| 中文名 | 4,4’-亚甲双(2,6-二异丙基苯胺) |
|---|---|
| 英文名 | 4-[[4-amino-3,5-di(propan-2-yl)phenyl]methyl]-2,6-di(propan-2-yl)aniline |
| 中文别名 | 4,4'-亚甲基双(2,6-二异丙基苯胺) |
| 英文别名 |
methylene-1,1-bis(2,6-diisopropylaniline)
EINECS 243-421-7 MFCD00071554 4-{[4-amino-3,5-bis(methylethyl)phenyl]methyl}-2,6-bis(methylethyl)phenylamine di(2,6-diisopropyl-4-aminophenyl)methane 4,4'-methylenebis(N-salicylidene-2,6-diisopropylaniline) 4,4'-methylene-bis(2,6-diisopropylaniline) |
| 密度 | 0.98 g/cm3 |
|---|---|
| 沸点 | 215-218ºC (0.5 mmHg) ,481ºC at 760 mmHg |
| 熔点 | 10-30ºC |
| 分子式 | C25H38N2 |
| 分子量 | 366.58300 |
| 闪点 | 294ºC |
| 精确质量 | 366.30300 |
| PSA | 52.04000 |
| LogP | 8.09780 |
| 外观性状 | 褐色熔融 |
| 蒸汽压 | 2.07E-09mmHg at 25°C |
| 折射率 | 1.559 |
| 储存条件 | 密闭于阴凉干燥环境中 |
| 稳定性 | 遵照规定使用和储存则不会分解。 |
| 分子结构 | 1、 摩尔折射率：120.77 2、 摩尔体积（m3/mol）：373.6 3、 等张比容（90.2K）：930.1 4、 表面张力（dyne/cm）：38.3 5、 极化率（10-24cm3）：47.88 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:7 2.氢键供体数量:2 3.氢键受体数量:2 4.可旋转化学键数量:6 5.互变异构体数量:无 6.拓扑分子极性表面积52 7.重原子数量:27 8.表面电荷:0 9.复杂度:366 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：无可用 2. 密度（g/mL,25/4℃）：0.99 3. 相对蒸汽密度（g/mL,空气=1）：无可用 4. 熔点（ºC）：10-30 5. 沸点（ºC,常压）：215-218 /0.5 mmHg 6. 沸点（ºC,5.2kPa）：无可用 7. 折射率：无可用 8. 闪点（ºC）：113 9. 比旋光度（º）：无可用 10. 自燃点或引燃温度（ºC）：无可用 11. 蒸气压（kPa,25ºC）：无可用 12. 饱和蒸气压（kPa,60ºC）：无可用 13. 燃烧热（KJ/mol）：无可用 14. 临界温度（ºC）：无可用 15. 临界压力（KPa）：无可用 16. 油水（辛醇/水）分配系数的对数值：无可用 17. 爆炸上限（%,V/V）：无可用 18. 爆炸下限（%,V/V）：无可用 19. 溶解性：无可用 |
Synonym:None Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 22 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful if swallowed.The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure Limits CAS# 19900-69-7: Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear a chemical apron. Respirators: A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: beige Odor: Not pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 215.0 - 218.0 deg C @ .50mmHg Freezing/Melting Point: 52.00 - 59.00 deg C Autoignition Temperature: Not available. Flash Point: > 110 deg C (> 230.00 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: insoluble Specific Gravity/Density: 1.0150g/cm3 Molecular Formula: C25H38N2 Molecular Weight: 366.58 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, irritating and toxic gases, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 19900-69-7 unlisted. LD50/LC50: Not available. Carcinogenicity: Benzenamine,4,4'-methylenebis2,6-bis(1-methylethyl)- - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 22 Harmful if swallowed. Safety Phrases: WGK (Water Danger/Protection) CAS# 19900-69-7: No information available. Canada CAS# 19900-69-7 is listed on Canada's NDSL List. CAS# 19900-69-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 19900-69-7 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 通常对水是不危害的，若无政府许可，勿将材料排入周围环境。
|
| 危害码 (欧洲) | Xn |
|---|---|
| 风险声明 (欧洲) | R36/38 |
| 安全声明 (欧洲) | 36/37/39-26 |
| 海关编码 | 2921590090 |
|
~40%
19900-69-7 |
| 文献：EXXONMOBIL CHEMICAL PATENTS, INC. Patent: WO2005/118605 A1, 2005 ; Location in patent: Page/Page column 107-108 ; |
| 上游产品 2 | |
|---|---|
| 下游产品 0 | |
| 海关编码 | 2921590090 |
|---|---|
| 中文概述 | 2921590090. 其他芳香多胺及衍生物及它们的盐. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2921590090. other aromatic polyamines and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0% |
