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| 中文名 | 4-甲氧基-3-硝基苯甲腈 |
|---|---|
| 英文名 | 4-methoxy-3-nitrobenzonitrile |
| 英文别名 |
3-Nitro-anissaeure-nitril
2-Nitro-4-cyanoanisol 4-methoxy-3-nitrobenzenecarbonitrile 4-Methoxy-3-nitro-benzonitril 3-Nitro-4-methoxy-benzoesaeure-nitril 5-Cyano-2-methoxynitrobenzene 3-Nitro-4-methoxybenzonitrile 4-methoxy-3-nitro-benzonitrile |
| 密度 | 1.32g/cm3 |
|---|---|
| 沸点 | 330.2ºC at 760mmHg |
| 熔点 | 148-150ºC |
| 分子式 | C8H6N2O3 |
| 分子量 | 178.14500 |
| 闪点 | 153.5ºC |
| 精确质量 | 178.03800 |
| PSA | 78.84000 |
| LogP | 1.99828 |
| 折射率 | 1.563 |
| 储存条件 | 室温 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 20/21/22 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. Causes respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 33224-23-6: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: off-white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 148 - 150 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C8H6N2O3 Molecular Weight: 178 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Acids, bases, oxidizing agents, reducing agents. Hazardous Decomposition Products: Hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 33224-23-6 unlisted. LD50/LC50: Not available. Carcinogenicity: 4-Methoxy-3-nitrobenzonitrile - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: NITRILES, SOLID, TOXIC, N.O.S.* Hazard Class: 6.1 UN Number: 3276 Packing Group: III IMO Shipping Name: NITRILES, TOXIC, N.O.S. Hazard Class: 6.1 UN Number: 3276 Packing Group: III RID/ADR Shipping Name: NITRILES, TOXIC, N.O.S. Hazard Class: 6.1 UN Number: 3276 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 33224-23-6: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 33224-23-6 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 33224-23-6 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 危害码 (欧洲) | Xn:Harmful; |
|---|---|
| 风险声明 (欧洲) | 20/21/22-36/37/38 |
| 安全声明 (欧洲) | 26-36/37/39 |
| 危险品运输编码 | UN 3276 |
| 海关编码 | 2926909090 |
|
~97%
33224-23-6 |
| 文献：Aridoss, Gopalakrishnan; Laali, Kenneth K. Journal of Organic Chemistry, 2011 , vol. 76, # 19 p. 8088 - 8094 |
|
~74%
33224-23-6 |
| 文献：Bakunov, Stanislav A.; Bakunova, Svetlana M.; Wenzler, Tanja; Ghebru, Maedot; Werbovetz, Karl A.; Brun, Reto; Tidwell, Richard R. Journal of Medicinal Chemistry, 2010 , vol. 53, # 1 p. 254 - 272 |
|
~99%
33224-23-6 |
| 文献：RECORDATI INDUSTRIA CHIMICA E FARMACEUTICA S.p.a.; RECORDATI S.A. CHEMICAL and PHARMACEUTICAL COMPANY Patent: EP1222183 B1, 2003 ; |
|
~%
33224-23-6 |
| 文献：Magnetic Resonance in Chemistry, , vol. 30, # 6 p. 497 - 499 |
|
~%
33224-23-6 |
| 文献：Chemische Berichte, , vol. 2, p. 666 |
|
~%
33224-23-6 |
| 文献：Recueil des Travaux Chimiques des Pays-Bas, , vol. 66, p. 369 Chem.Abstr., , vol. 42, p. 148 |
|
~%
33224-23-6 |
| 文献：Recueil des Travaux Chimiques des Pays-Bas, , vol. 41, p. 106,107 |
| 上游产品 9 | |
|---|---|
| 下游产品 4 | |
| 海关编码 | 2926909090 |
|---|---|
| 中文概述 | 2926909090 其他腈基化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0% |
