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| 中文名 | 3,3'-二甲基吡啶胺 |
|---|---|
| 英文名 | 1-pyridin-3-yl-N-(pyridin-3-ylmethyl)methanamine |
| 中文别名 |
3,3'-双(吡啶甲基)胺
双(3-吡啶基甲基)胺 3,3’-二甲基吡啶胺 α,α'-亚胺二(3-甲基吡啶) |
| 英文别名 |
Bis(3-pyridylmethyl)amine
3,3'-Dipicolylamine α,α'-Iminodi(3-picoline) EINECS 216-753-5 Bis-pyridin-3-ylmethyl-amine |
| 密度 | 1.118g/cm3 |
|---|---|
| 沸点 | 356.2ºC at 760mmHg |
| 分子式 | C12H13N3 |
| 分子量 | 199.25200 |
| 闪点 | 169.2ºC |
| 精确质量 | 199.11100 |
| PSA | 37.81000 |
| LogP | 2.15730 |
| 蒸汽压 | 2.98E-05mmHg at 25°C |
| 折射率 | 1.589 |
| 储存条件 | 室温，存于惰性气体中 |
| 分子结构 | 五、分子性质数据： 1、 摩尔折射率：60.06 2、 摩尔体积（m3/mol）：178.2 3、 等张比容（90.2K）：472.2 4、 表面张力（dyne/cm）：49.3 5、 极化率（10-24cm3）：23.81 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:1 3.氢键受体数量:3 4.可旋转化学键数量:4 5.互变异构体数量:无 6.拓扑分子极性表面积37.8 7.重原子数量:15 8.表面电荷:0 9.复杂度:154 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：未确定。 2. 密度（g/mL,25/4℃）： 1.12 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC,5.2kPa）： 未确定 7. 折射率： 未确定 8. 闪点（ºC）： 未确定 9. 比旋光度（º）： 未确定 10. 自燃点或引燃温度（ºC）： 未确定 11. 蒸气压（kPa,25ºC）： 未确定 12. 饱和蒸气压（kPa,60ºC）： 未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）： 未确定 15. 临界压力（KPa）： 未确定 16. 油水（辛醇/水）分配系数的对数值： 未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）： 未确定 19. 溶解性：未确定 |
|
Revision number: 5
Bis(3-pyridylmethyl)amine SAFETY DATA SHEET Section1. IDENTIFICATION Bis(3-pyridylmethyl)amine Product name: 5 Revision number: Section2. HAZARDS IDENTIFICATION GHS classification Not classified PHYSICAL HAZARDS HEALTH HAZARDS Category 2 Skin corrosion/irritation Category 2A Serious eye damage/eye irritation Not classified ENVIRONMENTAL HAZARDS GHS label elements, including precautionary statements Pictograms or hazard symbols Warning Signal word Causes skin irritation Hazard statements Causes serious eye irritation Precautionary statements: Wash hands thoroughly after handling. [Prevention] Wear protective gloves/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, [Response] if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Gently wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substance Substance/mixture: Bis(3-pyridylmethyl)amine Components: >97.0%(GC) Percent: 1656-94-6 CAS Number: 3,3'-Dipicolylamine , α,α'-Iminodi(3-picoline) Synonyms: C12H13N3 Chemical Formula: Section4. FIRST AID MEASURES Remove victim to fresh air and keep at rest in a position comfortable for breathing. Inhalation: Get medical advice/attention if you feel unwell. Bis(3-pyridylmethyl)amine Section4. FIRST AID MEASURES Remove/Take off immediately all contaminated clothing. Gently wash with plenty of Skin contact: soap and water. If skin irritation or rash occurs: Get medical advice/attention. Rinse cautiously with water for several minutes. Remove contact lenses, if present Eye contact: and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Get medical advice/attention if you feel unwell. Rinse mouth. Ingestion: A rescuer should wear personal protective equipment, such as rubber gloves and air- Protection of first-aiders: tight goggles. Section5. FIRE-FIGHTING MEASURES Dry chemical, foam, water spray, carbon dioxide. Suitable extinguishing media: Unsuitable extinguishing Solid streams of water media: Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to generate poisonous fume. from the chemical: Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Remove movable containers if safe to do so. When extinguishing fire, be sure to wear personal protective equipment. Special protective equipment for firefighters: Section6. ACCIDENTAL RELEASE MEASURES Use personal protective equipment. Keep people away from and upwind of spill/leak. Personal precautions, protective equipment and Ensure adequate ventilation. Entry to non-involved personnel should be controlled emergency procedures: around the leakage area by roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust). containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected up: material should be promptly disposed of, in accordance with appropriate laws and regulations. Section7. HANDLING AND STORAGE Precautions for safe handling Handling is performed in a well ventilated place. Wear suitable protective equipment. Technical measures: Prevent generation of vapour or mist. Wash hands and face thoroughly after handling. Use a ventilation, local exhaust if vapour or aerosol will be generated. Advice on safe handling: Avoid contact with skin, eyes and clothing. Conditions for safe storage, including any incompatibilities Keep container tightly closed. Store in a cool and dark place. Storage conditions: Store under inert gas. Store away from incompatible materials such as oxidizing agents. Air-sensitive Comply with laws. Packaging material: Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION Install a closed system or local exhaust as possible so that workers should not be Engineering controls: exposed directly. Also install safety shower and eye bath. Personal protective equipment Respiratory protection: Vapor respirator. Follow local and national regulations. Protective gloves. Hand protection: Safety glasses. A face-shield, if the situation requires. Eye protection: Skin and body protection: Protective clothing. Protective boots, if the situation requires. Bis(3-pyridylmethyl)amine Section9. PHYSICAL AND CHEMICAL PROPERTIES Liquid Physical state (20°C): Clear Form: Very pale yellow - Yellow Colour: No data available Odour: pH: No data available Melting point/freezing point:No data available No data available Boiling point/range: No data available Flash point: Flammability or explosive limits: No data available Lower: No data available Upper: 1.12 Relative density: Solubility(ies): No data available [Water] No data available [Other solvents] Section10. STABILITY AND REACTIVITY Stable under proper conditions. Chemical stability: Possibility of hazardous No special reactivity has been reported. reactions: Incompatible materials: Oxidizing agents Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx) products: Section11. TOXICOLOGICAL INFORMATION ivn-mus LD50:250 mg/kg Acute Toxicity: Skin corrosion/irritation: No data available No data available Serious eye damage/irritation: No data available Germ cell mutagenicity: Carcinogenicity: No data available IARC = No data available NTP = No data available Reproductive toxicity: UT4397000 RTECS Number: Section12. ECOLOGICAL INFORMATION Ecotoxicity: No data available Fish: No data available Crustacea: No data available Algae: Persistence / degradability: No data available No data available Bioaccumulative potential(BCF): Mobility in soil No data available Log Pow: No data available Soil adsorption (Koc): No data available Henry's Law constant(PaM3/mol): Section13. DISPOSAL CONSIDERATIONS Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when disposing of the substance. Bis(3-pyridylmethyl)amine Section14. TRANSPORT INFORMATION Does not correspond to the classification standard of the United Nations Hazards Class: Not listed UN-No: Section15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002 and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were prescribed. SECTION 16 - ADDITIONAL INFORMATION N/A |
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毒理学数据: 急性毒性：小鼠静脉LD50： 250mg/kg；
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATA
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| 危害码 (欧洲) | Xi: Irritant; |
|---|---|
| 风险声明 (欧洲) | 20/21/22-36/37/38 |
| 安全声明 (欧洲) | 26-36/37/39 |
| RTECS号 | UT4397000 |
| 海关编码 | 2933399090 |
|
~%
1656-94-6 |
| 文献：Journal of the American Chemical Society, , vol. 66, p. 1293 |
|
~12%
1656-94-6 |
| 文献：Organic Letters, , vol. 11, # 4 p. 883 - 886 |
|
~%
1656-94-6 |
| 文献：Tetrahedron Letters, , vol. 45, # 2 p. 397 - 399 |
|
~%
1656-94-6 |
| 文献：Journal of the American Chemical Society, , vol. 66, p. 1293 |
|
~%
1656-94-6 |
| 文献：Journal of the American Chemical Society, , vol. 66, p. 1293 |
|
~%
1656-94-6 |
| 文献：Journal of the American Chemical Society, , vol. 66, p. 1293 |
|
~8%
1656-94-6
详细
|
| 文献：Green Chemistry, , vol. 13, # 11 p. 3096 - 3100 |
|
~%
1656-94-6 |
| 文献：Journal of the American Chemical Society, , vol. 66, p. 876,877 |
| 上游产品 10 | |
|---|---|
| 下游产品 0 | |
| 海关编码 | 2933399090 |
|---|---|
| 中文概述 | 2933399090. 其他结构含非稠合吡啶环的化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0% |
| 申报要素 | 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期 |
| Summary | 2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0% |
