| 中文名 | 马杜拉霉素 |
|---|---|
| 英文名 | 1-bromo-3-ethyladamantane |
| 中文别名 | 1-溴-3-乙基金刚烷 |
| 英文别名 |
1-Brom-3-aethyl-adamantan
3-Brom-1-ethyl-adamantan 1-ethyl-3-bromoadamantane 3-Brom-1-aethyl-adamantan 1-bromo-3-ethyl-adamantane |
| 密度 | 1.344g/cm3 |
|---|---|
| 沸点 | 124ºC |
| 熔点 | 23ºC |
| 分子式 | C12H19Br |
| 分子量 | 243.18300 |
| 闪点 | 115.6ºC |
| 精确质量 | 242.06700 |
| LogP | 4.13030 |
| 折射率 | 1.567 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Keep refrigerated. (Store below 4C/39F.) Store in a tightly closed container. Store in a dry area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 878-61-5: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 124 - 125 deg C @7mmHg Freezing/Melting Point: 23 - 24 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C12H19Br Molecular Weight: 243 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, hydrogen bromide, acrid smoke and fumes, bromine. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 878-61-5 unlisted. LD50/LC50: Not available. Carcinogenicity: 1-Bromo-3-ethyladamantane - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 878-61-5: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 878-61-5 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 878-61-5 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 危害码 (欧洲) | Xi: Irritant; |
|---|---|
| 海关编码 | 2903890090 |
|
~90%
878-61-5 |
| 文献：Inomata, Sotaro; Harada, Yusuke; Nakamura, Yuya; Uehara, Yosuke; Ishizone, Takashi Journal of Polymer Science, Part A: Polymer Chemistry, 2013 , vol. 51, # 19 p. 4111 - 4124 |
|
~%
878-61-5 |
| 文献：Journal of Medicinal Chemistry, , vol. 25, # 1 p. 51 - 56 |
|
~%
878-61-5 |
| 文献：Journal of Medicinal Chemistry, , vol. 25, # 1 p. 51 - 56 |
|
~%
878-61-5 |
| 文献：Journal of Organic Chemistry USSR (English Translation), , vol. 5, p. 2123 - 2125 Zhurnal Organicheskoi Khimii, , vol. 5, # 12 p. 2187 - 2189 |
|
~%
878-61-5 |
| 文献：Journal of Organic Chemistry USSR (English Translation), , vol. 5, p. 2123 - 2125 Zhurnal Organicheskoi Khimii, , vol. 5, # 12 p. 2187 - 2189 |
| 海关编码 | 2903890090 |
|---|---|
| 中文概述 | 2903890090. 其他环烷烃、环烯烃或环萜烯烃的卤化衍生物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2903890090. halogenated derivatives of cyclanic, cyclenic or cyclotherpenic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0% |
