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| 中文名 | 2,4-二甲基喹啉 |
|---|---|
| 英文名 | 2,4-Dimethylquinoline |
| 中文别名 |
4-甲基喹哪啶
2,4-二甲基-1-氮杂萘 2,4-二甲基(5,6)苯并吡啶 2,4-二甲喹啉 |
| 英文别名 |
MFCD00006760
2,4-Dimethylquinoline 4-Methylquinaldine Quinoline, 2,4-dimethyl- EINECS 214-832-9 |
| 密度 | 1.1±0.1 g/cm3 |
|---|---|
| 沸点 | 263.8±9.0 °C at 760 mmHg |
| 分子式 | C11H11N |
| 分子量 | 157.212 |
| 闪点 | 107.6±11.3 °C |
| 精确质量 | 157.089142 |
| PSA | 12.89000 |
| LogP | 3.00 |
| 外观性状 | 液体;Colorless to Orange to Green clear liquid |
| 蒸汽压 | 0.0±0.5 mmHg at 25°C |
| 折射率 | 1.611 |
| 储存条件 | 保持贮藏器密封、储存在阴凉、干燥的地方，确保工作间有良好的通风或排气装置 |
| 稳定性 | 如果遵照规格使用和储存则不会分解，未有已知危险反应，避免氧化物 |
| 分子结构 | 1、 摩尔折射率：51.83 2、 摩尔体积（m3/mol）：149.3 3、 等张比容（90.2K）：380.5 4、 表面张力（dyne/cm）：42.1 5、 极化率（10 -24cm 3）：20.54 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:3 2.氢键供体数量:0 3.氢键受体数量:1 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积12.9 7.重原子数量:12 8.表面电荷:0 9.复杂度:155 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：黄色或无色液体 2. 密度（g/cm3,20℃）：1.061 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ ºC ）： 未确定 5. 沸点（ ºC, 常压）： 264-265 6. 沸点（ ºC,15mmHg ）： 未确定7. 折射率（n20/D）：1.605 8. 闪点（ºF）：>230 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（psi,55ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：能与乙醇、乙醚混溶，微溶于水。 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 1198-37-4: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: yellow Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 264 - 265 deg C Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: 113 deg C ( 235.40 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: 1.061 Molecular Formula: C11H11N Molecular Weight: 157.22 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 1198-37-4 unlisted. LD50/LC50: Not available. Carcinogenicity: 2,4-Dimethylquinoline - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 1198-37-4: No information available. Canada CAS# 1198-37-4 is listed on Canada's DSL List. CAS# 1198-37-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 1198-37-4 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 对水是稍微有危害的不要让未稀释或大量的产品接触地下水、水道或者污水系统，若无政府许可，勿将材料排入周围环境。
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| 危害码 (欧洲) | Xi: Irritant; |
|---|---|
| 风险声明 (欧洲) | R36/38 |
| 安全声明 (欧洲) | S26-S37/39 |
| WGK德国 | 3 |