID. MAY REACT VIOLENTLY AND/OR EVOLVE HEAT UPON EXPOSURE TO SHOCK, HEAT, AND FRICTION. Reactive with strong oxidizers; may be ignited by heat, sparks, or flames. Vapors may travel to source of Information ignition and flash back. Tightly seal container and store in a cool place. Closed containers may explode from heat of a fire. Empty containers may pose a fire risk. Evaporate residue under a fume hood if possible. Ground all equipment containing material. Keep away from heat and sources of ignition. Mechanical exhaust required. When not in use, tightly seal the container and store in a dry, cool place. Avoid excessive heat and light. DO NOT breathe dust. In case of insufficient ventilation, wear suitable respiratory equipment. If you feel unwell, seek medical attention and show the label when possible. Treat symptomatically and supportively. Avoid contact with skin and eyes. Always store away from incompatible compounds such as oxidizing agents. Section VIII. Exposure Controls/Personal Protection Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended Engineering Controls exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Splash goggles. Lab coat. Dust respirator. Boots. Gloves. A MSHA/NIOSH approved respirator must be used to avoid Personal Protection inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure LimitsNot available. Section IX. Physical and Chemical Properties Powder.Solubility Physical state @ 20°CNot available. Not available. Specific Gravity 234.6 Molecular WeightPartition CoefficientNot available. Boiling PointNot available.Vapor PressureNot available. Not available.Not available. Melting PointVapor Density Not available.VolatilityNot available. Refractive Index Not available. Critical TemperatureNot available.Odor ViscosityNot available.TasteNot available. Section X.Stability and Reactivity Data Stability This material is stable if stored under proper conditions. (See Section VII for instructions) Conditions of InstabilityAvoid excessive heat and light. Incompatibilities Reactive with oxidizing agents. Section XI. Toxicological Information Not available. RTECS Number Eye contact. Inhalation. Ingestion. Routes of Exposure Toxicity DataNot available. Chronic Toxic EffectsCARCINOGENIC EFFECTS : Not available. MUTAGENIC EFFECTS : Not available. TERATOGENIC EFFECTS : Not available. DEVELOPMENTAL TOXICITY: Not available. There is no known effect from chronic exposure to this product. Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions. Acute Toxic EffectsNo specific information is available in our data base regarding the toxic effects of this material for humans. However, exposure to any chemical should be kept to a minimum. Skin and eye contact may result in irritation. May be harmful if inhaled or ingested. Always follow safe industrial hygiene practices and wear proper protective equipment when handling this compound. Continued on Next Page 2,4-Dinitrophenylhydrazine Hydrochloride [for HPLC Labeling] Section XII.Ecological Information EcotoxicityNot available. Not available. Environmental Fate Section XIII. Disposal Considerations Recycle to process, if possible. Consult your local or regional authorities. You may be able to dissolve or mix material with a Waste Disposal combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all federal, state, and local regulations when disposing of this substance. Section XIV. Transport Information DOT CLASS 4.1: Flammable solid. DOT Classification PIN Number Proper Shipping NameFlammable solid, organic, n.o.s. Packing Group (PG)II DOT Pictograms Section XV. Other Regulatory Information and Pictograms TSCA Chemical InventoryThis product is NOT on the EPA Toxic Substances Control Act (TSCA) inventory. The following notices are required by 40 CFR 720.36 (C) for those products not on the inventory list: (EPA) (i) These products are supplied solely for use in research and development by or under the supervision of a technically qualified individual as defined in 40 CFR 720.0 et sec. (ii) The health risks of these products have not been fully determined. Any information that is or becomes available will be supplied on an MSDS sheet. WHMIS ClassificationNot controlled under WHMIS (Canada). (Canada) EINECS Number (EEC) 259-888-5 EEC Risk StatementsNot available. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 海关编码 | 2928000090 |
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| 海关编码 | 2928000090 |
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| 中文概述 | 2928000090 其他肼（联氨）及胲（羟胺）的有机衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:20.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0% |