14742-32-6

14742-32-6结构式

常用中文名：2-氨基-5-苯基-3-呋喃甲腈
常用英文名：2-amino-5-phenyl-3-furonitrile
CAS号：14742-32-6
分子式：C₁₁H₈N₂O
分子量：184.19400
发布时间：2018-12-30 17:35:30
更新时间：2024-01-02 16:07:12

中文名	2-氨基-5-苯基-3-呋喃甲腈
英文名	2-amino-5-phenylfuran-3-carbonitrile
中文别名	2-氨基-5-苯基-3-氰基呋喃
英文别名	2-amino-5-phenyl-3-cyanofuran MFCD00463472 2-amino-5-phenyl-3-furonitrile 2-Amino-5-phenyl-furan-3-carbonitrile 2-amino-3-cyano-5-phenylfuran F0777-1641 2-amino-5-phenyl-3-furancarbonitrile

密度	1.26g/cm3
沸点	378.8ºC at 760mmHg
熔点	196ºC
分子式	C₁₁H₈N₂O
分子量	184.19400
闪点	182.9ºC
精确质量	184.06400
PSA	62.95000
LogP	2.98168
蒸汽压	6.12E-06mmHg at 25°C
折射率	1.633

Name:	2-Amino-5-phenyl-3-furonitrile 97% Material Safety Data Sheet
Synonym:
CAS:	14742-32-6

Section 1 - Chemical Product MSDS Name:2-Amino-5-phenyl-3-furonitrile 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
14742-32-6	2-Amino-5-phenyl-3-furonitrile	97%	unlisted

Hazard Symbols: XN
Risk Phrases: 20/21/22

Section 3 - HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 14742-32-6: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 196 - 198 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C11H8N2O
Molecular Weight: 184

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 14742-32-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Amino-5-phenyl-3-furonitrile - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: NITRILES, SOLID, TOXIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3276
Packing Group: III
IMO
Shipping Name: NITRILES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing Group: III
RID/ADR
Shipping Name: NITRILES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 14742-32-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 14742-32-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 14742-32-6 is not listed on the TSCA inventory.
It is for research and development use only.

SECTION 16 - ADDITIONAL INFORMATION
N/A

危害码 (欧洲)	Xi: Irritant;
风险声明 (欧洲)	22-36
安全声明 (欧洲)	26
海关编码	2932190090

70-11-1

109-77-3

~80%

14742-32-6

文献：Bakavoli, Mehdi; Rahimizadeh, Mohammad; Gordi, Zinat Journal of Chemical Research, 2008 , # 10 p. 564 - 565

14476-72-3

~70%

14742-32-6

文献：Abdelhamid, Abdou O.; Negm, Abdalla M.; Abbas, Ikhlass M. Journal fuer Praktische Chemie (Leipzig), 1989 , vol. 331, # 1 p. 31 - 36

14476-72-3

~14%

14742-32-6

158692-52-5

文献：Foley, Louise H. Tetrahedron Letters, 1994 , vol. 35, # 33 p. 5989 - 5992

100805-20-7

~89%

14742-32-6

文献：Nasakin; Sheverdov; Moiseeva; Ershov; Chernushkin; Tafeenko Russian Journal of General Chemistry, 1999 , vol. 69, # 2 p. 291 - 300

70-11-1

14742-32-6

文献：Maeda, Yutaka; Nakano, Masato; Sato, Hideyuki; Miyazaki, Yasushi; Schweiker, Stephanie L.; Smith, Jeffery L.; Truesdale, Anne T. Bioorganic and Medicinal Chemistry Letters, 2004 , vol. 14, # 15 p. 3907 - 3911

上游产品 3
70-11-1 109-77-3 14476-72-3
下游产品 2
220696-22-0 18031-97-5

海关编码	2932190090
中文概述	2932190090 其他结构上有非稠合呋喃环化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

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