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| 中文名 | 1,3-双(叔丁基过氧异丙基)苯 |
|---|---|
| 英文名 | di(tert-butylperoxyisopropyl)benzene |
| 中文别名 |
双叔丁基过氧化二异丙基苯
无味DCP 无味交联剂 1,3-双丁基过氧异丙基苯 交联剂BIPB |
| 英文别名 |
Luperox 802
1,3-bis(t-butylperoxyisopropyl)benzene 1,3-Bis-(2-tert-butylperoxiisopropyl)benzol 1,3-Bis{2-[(2-methyl-2-propanyl)peroxy]-2-propanyl}benzene Perbutyl PT BIBP Perkadox14S 1,3-BIS(TERT-BUTYLDIOXYISOPROPYL)BENZENE LINKWELL BIPB 14s m-bis-(2-tert-Butylperoxy-2-propyl)benzene 1,3-Bis(tert-butylperoxyisopropyl)benzene Peroximon F Perhexa F 40 PEROXAN BIB [1,3-phenylenebis(1-methylethylidene)]bis[tert-butyl] peroxide EINECS 218-664-7 |
| 密度 | 1.0±0.1 g/cm3 |
|---|---|
| 沸点 | 360.1±35.0 °C at 760 mmHg |
| 熔点 | 43-49ºC |
| 分子式 | C20H34O4 |
| 分子量 | 338.482 |
| 闪点 | 129.6±25.8 °C |
| 精确质量 | 338.245697 |
| PSA | 36.92000 |
| LogP | 6.66 |
| 外观性状 | 白色至略黄色片 |
| 蒸汽压 | 0.0±0.8 mmHg at 25°C |
| 折射率 | 1.475 |
| 储存条件 | 密封储存，储存于阴凉、干燥的库房。远离可燃材料，还原剂。冷藏储存。 |
| 稳定性 | 危险的自加速分解反应，在某些情况下，爆炸或火灾可能是由于直接接触不相容的物质或热分解及以上的自加速分解温度。 避免与不相容材料，火源，可燃材料接触。 与还原剂，酸，碱，铁锈，重金属反应。 |
| 计算化学 | 1、 疏水参数计算参考值（XlogP）：4.5 2、 氢键供体数量：0 3、 氢键受体数量：4 4、 可旋转化学键数量：8 5、 互变异构体数量： 6、 拓扑分子极性表面积（TPSA）：36.9 7、 重原子数量：24 8、 表面电荷：0 9、 复杂度：351 10、 同位素原子数量：0 11、 确定原子立构中心数量：0 12、 不确定原子立构中心数量：0 13、 确定化学键立构中心数量：0 14、 不确定化学键立构中心数量：0 15、 共价键单元数量：1 |
| 更多 | 1. 性状：白色或黄色有微弱气味的薄片 2. 密度（g/mL,25℃）：未确定 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：43-49 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC,15mmHg）：未确定 7. 折射率(n20/D)：未确定 8. 闪点（ºC）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：＞380 11. 蒸气压（mPa,20ºC）：未确定 12. 饱和蒸气压（kPa,25ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：不溶于水 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36 7 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes. May cause fire. Potential Health Effects Eye: Causes eye irritation. Skin: Non-irritating to the skin. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Remove all sources of ignition. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid mechanical shock and friction. Storage: Do not store near combustible materials. Store in a tightly closed container. Store in a dry area. Keep refrigerated. (Store below 4C/39F.) Keep away from reducing agents. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use explosion-proof ventilation equipment. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure Limits CAS# 2212-81-9: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: white Odor: faint odor pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 44 - 48 deg C Autoignition Temperature: > 380 deg C (> 716.00 deg F) Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Insoluble. Specific Gravity/Density: Molecular Formula: C20H34O4 Molecular Weight: 338.49 Section 10 - STABILITY AND REACTIVITY Chemical Stability: A dangerous self-accelerating decomposition reaction and, under certain circumstances, explosion or fire can be caused by direct contact with incompatible substances or by thermal decomposition at and above the SADT (see Section 16). Conditions to Avoid: Incompatible materials, ignition sources, combustible materials. Incompatibilities with Other Materials: Reducing agents, acids, bases, rust, heavy metals. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, acetone, methane. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 2212-81-9 unlisted. LD50/LC50: Not available. Carcinogenicity: Di(tert-butylperoxyisopropyl)benzene - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Other No information available. Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI O Risk Phrases: R 36 Irritating to eyes. R 7 May cause fire. Safety Phrases: S 3/7 Keep container tightly closed in a cool, well-ventilated place. S 14A Keep away from acids, reducing agents and polymerisation catalysts. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 2212-81-9: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 2212-81-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 2212-81-9 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 危害码 (欧洲) | Xi,O |
|---|---|
| 风险声明 (欧洲) | R7 |
| 安全声明 (欧洲) | 36/37/39-3/7-26-14A |
| 危险品运输编码 | UN 3106 |
| 包装等级 | II |
| 危险类别 | 5.2 |
| 海关编码 | 2909600000 |
| 海关编码 | 2909600000 |
|---|---|
| 中文概述 | 2909600000 过氧化醇、过氧化醚、过氧化酮及其卤化、磺化、硝化、亚硝化衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2909600000 alcohol peroxides, ether peroxides, ketone peroxides and their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0% |