117249-17-9

117249-17-9结构式
117249-17-9结构式

化源商城直购

英文名 (2S,3S,4S)-2-methyl-3,4-bis(phenylmethoxy)-3,4-dihydro-2H-pyran
英文别名 3,4-di-O-benzyl-L-rhamnal
perbenzylated L-rhamnal
3,4,6-tribenzyl-L-rhamnal
3,4-di-O-benzyl-6-deoxy-L-glucal
密度 1.12g/cm3
沸点 434.2ºC at 760 mmHg
熔点 111ºC
分子式 C20H22O3
分子量 310.38700
闪点 148.1ºC
精确质量 310.15700
PSA 27.69000
LogP 4.08960
蒸汽压 2.45E-07mmHg at 25°C
折射率 1.577
Name: 3 4-Di-O-benzyl-L-rhamnal Material Safety Data Sheet
Synonym:
CAS: 117249-17-9
Section 1 - Chemical Product MSDS Name:3 4-Di-O-benzyl-L-rhamnal Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
117249-17-9 3,4-Di-O-benzyl-L-rhamnal unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 117249-17-9: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 111 - 113 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C20H22O3
Molecular Weight: 310.39

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 117249-17-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3,4-Di-O-benzyl-L-rhamnal - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 117249-17-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 117249-17-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 117249-17-9 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
安全声明 (欧洲) S24/25

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文献:Nicolaou; Snyder, Scott A.; Nalbandian, Annie Z.; Longbottom, Deborah A. Journal of the American Chemical Society, 2004 , vol. 126, # 20 p. 6234 - 6235

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文献:Madhusudan, Soni Kamlesh; Agnihotri, Geetanjali; Negi, Devendra S.; Misra, Anup Kumar Carbohydrate Research, 2005 , vol. 340, # 7 p. 1373 - 1377

~75%

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文献:Vedachalam, Seenuvasan; Tan, Shi Min; Teo, Hui Ping; Cai, Shuting; Liu, Xue-Wei Organic Letters, 2012 , vol. 14, # 1 p. 174 - 177

~88%

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文献:Zhao, Jinzhong; Shao, Huawu; Wu, Xin; Shi, Shaojing Chinese Journal of Chemistry, 2011 , vol. 29, # 7 p. 1434 - 1440

~18%

详细
文献:Thiem, Joachim; Klaffke, Werner; Springer, Dirk Carbohydrate Research, 1988 , vol. 174, p. 201 - 210

~%

117249-17-9结构式

117249-17-9

文献:Vedachalam, Seenuvasan; Tan, Shi Min; Teo, Hui Ping; Cai, Shuting; Liu, Xue-Wei Organic Letters, 2012 , vol. 14, # 1 p. 174 - 177

~%

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文献:Zagar, Cyrill; Scharf, Hans-Dieter Liebigs Annalen der Chemie, 1993 , # 4 p. 447 - 450